公开(公告)号：US4225398A

公开(公告)日：1980-09-30

申请号：US889443

申请日：1978-03-23

申请人： Mutsuo Hasegawa ,  Hatsuo Hirono ,  Katsuyuki Nagata ,  Shinji Hayashi ,  Hiroshi Yamagata

发明人： Mutsuo Hasegawa ,  Hatsuo Hirono ,  Katsuyuki Nagata ,  Shinji Hayashi ,  Hiroshi Yamagata

IPC分类号： B05D7/14 ,  C25D11/18 ,  C25D11/24 ,  C25D11/20 ,  C25D11/22

CPC分类号： B05D7/14 ,  C25D11/18 ,  C25D11/246

摘要： The corrosion resistance of an anodically oxidized surface film on aluminum articles is improved by sealing micropores and the like in such surface film with an aqueous sealing solution or dispersion containing siliceous material, such as silicic acid or a silicate, therein and thereafter overcoating the so-sealed surface with a select coating composition. The aqueous sealing solution is brought into contact with the aluminum article, such as by dipping the article into the solution and drying the so-coated article. Optionally, an electrical voltage may be applied through the sealing liquid and through the aluminum article during the sealing process. Further, in certain embodiments an electrical voltage may be applied through the sealing liquid before the liquid contacts the aluminum article. If desired, the surface of the aluminum article may be colored prior to sealing.

摘要翻译： 在铝制品上的阳极氧化的表面膜的耐腐蚀性通过用含有硅质或硅酸盐等硅质材料的水性密封溶液或分散体密封这种表面膜中的微孔等来改善， 密封表面与选择涂料组合物。 使水性密封溶液与铝制品接触，例如通过将制品浸入溶液中并干燥如此涂覆的制品。 可选地，可以在密封过程期间通过密封液体并通过铝制品施加电压。 此外，在某些实施例中，在液体接触铝制品之前，可以通过密封液体施加电压。 如果需要，铝制品的表面可以在密封之前着色。

公开(公告)号：US4042471A

公开(公告)日：1977-08-16

申请号：US663551

申请日：1976-03-03

申请人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Katsuyuki Nagata

发明人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Katsuyuki Nagata

IPC分类号： C25D11/22

CPC分类号： C25D11/22

摘要： Aluminum or aluminum alloy is first anodized to form an oxide film thereon. With the pores in this oxide film unsealed, the basis metal is then electrolyzed in an electrolytic solution containing at least two metallic salts and a strongly reducing compound, by use of alternating current at potentials not more than about 15 volts.

摘要翻译： 铝或铝合金首先被阳极化以在其上形成氧化膜。 随着该氧化膜中的孔未密封，然后通过使用电压不超过约15伏的交流电，在含有至少两种金属盐和强还原性化合物的电解液中电解基础金属。

公开(公告)号：US4070255A

公开(公告)日：1978-01-24

申请号：US663568

申请日：1976-03-03

申请人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Katsuyuki Nagata

发明人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Katsuyuki Nagata

IPC分类号： C25D11/22

CPC分类号： C25D11/22

摘要： Aluminum or aluminum alloy is first anodized to form an oxide film thereon. With the pores in this oxide film unsealed, the basis metal is then electrolyzed by use of alternating current at a preselected starting voltage, and this voltage is lowered at least once before completion of the electrolytic coloring of the basis metal. The electrolytic solution in which the electrolysis is effected contains either at least three metallic salts or at least two metallic salts and a strong reducing compound.

摘要翻译： 铝或铝合金首先被阳极化以在其上形成氧化膜。 在该氧化物膜中的孔未密封的情况下，通过在预先选择的起始电压下使用交流电，对基础金属进行电解，该电压在基础金属的电解着色完成之前至少降低一次。 进行电解的电解液含有至少三种金属盐或至少两种金属盐和强还原性化合物。

公开(公告)号：US4042468A

公开(公告)日：1977-08-16

申请号：US663561

申请日：1976-03-03

申请人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Shinji Hayashi

发明人： Mutsuo Hasegawa ,  Kazuo Aikawa ,  Shinji Hayashi

IPC分类号： C25D11/14 ,  C25D11/22

CPC分类号： C25D11/22 ,  C25D11/14

摘要： Aluminum or aluminum alloy is first anodized to form an oxide film thereon. Before being colored electrolytically in an electrolytic solution, the anodized basis metal is made anodic in this solution, and direct current is passed therethrough. The basis metal is then electrolyzed in the same solution by use of alternating current for actual coloring operation. The electrolytic solution in use contains at least two metallic salts, together with or without a strongly reducing compound.

摘要翻译： 铝或铝合金首先被阳极化以在其上形成氧化膜。 在电解液中电解着色之前，在该溶液中阳极氧化的基底金属被制成阳极，直流电流通过。 然后通过使用用于实际着色操作的交流电在相同的溶液中电解基础金属。 使用的电解液含有至少两种金属盐，连同或不具有强还原性化合物。

公开(公告)号：US4042469A

公开(公告)日：1977-08-16

申请号：US663625

申请日：1976-03-03

申请人： Mutsuo Hasegawa ,  Toshikazu Imaoka ,  Kazuo Aikawa

发明人： Mutsuo Hasegawa ,  Toshikazu Imaoka ,  Kazuo Aikawa

IPC分类号： C25D11/22

CPC分类号： C25D11/22

摘要： Aluminum or aluminum alloy is first anodized to form an oxide film thereon. The anodized basis metal is electrolyzed by use of alternating current in an electrolytic solution which is prepared by adding formaldehyde, usually as formalin, and a thiosulfate to an acid solution of stannous sulfate. The acid solution of stannous sulfate can be prepared by dissolving stannous sulfate in an aqueous solution of sulfuric acid, sulfamic acid, tartaric acid or the like.

摘要翻译： 铝或铝合金首先被阳极化以在其上形成氧化膜。 阳极氧化的基础金属通过在电解液中使用交流电进行电解，电解液通过将甲醛（通常作为福尔马林）和硫代硫酸盐加入到硫酸亚锡的酸溶液中制备。 硫酸亚锡的酸溶液可以通过将硫酸亚锡溶解在硫酸，氨基磺酸，酒石酸等的水溶液中来制备。

公开(公告)号：US4115607A

公开(公告)日：1978-09-19

申请号：US780427

申请日：1977-03-23

申请人： Mutsuo Hasegawa ,  Sunichi Segawa ,  Yuji Koise ,  Hisao Okada ,  Shiro Gomyo ,  Yoshiaki Kudo

发明人： Mutsuo Hasegawa ,  Sunichi Segawa ,  Yuji Koise ,  Hisao Okada ,  Shiro Gomyo ,  Yoshiaki Kudo

IPC分类号： B05D7/14 ,  C08L83/00 ,  C08L83/04 ,  C09D5/20 ,  C09D183/00 ,  C09D183/04 ,  C23F17/00

CPC分类号： B05D7/14 ,  B21C29/006 ,  C09D183/04 ,  Y10T29/49984 ,  Y10T29/49988

摘要： Shaped aluminum bars fresh from an extruder machine are coated with a specific organopolysiloxane composition while remaining uncooled and staying at temperatures not lower than about 250.degree. C, or at a temperature between about 550.degree. and 250.degree. C. The thus coated aluminum bars are then, preferably, subjected to annealing. The coatings formed on the surfaces of the aluminum materials have a superior resistance to attack by chemicals, weather, stains and heat as well as excellent adhesion and mechanical properties.

摘要翻译： 来自挤出机的新鲜的铝棒用特定的有机聚硅氧烷组合物涂覆，同时保持未冷却并保持在不低于约250℃或在约550℃至250℃之间的温度。然后将这样涂覆的铝条 ，优选进行退火。 形成在铝材表面上的涂层具有优异的耐化学品，天气，污渍和热量的抵抗性，以及优异的粘合力和机械性能。