摘要:
A thermosetting resin of a norbornene monomer is prepared by bulk-polymerizing a norbornene monomer in a mold in the presence of a metathesis catalyst system and further in the presence of a dicyclopentadiene heat-polymerized resin in an amount of 15 to 150 parts by weight per 100 parts by weight of the monomer.
摘要:
This invention relates to a composite molded article where a polymer film of superior weather resistance, adhesion and surface smoothness is made into an integral composite body on the surface of polynorbornene base material by utilizing reaction injection molding in combination with an in-mold coating process. By means of this invention, it is possible to manufacture three dimensional composite molded articles, composite molded articles of complex shapes and deep-drawn composite molded articles. The composite molded articles of this invention can be used for a variety of purposes, such as automobile parts, electrical parts, construction, etc.
摘要:
A silicon carbide-silicon carbide fiber composite consists of silicon carbide particles and silicon carbide fibers. The composite has excellent oxidation resistance and finds a wide range of application as heat resistant material. The silicon carbide conversion method is simple and consistent enough to ensure production of silicon carbide-silicon carbide fiber composites with minimized variation in quality.
摘要:
Particulate silica is prepared by feeding a gas mixture of an organohalosilane gas, a flammable gas capable of generating water vapor when burned, and a free oxygen-containing gas to a reaction chamber through a multiple-tube burner, whereby the organohalosilane is subjected to flame hydrolysis and oxidation reaction. The amount of the flammable gas fed is 0.5-9 mol per mol of the organohalosilane and such that the amount of water vapor resulting from combustion of the flammable gas is 1-6 times the stoichiometric amount, and the gas mixture is fed to the center tube of the burner such that it may have a linear velocity at the outlet of 50-120 m/sec, calculated in the standard state. The resulting silica has a surface area of 100-400 m2/g and a narrow particle size distribution of primary particles and ensures the transparency of silicone rubber filled therewith.
摘要:
In an industrial process for preparing organohalosilanes by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst, a contact mass composed of the metallic silicon and the catalyst further contains an effective amount of a phosphonium compound having on the molecule at least one group of the formula: [R2R3R4P—]+Y− wherein R2, R3 and R4 each are a monovalent hydrocarbon group and Y is a halogen atom or acid group. The invention drastically increases the silane formation rate and the utilization of silicon without lowering the selectivity of useful silane.
摘要:
Hydrophobic silica fine powder is produced by pyrolyzing a silane compound to form a silica fine powder and hydrophobizing the silica fine powder with an organohalosilane as hydrophobizing agent in a fluidization vessel. A portion of the silica fine powder is bypassed to a waste gas line from the fluidization vessel and collected with a cyclone and bag filter, and the collected powder is fed to the fluidization vessel where it is hydrophobized. The amount of unreacted organohalosilane in the waste gases is reduced, alleviating the burden on waste gas treatment. The silica having the unreacted organohalosilane borne thereon is fed back to the fluidization vessel, increasing the reaction efficiency of organohalosilane.
摘要:
Organohalosilanes are prepared by the Rochow process of reacting metallic silicon particles with an organohalide in the presence of a copper catalyst. The metallic silicon particles, which are prepared by committing fragments of metallic silicon raw material, have a mean particle size of 10 &mgr;m to 10 mm and a surface oxygen quantity of at least 0.05 wt % and/or at least 0.001 g of oxygen/m2 of silicon surface area, which is given as the difference between the oxygen concentrations determined by in-metal oxygen analysis of the metallic silicon particles and the fragments, respectively. On analysis, the metallic silicon particles have been held for at least 3 hours in an air atmosphere at 25° C. and RH 55%
摘要翻译:有机卤代硅烷通过在铜催化剂存在下使金属硅颗粒与有机卤化物反应的Rochow方法制备。 通过制造金属硅原料的碎片而制备的金属硅颗粒的平均粒径为10〜10μm,表面氧量为0.05重量%以上,和/或至少为0.001克氧/ m 2 的硅表面积,其分别由金属硅颗粒和片段的金属间氧分析确定的氧浓度之差给出。 经分析,金属硅颗粒在空气气氛中在25℃下保持至少3小时,RH为55%
摘要:
A contact mass for use in the synthesis of organohalosilanes is prepared by adding metallic copper particles to metallic silicon particles, and rubbing the particles against each other under high shear forces in a non-oxidizing atmosphere, thereby forming a metallic copper thin film on the surface of the metallic silicon particles in a spot pattern or entirely. The contact mass is capable of reducing the time required for activation and has an extended lifetime.
摘要:
A process to prevent scale adhesion on rector surfaces when polymerizing vinyl esters, vinyl esthers, carboxylic acids, styrene or diene monomers. Coating of internal reactor surfaces with a combination of an amino containing aromatic compound, and an alkali metal or ammonium salt of polyvinylsulfuric acid results in the scale prevention. This combination is applied to reactor surfaces via its mixture with a solvent and is subsequently dried to form the coating.
摘要:
A method of preventing polymer scale deposition during polymerization of a monomer having an ethylenically double bond in a polymerization vessel, comprising the step of carrying out said polymerization in a polymerization vessel of which the inner wall surface has a coating comprising:(A) a lignin, and(B) a cellulose derivative; and a polymer scale preventive agent comprising said components (A) and (B).Deposition of polymer scale can be effectively prevented; polymers with high whiteness can be prepared; the scale preventive agent used has no poisonousness and are highly safe, therefore this method can be performed with high safe.