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1.发明申请公开(公告)号：US20150361112A1
公开(公告)日：2015-12-17
申请号：US14737930
申请日：2015-06-12
Applicant: Momentive Performance Materials Inc.
Inventor： Aroop Kumar Roy , Julie L. Boyer , Juergen Koller , David Jenkins , Andrea Trotto , Kenrick M. Lewis
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/12 , C07F7/14 , C07F7/1804
Abstract: A process for the hydrosilylation of an unsaturated compound comprising reacting (a) a silyl hydride with (b) an unsaturated compound in the presence of (c) a platinum compound and (d) a cyclodiene, with the provisos that (i) when the unsaturated compound is a terminal alkyne, the silyl hydride is other than a halosilane, and (ii) when the platinum compound is a Pt(II)-based compound, the ratio of total moles of cyclodiene to moles of platinum is less than 3:1.
Abstract translation: 一种不饱和化合物的氢化硅烷化方法，包括在（c）铂化合物和（d）环二烯的存在下使（a）甲硅烷基氢化物与（b）不饱和化合物反应，条件是（ⅰ）当 不饱和化合物是末端炔烃，甲硅烷基氢化物不是卤代硅烷，（ii）当铂化合物是基于Pt（II）的化合物时，环二烯的总摩尔数与铂的摩尔数之比小于3： 1。
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2.发明授权公开(公告)号：US09434749B2
公开(公告)日：2016-09-06
申请号：US14737930
申请日：2015-06-12
Applicant: Momentive Performance Materials Inc.
Inventor： Aroop Kumar Roy , Julie L. Boyer , Juergen Koller , David Jenkins , Andrea Trotto , Kenrick M. Lewis
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/12 , C07F7/14 , C07F7/1804
Abstract: A process for the hydrosilylation of an unsaturated compound comprising reacting (a) a silyl hydride with (b) an unsaturated compound in the presence of (c) a platinum compound and (d) a cyclodiene, with the provisos that (i) when the unsaturated compound is a terminal alkyne, the silyl hydride is other than a halosilane, and (ii) when the platinum compound is a Pt(II)-based compound, the ratio of total moles of cyclodiene to moles of platinum is less than 3:1.
Abstract translation: 一种不饱和化合物的氢化硅烷化方法，包括在（c）铂化合物和（d）环二烯的存在下使（a）甲硅烷基氢化物与（b）不饱和化合物反应，条件是（ⅰ）当 不饱和化合物是末端炔烃，甲硅烷基氢化物不是卤代硅烷，（ii）当铂化合物是基于Pt（II）的化合物时，环二烯的总摩尔数与铂的摩尔数之比小于3： 1。
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