公开(公告)号：US20100081776A1

公开(公告)日：2010-04-01

申请号：US12565220

申请日：2009-09-23

申请人： Myungahn Ok ,  Dongcheol SHIN ,  Jisu JEONG ,  Hoseong LEE ,  Jongsok HAHN ,  Choonsik SHIM

发明人： Myungahn Ok ,  Dongcheol SHIN ,  Jisu JEONG ,  Hoseong LEE ,  Jongsok HAHN ,  Choonsik SHIM

IPC分类号： C08F4/64 ,  C07F7/00 ,  C07F7/28 ,  B01J31/14 ,  C08F4/42 ,  C08F4/52

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于催化剂包含围绕第4族过渡金属环戊二烯衍生物和至少一种具有芴基或其衍生物的芳氧基配体（其准备好 在9位被取代），其用作电子给体并且用于通过围绕在配位体处将配体连接到过渡金属的氧原子来稳定催化体系，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US20110319576A1

公开(公告)日：2011-12-29

申请号：US13223636

申请日：2011-09-01

申请人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

发明人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

IPC分类号： C08F10/02 ,  C08F4/6592 ,  C08F4/76

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于催化剂包含围绕第4族过渡金属环戊二烯衍生物和至少一种具有芴基或其衍生物的芳氧基配体（其准备好 在9位被取代），其用作电子给体并且用于通过围绕在配位体处将配体连接到过渡金属的氧原子来稳定催化体系，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US07928173B2

公开(公告)日：2011-04-19

申请号：US12565220

申请日：2009-09-23

申请人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

发明人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

IPC分类号： C08F4/6592 ,  C08F4/642 ,  B01J31/22 ,  B01J31/14 ,  C07F17/00

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于催化剂包含围绕第4族过渡金属环戊二烯衍生物和至少一种具有芴基或其衍生物的芳氧基配体（其准备好 在9位被取代），其用作电子给体并且用于通过围绕在配位体处将配体连接到过渡金属的氧原子来稳定催化体系，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US08232359B2

公开(公告)日：2012-07-31

申请号：US13223636

申请日：2011-09-01

申请人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

发明人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Hoseong Lee ,  Jongsok Hahn ,  Choonsik Shim

IPC分类号： C08F4/6592 ,  C08F4/642 ,  B01J31/22

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于催化剂包含围绕第4族过渡金属环戊二烯衍生物和至少一种具有芴基或其衍生物的芳氧基配体（其准备好 在9位被取代），其用作电子给体并且用于通过围绕在配位体处将配体连接到过渡金属的氧原子来稳定催化体系，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US20110282011A1

公开(公告)日：2011-11-17

申请号：US13192812

申请日：2011-07-28

申请人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

发明人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

IPC分类号： C08F4/6592 ,  C08F4/76 ,  C08F210/02 ,  C08F2/00

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/16 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03

摘要： Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.

摘要翻译： 提供一种制备乙烯与α-烯烃的共聚物的方法。 更具体地，提供了用作制备那些共聚物的催化剂的过渡金属化合物，包含它们的催化剂组合物，以及制备乙烯与α-烯烃的弹性共聚物的方法，其密度不大于0.910，其可以是 适用于各种应用，包括胶片，电线和热熔胶。 催化剂组合物是一种催化体系，其包含过渡金属催化剂，其包含环戊二烯衍生物和至少一个芳氧基的阴离子配体与邻位的芳基衍生物，以及硼或铝化合物作为活化剂。 本发明提供一种乙烯与α-烯烃共聚以制备密度不大于0.910的分子量分布窄，密度分布均匀的共聚物，对高级α-烯烃具有高活性和优异的反应性的方法。

公开(公告)号：US08013086B2

公开(公告)日：2011-09-06

申请号：US12612157

申请日：2009-11-04

申请人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

发明人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

IPC分类号： C08F4/64 ,  C08F4/6592 ,  C08F210/02 ,  B01J31/22

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/16 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03

摘要： Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.

摘要翻译： 提供一种制备乙烯与α-烯烃的共聚物的方法。 更具体地，提供了用作制备那些共聚物的催化剂的过渡金属化合物，包含它们的催化剂组合物，以及制备乙烯与α-烯烃的弹性共聚物的方法，其密度不大于0.910，其可以是 适用于各种应用，包括胶片，电线和热熔胶。 催化剂组合物是一种催化体系，其包含过渡金属催化剂，其包含环戊二烯衍生物和至少一个芳氧基的阴离子配体与邻位的芳基衍生物，以及硼或铝化合物作为活化剂。 本发明提供一种乙烯与α-烯烃共聚以制备密度不大于0.910的分子量分布窄，密度分布均匀的共聚物，对高级α-烯烃具有高活性和优异的反应性的方法。

公开(公告)号：US20100113720A1

公开(公告)日：2010-05-06

申请号：US12612157

申请日：2009-11-04

申请人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

发明人： Myungahn Ok ,  Daeho Shin ,  Seungbum Kwon ,  Jongsok Hahn ,  Hoseong Lee ,  Choonsik Shim ,  Hyeongtaek Ham ,  Jisu Jeong ,  Sungseok Chae

IPC分类号： C08F4/76 ,  C08F4/06 ,  C08F4/44

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/16 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/6592 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03

摘要： Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.

摘要翻译： 提供一种制备乙烯与α-烯烃的共聚物的方法。 更具体地，提供了用作制备那些共聚物的催化剂的过渡金属化合物，包含它们的催化剂组合物，以及制备密度不大于0.910的乙烯与α-烯烃的弹性共聚物的方法，其可以是 适用于各种应用，包括胶片，电线和热熔胶。 催化剂组合物是一种催化体系，其包含过渡金属催化剂，其包含环戊二烯衍生物和至少一个芳氧基的阴离子配体与邻位的芳基衍生物，以及硼或铝化合物作为活化剂。 本发明提供一种乙烯与α-烯烃共聚以制备密度不大于0.910的分子量分布窄，密度分布均匀的共聚物，对高级α-烯烃具有高活性和优异的反应性的方法。

公开(公告)号：US20110172380A1

公开(公告)日：2011-07-14

申请号：US13063513

申请日：2009-09-24

申请人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Jongsok Hahn ,  Hoseong Lee ,  Daeho Shin

发明人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Jongsok Hahn ,  Hoseong Lee ,  Daeho Shin

IPC分类号： C08F4/76 ,  C07F7/28 ,  C08F4/44

CPC分类号： C07F17/00 ,  C08F210/16 ,  C08F4/6592

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the Group 4 transition metal catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one naphthoxide ligand(s) having aryl substituent(s) that function(s) as an electron donor and serve(s) to stabilize the catalyst system by surrounding an oxygen atom that links the ligand to the transition metal at 2-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于第4族过渡金属催化剂包括围绕第4族过渡金属环戊二烯衍生物和至少一种具有芳基取代基的萘氧基配体 （s）作为电子给体，并通过围绕将配体连接到2-位上的过渡金属的氧原子来使催化剂体系稳定，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US08372996B2

公开(公告)日：2013-02-12

申请号：US13063513

申请日：2009-09-24

申请人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Jongsok Hahn ,  Hoseong Lee ,  Daeho Shin

发明人： Myungahn Ok ,  Dongcheol Shin ,  Jisu Jeong ,  Jongsok Hahn ,  Hoseong Lee ,  Daeho Shin

IPC分类号： C08F4/643 ,  C08F4/6592 ,  C08F110/02 ,  C08F210/02 ,  B01J31/22 ,  C07F17/00

CPC分类号： C07F17/00 ,  C08F210/16 ,  C08F4/6592

摘要： Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the Group 4 transition metal catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one naphthoxide ligand(s) having aryl substituent(s) that function(s) as an electron donor and serve(s) to stabilize the catalyst system by surrounding an oxygen atom that links the ligand to the transition metal at 2-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

摘要翻译： 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地，提供了第4族过渡金属催化剂，其特征在于第4族过渡金属催化剂包括围绕第4族过渡金属环戊二烯衍生物和至少一种具有芳基取代基的萘氧基配体 （s）作为电子给体，并通过围绕将配体连接到2-位上的过渡金属的氧原子来使催化剂体系稳定，并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

公开(公告)号：US08222361B2

公开(公告)日：2012-07-17

申请号：US12991818

申请日：2009-12-21

申请人： Byoungtak Yim ,  Youngwook Kim ,  Myungahn Ok ,  Jongsok Hahn ,  Dongcheol Shin

发明人： Byoungtak Yim ,  Youngwook Kim ,  Myungahn Ok ,  Jongsok Hahn ,  Dongcheol Shin

IPC分类号： C08F4/6592 ,  C08F236/02 ,  C08F236/04 ,  B01J31/22

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/18 ,  C08F2420/04 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/03

摘要： The present invention relates to a method for the production of an ethylene/propylene/diene copolymer by means of solution polymerization, and more specifically one for a copolymer whose main components are ethylene, propylene and diene monomers using a catalyst of a transition metal coordination compound; the constituent components and characteristics of the copolymer being as follows. The catalyst composition provided by the present invention, which is used to produce a copolymer of which (a) the ethylene content is from 30 wt. % to 80 wt. %, (b) the propylene content is from 19.9% to 60 wt. % and (c) the diene content is from more than 0 wt. % to 15 wt. %, comprises a catalyst system using an activating agent of a compound of aluminum or boron, or aluminoxane together with a transition metal catalyst comprising at least one anionic ligand having an aryloxy group substituted with an aryl derivative in the ortho position and a cyclopentadiene derivative, and provides a highly active polymerization method with outstanding reactivity with respect to ethylene, propylene and diene compounds.

摘要翻译： 本发明涉及一种通过溶液聚合制备乙烯/丙烯/二烯共聚物的方法，更具体地说，涉及使用过渡金属配位化合物的催化剂的主要成分为乙烯，丙烯和二烯单体的共聚物的方法 ; 共聚物的组成成分和特性如下。 由本发明提供的催化剂组合物，其用于制备共聚物，其中（a）乙烯含量为30重量％ ％至80wt。 ％，（b）丙烯含量为19.9％至60wt。 ％和（c）二烯含量大于0wt。 ％至15wt。 ％，包括使用铝或硼化合物的活化剂或铝氧烷的催化剂体系以及包含至少一个在邻位被芳基衍生物取代的芳氧基的阴离子配体和环戊二烯衍生物的过渡金属催化剂， 并提供了对乙烯，丙烯和二烯化合物具有突出反应性的高活性聚合方法。