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1.发明授权Coated steel sheet comprising a composite coat containing compounded resin particles 有权涂覆钢板包括含有复合树脂颗粒的复合涂层公开(公告)号：US08241742B2
公开(公告)日：2012-08-14
申请号：US12303191
申请日：2006-06-15
申请人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B5/16 , B32B15/18 , B32B15/095
CPC分类号： C09D123/0869 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/44 , C08G18/6662 , C08G18/758 , C08G2150/90 , C08L2666/20 , C09D123/04 , C09D175/04 , C09J123/0869 , C23C26/00 , C23C30/00 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/26 , Y10T428/273 , C08G18/3893 , C08L91/06 , C08L2666/04 , C08G18/3231
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as tape peeling resistance, solvent resistance, alkali resistance and abrasion resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat comprises a compounded resin (A) in which polyurethane resin particles (A-1) and ethylene-unsaturated carboxylic acid copolymerization resin particles (A-2), respectively having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl, group, are contained in a mass ratio of 20:80 to 90:10 and silicon oxide particles (A-3) having an average particle diameter of 5 to 20 nm and an organic titanium compound (A-4) are compounded, polyolefin wax particles (B) having an average particle diameter of 0.5 to 4 μm and a softening point of 100 to 140° C., and silicon oxide particles (C) having an average particle diameter of 70 to 200 nm, and wherein an amount of a coat of said composite coat is 0.5 to 3 g/cm2.
摘要翻译： 本发明的目的是提供一种涂层钢板，其性能如带剥离性，耐溶剂性，耐碱性和耐磨性得到改善。 涂覆有复合涂层的涂覆钢板，其中所述复合涂层包括其中分别具有平均值的聚氨酯树脂颗粒（A-1）和乙烯 - 不饱和羧酸共聚树脂颗粒（A-2）的复合树脂（A） 20〜100nm的粒径和硅烷醇基和/或烷氧基甲硅烷基，以20:80〜90:10的质量比包含，平均粒径为5〜3的氧化硅粒子（A-3） 20nm的有机钛化合物（A-4），平均粒径为0.5〜4μm，软化点为100〜140℃的聚烯烃蜡粒子（B）和氧化硅粒子（C） 平均粒径为70〜200nm，所述复合涂层的涂层量为0.5〜3g / cm 2。
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公开(公告)号：US20100233469A1
公开(公告)日：2010-09-16
申请号：US12303191
申请日：2006-06-15
申请人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Motohiro Sasaki , Junpei Karoji , Koichi Saito , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B5/16 , B32B15/06 , B32B15/095 , B32B15/18
CPC分类号： C09D123/0869 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/44 , C08G18/6662 , C08G18/758 , C08G2150/90 , C08L2666/20 , C09D123/04 , C09D175/04 , C09J123/0869 , C23C26/00 , C23C30/00 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/26 , Y10T428/273 , C08G18/3893 , C08L91/06 , C08L2666/04 , C08G18/3231
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as tape peeling resistance, solvent resistance, alkali resistance and abrasion resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat comprises a compounded resin (A) in which polyurethane resin particles (A-1) and ethylene-unsaturated carboxylic acid copolymerization resin particles (A-2), respectively having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl, group, are contained in a mass ratio of 20:80 to 90:10 and silicon oxide particles (A-3) having an average particle diameter of 5 to 20 nm and an organic titanium compound (A-4) are compounded, polyolefin wax particles (B) having an average particle diameter of 0.5 to 4 μm and a softening point of 100 to 140° C., and silicon oxide particles (C) having an average particle diameter of 70 to 200 nm, and wherein an amount of a coat of said composite coat is 0.5 to 3 g/cm2.
摘要翻译： 本发明的目的是提供一种涂层钢板，其性能如带剥离性，耐溶剂性，耐碱性和耐磨性得到改善。 涂覆有复合涂层的涂覆钢板，其中所述复合涂层包括其中分别具有平均值的聚氨酯树脂颗粒（A-1）和乙烯 - 不饱和羧酸共聚树脂颗粒（A-2）的复合树脂（A） 20〜100nm的粒径和硅烷醇基和/或烷氧基甲硅烷基，以20:80〜90:10的质量比包含，平均粒径为5〜3的氧化硅粒子（A-3） 20nm的有机钛化合物（A-4），平均粒径为0.5〜4μm，软化点为100〜140℃的聚烯烃蜡粒子（B）和氧化硅粒子（C） 平均粒径为70〜200nm，所述复合涂层的涂层量为0.5〜3g / cm 2。
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公开(公告)号：US07476445B2
公开(公告)日：2009-01-13
申请号：US11540507
申请日：2006-10-02
申请人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B15/082 , B32B15/085 , B32B15/092 , B32B15/095 , B32B27/18
CPC分类号： C23C26/00 , C09D5/084 , C23C30/00 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692
摘要： It is an object of the present invention to provide an organic coating-treated metal sheet, having a coat capable of satisfying all the corrosion resistance, alkali resistance, solvent resistance, anti-scratch property and adhesion requirements which the conventional nonchromate type coating technologies have been difficult to meet. A surface-treated metal sheet with a coat comprising 50; to 90% by weight of a crosslinked resin matrix (A) and 10 to 50% by weight of an inorganic rust preventive (B) as formed on the metal sheet surface, wherein the crosslinked resin matrix (A) is formed by the reaction between a water-borne resin and a crosslinking agent and has an acid value of 0 to 30 due to carboxylic acid groups not neutralized by an alkali metal and a hydroxyl value of 5 to 50.
摘要翻译： 本发明的目的是提供一种有机涂层处理的金属片，其具有能够满足常规非铬酸盐型涂覆技术具有的所有耐腐蚀性，耐碱性，耐溶剂性，抗划伤性和粘附要求的涂层 很难见面。 具有包含50的涂层的表面处理金属片; 至90重量％的交联树脂基体（A）和10〜50重量％的形成在金属板表面上的无机防锈剂（B），其中交联树脂基质（A）通过 水性树脂和交联剂，并且由于未被碱金属中和且羟值为5〜50的羧酸基，其酸值为0〜30。
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公开(公告)号：US20080081196A1
公开(公告)日：2008-04-03
申请号：US11540507
申请日：2006-10-02
申请人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
发明人： Koichi Saito , Motohiro Sasaki , Atsushi Morishita , Akira Takahashi , Hiroshi Kanai , Masahiro Fuda
IPC分类号： B32B15/08 , B32B27/18 , B32B15/085 , B32B15/09 , B32B15/092 , B32B15/095
CPC分类号： C23C26/00 , C09D5/084 , C23C30/00 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692
摘要： It is an object of the present invention to provide an organic coating-treated metal sheet, having a coat capable of satisfying all the corrosion resistance, alkali resistance, solvent resistance, anti-scratch property and adhesion requirements which the conventional nonchromate type coating technologies have been difficult to meet.A surface-treated metal sheet with a coat comprising 50 to 90% by weight of a crosslinked resin matrix (A) and 10 to 50% by weight of an inorganic rust preventive (B) as formed on the metal sheet surface,wherein the crosslinked resin matrix (A) is formed by the reaction between a water-borne resin and a crosslinking agent and has an acid value of 0 to 30 due to carboxylic acid groups not neutralized by an alkali metal and a hydroxyl value of 5 to 50.
摘要翻译： 本发明的目的是提供一种有机涂层处理的金属片，其具有能够满足常规非铬酸盐型涂覆技术具有的所有耐腐蚀性，耐碱性，耐溶剂性，抗划伤性和粘附要求的涂层 很难见面。 一种表面处理金属片，其具有在金属片表面上形成的包含交联树脂基体（A）50至90重量％和10至50重量％的无机防锈剂（B）的涂层，其中交联 树脂基体（A）是由水性树脂与交联剂的反应形成的，由于未被碱金属中和且羟值为5〜50的羧酸基，酸值为0〜30。
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公开(公告)号：US08349446B2
公开(公告)日：2013-01-08
申请号：US12303195
申请日：2006-06-15
CPC分类号： C09D123/0853 , C08K3/36 , C08K5/0091 , C09J123/0869 , Y10T428/254
摘要： A coated steel sheet coated with a composite coat, wherein said composite coat is a coat formed by compounding ethylene-unsaturated carboxylic acid copolymerization resin particles (A) having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl group, silicon oxide particles (B) having an average particle diameter of 5 to 50 nm and an organic titanium compound (C), and wherein an amount of a coat of said composite coat is 0.5 to 3 g/m2.
摘要翻译： 涂覆有复合涂层的涂覆钢板，其中所述复合涂层是通过将平均粒径为20-100nm的乙烯 - 不饱和羧酸共聚树脂颗粒（A）与硅烷醇基和/或烷氧基甲硅烷基 基团，平均粒径为5〜50nm的氧化硅粒子（B）和有机钛化合物（C），其中所述复合涂层的涂层量为0.5〜3g / m 2。
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公开(公告)号：US20100233470A1
公开(公告)日：2010-09-16
申请号：US12303195
申请日：2006-06-15
CPC分类号： C09D123/0853 , C08K3/36 , C08K5/0091 , C09J123/0869 , Y10T428/254
摘要： It is an object of the present invention to provide a coated steel sheet, properties of which such as an adhesion property to a substrate and press oil resistance are improved.A coated steel sheet coated with a composite coat, wherein said composite coat is a coat formed by compounding ethylene-unsaturated carboxylic acid copolymerization resin particles (A) having an average particle diameter of 20 to 100 nm and a silanol group and/or an alkoxysilyl group, silicon oxide particles (B) having an average particle diameter of 5 to 50 nm and an organic titanium compound (C), and wherein an amount of a coat of said composite coat is 0.5 to 3 g/m2.
摘要翻译： 本发明的目的是提供一种涂层钢板，其特性如对基材的粘合性能和耐压油性提高。 涂覆有复合涂层的涂覆钢板，其中所述复合涂层是通过将平均粒径为20-100nm的乙烯 - 不饱和羧酸共聚树脂颗粒（A）与硅烷醇基和/或烷氧基甲硅烷基 基团，平均粒径为5〜50nm的氧化硅粒子（B）和有机钛化合物（C），其中所述复合涂层的涂层量为0.5〜3g / m 2。
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公开(公告)号：US08034456B2
公开(公告)日：2011-10-11
申请号：US12308538
申请日：2007-06-22
IPC分类号： B32B15/095 , C08L83/08
CPC分类号： C09D175/12 , C08G18/0823 , C08G18/12 , C08G18/4238 , C08G18/44 , C08G18/6659 , C08G18/758 , C08G2150/90 , C09D5/08 , C09D175/06 , C23C26/00 , C23C30/00 , Y10T428/31605 , C08G18/3231 , C08G18/289 , C08L2666/06
摘要： The present invention provides a surface-treated metal material having a film formed on at least a portion of a surface of a metal material, the film containing at least polyurethane resin and silicon oxide, and a metal surface treatment agent used to obtain the surface-treated metal material. The polyurethane resin contains one or more of siloxane bond, dehydration-condensation bond of silanol group and different functional group, and silanol moiety, and urea bond. The sum of the siloxane bond, the dehydration-condensation bond of silanol group and different functional group, total amount of the silanol moiety, and the silicon oxide falls within a range of equal to or more than 1.6 wt % to equal to or less than 25 wt % for solids of the film. The ratio of the total amount of urea bond and urethane bond to the total amount of resin components falls within a range of equal to or more than 0.1 wt % to equal to or less than 10 wt %.
摘要翻译： 本发明提供了一种表面处理的金属材料，其具有形成在金属材料表面的至少一部分上的膜，所述膜至少含有聚氨酯树脂和氧化硅，以及用于获得表面处理金属的金属表面处理剂， 处理过的金属材料。 聚氨酯树脂含有一个或多个硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，以及硅烷醇部分和脲键。 硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，硅烷醇部分的总量和氧化硅的总和在1.6重量％以上的范围内，等于或小于 对于固体膜为25重量％。 脲键和氨基甲酸酯键的总量与树脂组分的总量的比例落入等于或大于0.1重量％至等于或小于10重量％的范围内。
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公开(公告)号：US20100233490A1
公开(公告)日：2010-09-16
申请号：US12308538
申请日：2007-06-22
IPC分类号： B32B15/095 , C08L83/08 , C04B24/22 , C08K3/32
CPC分类号： C09D175/12 , C08G18/0823 , C08G18/12 , C08G18/4238 , C08G18/44 , C08G18/6659 , C08G18/758 , C08G2150/90 , C09D5/08 , C09D175/06 , C23C26/00 , C23C30/00 , Y10T428/31605 , C08G18/3231 , C08G18/289 , C08L2666/06
摘要： The present invention provides a surface-treated metal material having a film formed on at least a portion of a surface of a metal material, the film containing at least polyurethane resin and silicon oxide, and a metal surface treatment agent used to obtain the surface-treated metal material. The polyurethane resin contains one or more of siloxane bond, dehydration-condensation bond of silanol group and different functional group, and silanol moiety, and urea bond. The sum of the siloxane bond, the dehydration-condensation bond of silanol group and different functional group, total amount of the silanol moiety, and the silicon oxide falls within a range of equal to or more than 1.6 wt % to equal to or less than 25 wt % for solids of the film. The ratio of the total amount of urea bond and urethane bond to the total amount of resin components falls within a range of equal to or more than 0.1 wt % to equal to or less than 10 wt %.
摘要翻译： 本发明提供了一种表面处理的金属材料，其具有形成在金属材料表面的至少一部分上的膜，所述膜至少含有聚氨酯树脂和氧化硅，以及用于获得表面处理金属的金属表面处理剂， 处理过的金属材料。 聚氨酯树脂含有一个或多个硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，以及硅烷醇部分和脲键。 硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，硅烷醇部分的总量和氧化硅的总和在1.6重量％以上的范围内，等于或小于 对于固体膜为25重量％。 脲键和氨基甲酸酯键的总量与树脂组分的总量的比例落入等于或大于0.1重量％至等于或小于10重量％的范围内。
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公开(公告)号：US20050025991A1
公开(公告)日：2005-02-03
申请号：US10874754
申请日：2004-06-24
申请人： Kiyokazu Ishizuka , Hidetoshi Shindo , Atsushi Morishita , Koichi Saito , Motohiro Sasaki , Atsuhiko Tounaka
发明人： Kiyokazu Ishizuka , Hidetoshi Shindo , Atsushi Morishita , Koichi Saito , Motohiro Sasaki , Atsuhiko Tounaka
CPC分类号： B05D7/51 , C09D5/082 , C23C22/83 , C23C28/00 , C23C28/3225 , C23C28/345 , Y10T428/12569 , Y10T428/12799 , Y10T428/12951 , Y10T428/31678 , Y10T428/31692
摘要： The present invention provides an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any chromium and which is excellent in corrosion resistance after degreasing, coating adhesion and electrodeposition coating performance. The inorganic-organic composite-treated zinc-plated steel sheet, which is obtained by forming a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and forming thereon a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, by using a post-treatment composition containing at least one compound (A) selected from the group consisting of thiocarbonyl group-containing compounds, sulfide group-containing compounds and guanidyl group-containing compounds, an organic resin (B), a crosslinking agent (C) and an inorganic corrosion inhibitor (D).
摘要翻译： 本发明提供了一种无机 - 有机复合处理的镀锌钢板，其经处理的涂层不含任何铬，并且在脱脂，涂层粘附性和电沉积涂布性能之后具有优异的耐腐蚀性。 通过在镀锌钢板表面上以0.3〜5g / m 2的涂布量形成磷酸锌被膜而得到的无机 - 有机复合处理镀锌钢板，并在其上形成 通过使用含有至少一种选自含硫代羰基的化合物，硫化物基团的化合物（A）的后处理组合物，涂覆重量为0.01〜1g / m 2的后处理涂布， 含有化合物和含胍基的化合物，有机树脂（B），交联剂（C）和无机缓蚀剂（D）。
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公开(公告)号：US07029762B2
公开(公告)日：2006-04-18
申请号：US10874754
申请日：2004-06-24
申请人： Kiyokazu Ishizuka , Hidetoshi Shindo , Atsushi Morishita , Koichi Saito , Motohiro Sasaki , Atsuhiko Tounaka
发明人： Kiyokazu Ishizuka , Hidetoshi Shindo , Atsushi Morishita , Koichi Saito , Motohiro Sasaki , Atsuhiko Tounaka
CPC分类号： B05D7/51 , C09D5/082 , C23C22/83 , C23C28/00 , C23C28/3225 , C23C28/345 , Y10T428/12569 , Y10T428/12799 , Y10T428/12951 , Y10T428/31678 , Y10T428/31692
摘要： The present invention provides an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any chromium and which is excellent in corrosion resistance after degreasing, coating adhesion and electrodeposition coating performance.The inorganic-organic composite-treated zinc-plated steel sheet, which is obtained by forming a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and forming thereon a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, by using a post-treatment composition containing at least one compound (A) selected from the group consisting of thiocarbonyl group-containing compounds, sulfide group-containing compounds and guanidyl group-containing compounds, an organic resin (B), a crosslinking agent (C) and an inorganic corrosion inhibitor (D).
摘要翻译： 本发明提供了一种无机 - 有机复合处理的镀锌钢板，其经处理的涂层不含任何铬，并且在脱脂，涂层粘附性和电沉积涂布性能之后具有优异的耐腐蚀性。 通过在镀锌钢板上以0.3〜5g / m 2的涂布量形成磷酸锌被膜而得到的无机 - 有机复合处理的镀锌钢板 通过使用含有至少一种选自下组的化合物（A）的后处理组合物，其表面和其上形成后处理涂层，涂层重量为0.01至1g / m 2， 含硫基羰基化合物，含硫化物基化合物和含胍基的化合物，有机树脂（B），交联剂（C）和无机缓蚀剂（D）。
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