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公开(公告)号：US20130001095A1
公开(公告)日：2013-01-03
申请号：US13612192
申请日：2012-09-12
IPC分类号： C25B3/04
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products. The method involves obtaining a sodium salt of a carboxylic acid. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane) that separates an anolyte compartment housing the anolyte from a catholyte compartment housing a catholyte. The anolyte includes a first solvent or mixture of solvents and a quantity of the sodium salt of the carboxylic acid. When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译： 一种产生偶联产物的方法。 该方法包括获得羧酸的钠盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱性离子传导膜（例如NaSICON膜），其将容纳阴极电解液的阳极电解液室与容纳阴极电解液的阴极电解液室隔开。 阳极电解液包括第一溶剂或溶剂的混合物和一定量的羧酸的钠盐。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。
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公开(公告)号：US08506789B2
公开(公告)日：2013-08-13
申请号：US12840508
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US08647492B2
公开(公告)日：2014-02-11
申请号：US12840913
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US20120304530A1
公开(公告)日：2012-12-06
申请号：US13479057
申请日：2012-05-23
申请人： Pallavi Chitta , Mukund Karanjikar
发明人： Pallavi Chitta , Mukund Karanjikar
IPC分类号： C10L1/18 , B01J23/74 , B01J23/75 , B01J21/00 , B01J23/755
CPC分类号： B01J23/83 , B01J21/08 , B01J23/70 , B01J23/72 , B01J35/023 , B01J35/1014 , B01J37/0036 , B01J37/0201 , B01J37/04 , C10G3/44 , C10G3/49 , C10G3/52 , C10L1/18 , Y02P30/20
摘要： A method for upgrading pyrolysis oil into a hydrocarbon fuel involves obtaining a quantity of pyrolysis oil, separating the pyrolysis oil into an organic phase and an aqueous phase, and then upgrading the organic phase into a hydrocarbon fuel by reacting the organic phase with hydrogen gas using a catalyst. The catalyst used in the reaction includes a support material, an active metal and a zirconia promoter material. The support material may be alumina, silica gel, carbon, silicalite or a zeolite material. The active metal may be copper, iron, nickel or cobalt. The zirconia promoter material may be zirconia itself, zirconia doped with Y, zirconia doped with Sc and zirconia doped with Yb.
摘要翻译： 将热解油升级为烃燃料的方法包括获得一定量的热解油，将热解油分离成有机相和水相，然后通过有机相与氢气反应将有机相转化为烃燃料，使用 催化剂 用于反应的催化剂包括载体材料，活性金属和氧化锆促进剂材料。 载体材料可以是氧化铝，硅胶，碳，硅沸石或沸石材料。 活性金属可以是铜，铁，镍或钴。 氧化锆促进剂材料可以是氧化锆本身，掺杂有Y的氧化锆，掺杂有Sc的氧化锆和用Yb掺杂的氧化锆。
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公开(公告)号：US20110027848A1
公开(公告)日：2011-02-03
申请号：US12840913
申请日：2010-07-21
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US09051656B2
公开(公告)日：2015-06-09
申请号：US13092685
申请日：2011-04-22
申请人： Sai Bhavaraju , Mukund Karanjikar , Pallavi Chitta
发明人： Sai Bhavaraju , Mukund Karanjikar , Pallavi Chitta
摘要： An aryl-alkyl (R—Ar) hydrocarbon is prepared by an electrosynthesis process in an electrolytic cell having an alkali ion conductive membrane positioned between an anolyte compartment configured with an anode and a catholyte compartment configured with a cathode. An anolyte solution containing an alkali metal salt of an alkyl carboxylic acid and an aryl compound is introduced into the anolyte compartment. The aryl compound may include an alkali metal salt of an aryl carboxylic acid, an arene (aromatic) hydrocarbon, or an aryl alkali metal adduct (Ar−M+). The anolyte solution undergoes electrolytic decarboxylation to form an alkyl radical. The alkyl radical reacts with the aryl compound to produce the aryl-alkyl hydrocarbon.
摘要翻译： 通过电解槽法制备芳基 - 烷基（R-Ar）烃，该电解槽具有位于由阳极构成的阳极电解室与构成阴极的阴极电解室之间的碱离子导电膜。 将含有烷基羧酸和芳基化合物的碱金属盐的阳极电解液引入阳极电解液室。 芳基化合物可以包括芳基羧酸的碱金属盐，芳烃（芳族）烃或芳基碱金属加合物（Ar-M +）。 阳极电解液经历电解脱羧以形成烷基。 烷基与芳基化合物反应生成芳基 - 烷基烃。
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公开(公告)号：US20110168569A1
公开(公告)日：2011-07-14
申请号：US12840508
申请日：2010-07-21
IPC分类号： C25B3/10
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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公开(公告)号：US20110024288A1
公开(公告)日：2011-02-03
申请号：US12840401
申请日：2010-07-21
IPC分类号： C25B9/00
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This material may be a carboxylic acid, an ester of a carboxylic acid, a triglyceride of a carboxylic acid, or a metal salt of a carboxylic acid, or any other fatty acid derivative. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译： 从生物质产生偶联的自由基产物的方法。 该方法包括从生物质获得脂质或羧酸物质。 该材料可以是羧酸，羧酸的酯，羧酸的甘油三酸酯，或羧酸的金属盐，或任何其它的脂肪酸衍生物。 将该脂质物质或羧酸物质转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。
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