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    Acid-functional polymers derived from cellulose ester-unsaturated alcohol copolymers, which are reacted with cyclic anhydrides
    2.
    发明授权
    Acid-functional polymers derived from cellulose ester-unsaturated alcohol copolymers, which are reacted with cyclic anhydrides 失效
    衍生自与环状酸酐反应的纤维素酯 - 不饱和醇共聚物的酸官能聚合物

    公开(公告)号：US4859758A

    公开(公告)日：1989-08-22

    申请号：US121265

    申请日：1987-11-16

    申请人： Mohamad D. Shalati ,  James A. Marquart ,  John R. Babjak ,  Rodney M. Harris

    发明人： Mohamad D. Shalati ,  James A. Marquart ,  John R. Babjak ,  Rodney M. Harris

    IPC分类号： C08F251/02

    CPC分类号： C08F251/02

    摘要： Novel carboxylic acid-functional polymers are obtained by reacting:(a) a hydroxy-functional polymer having an average of at least two hydroxyl groups per molecule; and(b) a cyclic anhydride under reaction conditions to produce acid groups and ester groups; andwherein the hydroxy-functional polymer is obtained by the copolymerization of:(i) 1-95 weight percent of a cellulose ester; and(ii) 5-99 weight percent of at least one ethylenically unsaturated alcohol copolymerizable with the cellulose acetate butyrate; and(iii) 0-94 weight percent of at least one other ethylenically unsaturated monomer copolymerizable with the cellulose ester and the ethylenically unsaturated alcohol.Curable compositions especially useful as coatings are prepared by mixing the novel carboxylic acid-functional polymers with epoxy-functional compounds and, optionally, with anhydride-functional compounds and, optionally, hydroxy-functional compounds. The coatings are especially useful in clearcoat/basecoat compositions.

    摘要翻译： 通过以下方法获得新型羧酸官能聚合物：（a）每分子平均具有至少两个羟基的羟基官能聚合物; 和（b）在酸性基团和酯基团的反应条件下的环状酸酐; 并且其中所述羟基官能聚合物通过以下共聚获得：（i）1-95重量％的纤维素酯; 和（ii）5-99重量％的可与乙酸丁酸纤维素共聚的至少一种烯属不饱和醇; 和（iii）0-94重量％的可与纤维素酯和烯键式不饱和醇共聚的至少一种其它烯属不饱和单体。 通过将新型羧酸官能聚合物与环氧官能化合物和任选的酸酐官能化合物和任选的羟基官能化合物混合来制备特别用作涂层的可固化组合物。 涂料在透明涂料/底漆组合物中特别有用。

    Acid-functional polymers derived from cellulose acetate butyrate unsaturated alcohol copolymers and coatings prepared from same
    5.
    发明授权
    Acid-functional polymers derived from cellulose acetate butyrate unsaturated alcohol copolymers and coatings prepared from same 失效
    衍生自醋酸丁酸纤维素不饱和醇共聚物的酸官能聚合物和由其制备的涂料

    公开(公告)号：US5086144A

    公开(公告)日：1992-02-04

    申请号：US393194

    申请日：1989-08-14

    申请人： Mohamad D. Shalati ,  James A. Marquart ,  John R. Babjak ,  Rodney M. Harris

    发明人： Mohamad D. Shalati ,  James A. Marquart ,  John R. Babjak ,  Rodney M. Harris

    IPC分类号： C08F251/02

    CPC分类号： C08F251/02 ,  Y10T428/31511 ,  Y10T428/31515

    摘要： Novel carboxylic acid-functional polymers are obtained by reacting:(a) a hydroxy-functional polymer having an average of at least two hydroxyl groups per molecule; and(b) a cyclic anhydride under reaction conditions to produce acid groups and ester groups; andwherein the hydroxy-functional polymer is obtained by the copolymerization of:(i) 1-95 weight percent of a cellulose ester; and(ii) 5-99 weight percent of at least one ethylenically unsaturated alcohol copolymerizable with the cellulose acetate butyrate; and(iii) 0-94 weight percent of at least one other ethylenically unsaturated monomer copolymerizable with the cellulose ester and the ethylenically unsaturated alcohol.Curable compositions especially useful as coatings are prepared by mixing the novel carboxylic acid-functional polymers with epoxy-functional compounds and, optionally, with anhydridefunctional compounds and, optionally, hydroxy-functional compounds. The coatings are especially useful in clearcoat/basecoat compositions.

    摘要翻译： 通过以下方法获得新型羧酸官能聚合物：（a）每分子平均具有至少两个羟基的羟基官能聚合物; 和（b）在酸性基团和酯基团的反应条件下的环状酸酐; 并且其中所述羟基官能聚合物通过以下共聚获得：（i）1-95重量％的纤维素酯; 和（ii）5-99重量％的可与乙酸丁酸纤维素共聚的至少一种烯属不饱和醇; 和（iii）0-94重量％的可与纤维素酯和烯键式不饱和醇共聚的至少一种其它烯属不饱和单体。 通过将新型羧酸官能聚合物与环氧官能化合物和任选地与酸酐官能化合物和任选的羟基官能化合物混合来制备特别可用作涂层的可固化组合物。 涂料在透明涂料/底漆组合物中特别有用。