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公开(公告)号：US20110027848A1
公开(公告)日：2011-02-03
申请号：US12840913
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US20130001095A1
公开(公告)日：2013-01-03
申请号：US13612192
申请日：2012-09-12
IPC分类号： C25B3/04
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products. The method involves obtaining a sodium salt of a carboxylic acid. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane) that separates an anolyte compartment housing the anolyte from a catholyte compartment housing a catholyte. The anolyte includes a first solvent or mixture of solvents and a quantity of the sodium salt of the carboxylic acid. When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译： 一种产生偶联产物的方法。 该方法包括获得羧酸的钠盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱性离子传导膜（例如NaSICON膜），其将容纳阴极电解液的阳极电解液室与容纳阴极电解液的阴极电解液室隔开。 阳极电解液包括第一溶剂或溶剂的混合物和一定量的羧酸的钠盐。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。
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公开(公告)号：US08647492B2
公开(公告)日：2014-02-11
申请号：US12840913
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US08506789B2
公开(公告)日：2013-08-13
申请号：US12840508
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US20110168569A1
公开(公告)日：2011-07-14
申请号：US12840508
申请日：2010-07-21
IPC分类号： C25B3/10
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US20110024288A1
公开(公告)日：2011-02-03
申请号：US12840401
申请日：2010-07-21
IPC分类号： C25B9/00
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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