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公开(公告)号：US20100185018A1
公开(公告)日：2010-07-22
申请号：US12601858
申请日：2008-05-29
申请人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , Jae-Hui Choi
发明人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , Jae-Hui Choi
CPC分类号： C07C45/50 , B01J4/002 , B01J10/00 , B01J19/2465 , B01J2219/0011 , Y02P20/582 , C07C47/02
摘要： The present invention relates to a method for preparing aldehydes by reacting olefins with a synthesis gas including carbon monoxide and hydrogen, and to an apparatus therefore. More particularly, the present invention relates to a method for preparing aldehydes, characterized by spraying and supplying olefins, synthesis gas including carbon monoxide and hydrogen, and a catalyst composition into an oxo reactor through a nozzle, and to an apparatus therefore. According to the present invention, the hydroformylation efficiency can be improved, thereby obtaining desirable aldehydes with a high yield.
摘要翻译： 本发明涉及一种通过使烯烃与包括一氧化碳和氢气在内的合成气反应制备醛的方法及其装置。 更具体地说，本发明涉及一种制备醛的方法，其特征在于通过喷嘴将催化剂组合物喷射并供给烯烃，包括一氧化碳和氢气的合成气，以及催化剂组合物装入氧代反应器，因此涉及一种设备。 根据本发明，可以提高加氢甲酰化效率，从而以高产率获得所需的醛。
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公开(公告)号：US07939694B2
公开(公告)日：2011-05-10
申请号：US12601858
申请日：2008-05-29
申请人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , Jae-Hui Choi
发明人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , Jae-Hui Choi
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , B01J4/002 , B01J10/00 , B01J19/2465 , B01J2219/0011 , Y02P20/582 , C07C47/02
摘要： The present invention relates to a method for preparing aldehydes by reacting olefins with a synthesis gas including carbon monoxide and hydrogen, and to an apparatus therefore. More particularly, the present invention relates to a method for preparing aldehydes, characterized by spraying and supplying olefins, synthesis gas including carbon monoxide and hydrogen, and a catalyst composition into an oxo reactor through a nozzle, and to an apparatus therefore. According to the present invention, the hydroformylation efficiency can be improved, thereby obtaining desirable aldehydes with a high yield.
摘要翻译： 本发明涉及一种通过使烯烃与包括一氧化碳和氢气在内的合成气反应制备醛的方法及其装置。 更具体地说，本发明涉及一种制备醛的方法，其特征在于通过喷嘴将催化剂组合物喷射并供给烯烃，包括一氧化碳和氢气的合成气，以及催化剂组合物装入氧代反应器，因此涉及一种设备。 根据本发明，可以提高加氢甲酰化效率，从而以高产率获得所需的醛。
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公开(公告)号：US20110135544A1
公开(公告)日：2011-06-09
申请号：US13007858
申请日：2011-01-17
申请人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , JAE-Hui Choi
发明人： Moo-Ho Hong , Dong-Hyun Ko , Sang-Oeb Na , Sung-Shik Eom , Sang-Gi Lee , O-Hark Kwon , Dae-Chul Kim , JAE-Hui Choi
IPC分类号： B01J10/00
CPC分类号： C07C45/50 , B01J4/002 , B01J10/00 , B01J19/2465 , B01J2219/0011 , Y02P20/582 , C07C47/02
摘要： The present invention relates to a method for preparing aldehydes by reacting olefins with a synthesis gas including carbon monoxide and hydrogen, and to an apparatus therefore. More particularly, the present invention relates to a method for preparing aldehydes, characterized by spraying and supplying olefins, synthesis gas including carbon monoxide and hydrogen, and a catalyst composition into an oxo reactor through a nozzle, and to an apparatus therefore. According to the present invention, the hydroformylation efficiency can be improved, thereby obtaining desirable aldehydes with a high yield.
摘要翻译： 本发明涉及一种通过使烯烃与包括一氧化碳和氢气在内的合成气反应制备醛的方法及其装置。 更具体地说，本发明涉及一种制备醛的方法，其特征在于通过喷嘴将催化剂组合物喷射并供给烯烃，包括一氧化碳和氢气的合成气，以及催化剂组合物装入氧代反应器，因此涉及一种设备。 根据本发明，可以提高加氢甲酰化效率，从而以高产率获得所需的醛。
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4.发明授权Phosphorus-containing catalyst composition and hydroformylation process using the same 有权含磷催化剂组合物和使用其的加氢甲酰化方法公开(公告)号：US08053605B2
公开(公告)日：2011-11-08
申请号：US12677496
申请日：2008-06-05
申请人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
发明人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
CPC分类号： B01J31/24 , B01J31/1875 , B01J31/20 , B01J31/2208 , B01J31/2291 , B01J31/2295 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845
摘要： The present invention relates to a catalyst composition that includes a triphenylphosphine ligand, a monodentate phosphine ligand, a monodentate phosphine oxide ligand, and a transition metal catalyst, and a hydroformylation process using the same. In the hydroformylation process using the catalyst composition according to the present invention, the high catalytic activity can be obtained, and the selectivity (N/I selectivity) in respects to normal- or iso-aldehyde can be desirably controlled.
摘要翻译： 本发明涉及包含三苯基膦配体，单齿膦配位体，单齿氧化膦配体和过渡金属催化剂的催化剂组合物，以及使用该催化剂组合物的加氢甲酰化方法。 在使用根据本发明的催化剂组合物的加氢甲酰化方法中，可以获得高催化活性，并且可以期望控制相对于正醛或异醛的选择性（N / I选择性）。
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5.发明申请PHOSPHORUS-CONTAINING CATALYST COMPOSITION AND HYDROFORMYLATION PROCESS USING THE SAME 有权含磷的催化剂组合物和使用相同的氢化方法公开(公告)号：US20100324339A1
公开(公告)日：2010-12-23
申请号：US12677496
申请日：2008-06-05
申请人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
发明人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Sang-Gi Lee , Moo-Ho Hong , O-Hark Kwon
CPC分类号： B01J31/24 , B01J31/1875 , B01J31/20 , B01J31/2208 , B01J31/2291 , B01J31/2295 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845
摘要： The present invention relates to a catalyst composition that includes a triphenylphosphine ligand, a monodentate phosphine ligand, a monodentate phosphine oxide ligand, and a transition metal catalyst, and a hydroformylation process using the same. In the hydroformylation process using the catalyst composition according to the present invention, the high catalytic activity can be obtained, and the selectivity (N/I selectivity) in respects to normal- or iso-aldehyde can be desirably controlled.
摘要翻译： 本发明涉及包含三苯基膦配体，单齿膦配位体，单齿氧化膦配体和过渡金属催化剂的催化剂组合物，以及使用该催化剂组合物的加氢甲酰化方法。 在使用根据本发明的催化剂组合物的加氢甲酰化方法中，可以获得高催化活性，并且可以期望控制相对于正醛或异醛的选择性（N / I选择性）。
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6.发明申请Catalyst Composition Including Phosphite Ligands and Hydroformylation Method Using the Same 有权包含亚磷酸酯配体的催化剂组合物及其加氢甲酰化方法公开(公告)号：US20100130792A1
公开(公告)日：2010-05-27
申请号：US12595074
申请日：2008-04-08
申请人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Ji-Joong Moon , Sang-Gi Lee , O-Hark Kwon
发明人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Ji-Joong Moon , Sang-Gi Lee , O-Hark Kwon
CPC分类号： C07C45/50 , C07C47/02 , C07C47/235
摘要： The present invention relates to a catalyst composition that includes a bis-phosphite ligand, a poly-phosphite ligand or a mono-phosphite ligand, and a transition metal catalyst, and a hydroformylation reaction using the same. The catalyst composition has the excellent catalytic activity, and the normal/iso (N/I) selectivity of aldehyde generated by the hydroformylation reaction using the same is increased.
摘要翻译： 本发明涉及包含双亚磷酸酯配体，聚亚磷酸酯配体或单亚磷酸酯配体和过渡金属催化剂的催化剂组合物，以及使用其的加氢甲酰化反应。 催化剂组合物具有优异的催化活性，并且通过使用其的加氢甲酰化反应产生的醛的正/异（N / I）选择性增加。
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7.发明授权Catalyst composition including phosphite ligands and hydroformylation method using the same 有权催化剂组合物包括亚磷酸酯配体和使用其的加氢甲酰化方法公开(公告)号：US07943801B2
公开(公告)日：2011-05-17
申请号：US12595074
申请日：2008-04-08
申请人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Ji-Joong Moon , Sang-Gi Lee , O-Hark Kwon
发明人： Jae-Hui Choi , Dong-Hyun Ko , Sung-Shik Eom , Ji-Joong Moon , Sang-Gi Lee , O-Hark Kwon
CPC分类号： C07C45/50 , C07C47/02 , C07C47/235
摘要： The present invention relates to a catalyst composition that includes a bis-phosphite ligand, a poly-phosphite ligand or a mono-phosphite ligand, and a transition metal catalyst, and a hydroformylation reaction using the same. The catalyst composition has the excellent catalytic activity, and the normal/iso (N/I) selectivity of aldehyde generated by the hydroformylation reaction using the same is increased.
摘要翻译： 本发明涉及包含双亚磷酸酯配体，聚亚磷酸酯配体或单亚磷酸酯配体和过渡金属催化剂的催化剂组合物，以及使用其的加氢甲酰化反应。 催化剂组合物具有优异的催化活性，通过加氢甲酰化反应产生的醛的正/异（N / I）选择性增加。
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公开(公告)号：US20140135533A1
公开(公告)日：2014-05-15
申请号：US14125886
申请日：2012-06-04
申请人： Dong-Hyun Ko , Sung-Shik Eom , Moo-Ho Hong , O-Hak Kwon , Jae-Hui Choi , Dae-Chul Kim
发明人： Dong-Hyun Ko , Sung-Shik Eom , Moo-Ho Hong , O-Hak Kwon , Jae-Hui Choi , Dae-Chul Kim
IPC分类号： C07C45/56
CPC分类号： C07C45/56 , B01J31/02 , B01J31/0208 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/222 , C07C49/20 , C07F9/65746 , C07C47/02
摘要： Disclosed is a hydroformylation method having improved catalyst stability in a reaction. Advantageously, provided is a hydroformylation method in which a specific α,β-unsaturated carbonyl compound is incorporated during a hydroformylation reaction to prevent alkyl phosphite decomposed from a phosphite ligand from acting as a catalyst poison, thereby improving a yield of reaction and inhibiting decomposition of ligand and catalyst.
摘要翻译： 公开了一种在反应中具有改善的催化剂稳定性的加氢甲酰化方法。 有利地，提供了加氢甲酰化方法，其中在加氢甲酰化反应期间引入特定的α，β-不饱和羰基化合物以防止从亚磷酸酯配体分解的亚磷酸烷基作为催化剂毒物，从而提高反应产率和抑制分解 的配体和催化剂。
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公开(公告)号：US08884071B2
公开(公告)日：2014-11-11
申请号：US14125886
申请日：2012-06-04
申请人： Dong-Hyun Ko , Sung-Shik Eom , Moo-Ho Hong , O-Hak Kwon , Jae-Hui Choi , Dae-Chul Kim
发明人： Dong-Hyun Ko , Sung-Shik Eom , Moo-Ho Hong , O-Hak Kwon , Jae-Hui Choi , Dae-Chul Kim
IPC分类号： C07C45/50 , C07C49/20 , C07C47/222 , C07F9/6574 , B01J31/02 , C07C45/56
CPC分类号： C07C45/56 , B01J31/02 , B01J31/0208 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/222 , C07C49/20 , C07F9/65746 , C07C47/02
摘要： Disclosed is a hydroformylation method having improved catalyst stability in a reaction. Advantageously, provided is a hydroformylation method in which a specific α,β-unsaturated carbonyl compound is incorporated during a hydroformylation reaction to prevent alkyl phosphite decomposed from a phosphite ligand from acting as a catalyst poison, thereby improving a yield of reaction and inhibiting decomposition of ligand and catalyst.
摘要翻译： 公开了一种在反应中具有改善的催化剂稳定性的加氢甲酰化方法。 有利地，提供了加氢甲酰化方法，其中在加氢甲酰化反应期间引入特定的α，β-不饱和羰基化合物以防止从亚磷酸酯配体分解的亚磷酸烷基作为催化剂毒物，从而提高反应产率和抑制分解 的配体和催化剂。
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公开(公告)号：US08673244B2
公开(公告)日：2014-03-18
申请号：US13121755
申请日：2011-03-30
申请人： Dong-Hyun Ko , Sung-Shik Eom , Yong-Jin Choe , Chan-Hong Lee , Moo-Ho Hong , O-Hak Kwon , Dae-Chul Kim , Jae-Hui Choi
发明人： Dong-Hyun Ko , Sung-Shik Eom , Yong-Jin Choe , Chan-Hong Lee , Moo-Ho Hong , O-Hak Kwon , Dae-Chul Kim , Jae-Hui Choi
CPC分类号： C07C29/141 , B01J23/72 , B01J25/02 , B01J31/20 , B01J31/2234 , B01J31/2404 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C31/125 , C07C47/02
摘要： The present invention relates to an apparatus for producing alcohols from olefins, comprising: a hydroformylation reactor wherein aldehydes are produced from olefins; a catalyst/aldehydes separator; a hydrogenation reactor wherein the aldehydes are hydrogenated to produce alcohols; and a distillation column. The hydroformylation reactor is equipped with a distributor plate, which has a broad contact surface for providing sufficient reaction area for reactants such as olefins and synthesis gas, and allows the reaction mixture to circulate and mix sufficiently, which contribute to excellent efficiency in terms of production of aldehydes. In addition, the hydrogenation reactor suppresses sub-reactions to improve the production yield of alcohols.
摘要翻译： 本发明涉及一种用于从烯烃生产醇的设备，包括：加氢甲酰化反应器，其中醛由烯烃生产; 催化剂/醛分离器; 氢化反应器，其中醛被氢化以产生醇; 和蒸馏塔。 加氢甲酰化反应器配备有分布板，其具有宽的接触表面，用于为反应物例如烯烃和合成气提供足够的反应面积，并允许反应混合物充分循环和混合，这有助于在生产方面优异的效率 的醛。 此外，氢化反应器抑制副反应以提高醇的产率。
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