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公开(公告)号：US10941282B2
公开(公告)日：2021-03-09
申请号：US16309977
申请日：2017-06-15
申请人： NEC CORPORATION , Yutaro Shimode
摘要： A cellulose resin composition comprising a cellulose resin, a high refractive-index organic material and a carbon black, in which the cellulose resin is an acylated cellulose obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, the carbon black is an acidic carbon black, the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30, and the content of the carbon black (C) relative to the total of the cellulose resin composition falls within the range of 0.05 to 10% by mass.
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公开(公告)号：US10005849B2
公开(公告)日：2018-06-26
申请号：US15030936
申请日：2014-10-07
申请人： NEC Corporation
发明人： Kiyohiko Toyama , Masatoshi Iji , Shukichi Tanaka
摘要： A process for producing a cellulose derivative, comprising: a first step including reacting a cellulose and a first reactant comprising a long-chain reactant for reacting with a hydroxy group of the cellulose to introduce a long-chain organic group having 5 or more carbon atoms, in a solid-liquid heterogeneous system, to form a cellulose derivative in a swollen state, the cellulose derivative having the long-chain organic group having 5 or more carbon atoms introduced therein and having a part of hydroxy groups of the cellulose remained, and performing solid-liquid separation to obtain the cellulose derivative as an intermediate; and a second step including reacting the intermediate cellulose derivative and a second reactant comprising a short-chain reactant for reacting with a remaining hydroxy group of the intermediate cellulose derivative to introduce a short-chain organic group having 4 or less carbon atoms to form a final cellulose derivative having the short-chain organic group having 4 or less carbon atoms introduced therein.
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3.发明公开公开(公告)号：US20230272123A1
公开(公告)日：2023-08-31
申请号：US18136931
申请日：2023-04-20
IPC分类号： C08B37/00
CPC分类号： C08B37/0024
摘要： A paramylon-based resin having a weight-average molecular weight of paramylon in a range of 70000 to 140000, and formed by substituting hydrogen atoms of hydroxy groups of a paramylon with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component being an acyl group (acetyl group or/and propionyl group) having 2 or 3 carbon atoms, wherein a degree of substitution with the long-chain component (DSLo) and a degree of substitution with the short-chain component (DSSh) satisfy the following conditional expressions (1) and (2), Izod impact strength is 5.0 kJ/m2 or more, and an MFR (melt flow rate at 210° C. and under a load of 5 kg) is 2 g/10 min or more. To provide a paramylon-based resin excellent in mechanical characteristics and thermoplasticity. 2.2≤DSLo+DSSh≤2.8 (1) 5≤DSSh/DSLo≤25 (2)
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公开(公告)号：US11505681B2
公开(公告)日：2022-11-22
申请号：US16772580
申请日：2018-12-17
申请人： NEC CORPORATION
发明人： Kiyohiko Toyama , Mina Shimizu , Masatoshi Iji , Midori Shimura , Shukichi Tanaka , Toshie Miyamoto
摘要： A cellulose resin composition comprising a cellulose derivative and a lubricant, wherein the cellulose derivative is an acylated cellulose obtained by substituting at least a part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, and the content of the lubricant is in the range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.
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公开(公告)号：US11434350B2
公开(公告)日：2022-09-06
申请号：US16772422
申请日：2018-12-17
申请人： NEC CORPORATION
发明人： Midori Shimura , Shukichi Tanaka , Kiyohiko Toyama , Masatoshi Iji , Mina Shimizu , Toshie Miyamoto
IPC分类号： C08L1/14 , C08G18/71 , C08K3/04 , C08K3/36 , C08K5/098 , C08K5/20 , C08K5/21 , C08L1/28 , C08L83/04
摘要： A cellulose resin composition comprising a cellulose derivative (A) and a lubricant (B), wherein the cellulose derivative (A) is a cellulose derivative obtained by substituting at least a part of hydrogen atoms of hydroxyl groups of a cellulose with a short-chain organic group having 2 to 4 carbon atoms and a long-chain organic group having 8 to 30 carbon atoms with specific degrees of substitution; the lubricant (B) is at least one selected from the group consisting of a urea compound (B1) having a urea group (—NH—C(═O)—NH—) and an acyclic aliphatic group having 6 to 33 carbon atoms, an amide compound (B2) having an amide group (—C(═O)—NH—) and an acyclic aliphatic group having 6 to 33 carbon atoms, a fatty acid metal salt (B3), and a silicone-based lubricant (B4); and a content of the lubricant (B) is in a range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.
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公开(公告)号：US11591410B2
公开(公告)日：2023-02-28
申请号：US15521965
申请日：2015-04-24
申请人： NEC Corporation
发明人： Kiyohiko Toyama , Masatoshi Iji , Shukichi Tanaka
摘要： A cellulose derivative having a long-chain organic group having 5 or more carbon atoms and a short-chain organic group having 4 or less carbon atoms which are introduced by use of hydroxy groups of a cellulose, and including a crystal structure derived from a cellulose derivative portion to which the short-chain organic group is linked, wherein an average number of hydroxy groups per glucose unit is of 1.0 or less.
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公开(公告)号：US11149133B2
公开(公告)日：2021-10-19
申请号：US16310003
申请日：2017-06-15
申请人： NEC CORPORATION
IPC分类号： C08L1/10 , C08K3/04 , C08K5/06 , C08B3/16 , C08K5/523 , C08L1/14 , C08K5/00 , C08K5/01 , C08K5/521 , C08K5/3492 , C08K5/07 , C08K5/37
摘要： A cellulose resin composition containing a cellulose resin (A) and a high refractive-index organic material (B), in which the cellulose resin (A) is a cellulose derivative obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms and a long-chain organic group having 7 or more carbon atoms, and the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30.
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公开(公告)号：US10961388B2
公开(公告)日：2021-03-30
申请号：US15780760
申请日：2016-12-02
申请人： NEC CORPORATION
发明人： Makoto Soyama , Masatoshi Iji , Shukichi Tanaka , Kiyohiko Toyama
IPC分类号： C08L67/04 , C08G77/18 , C08G77/26 , C08G77/44 , C08G77/445 , C08G63/695 , C08L67/00 , C08K7/14 , C08K9/06 , C08K5/29 , C08L101/16
摘要： Resin compositions according to exemplary embodiments of the present invention are first compositions containing a polylactic acid resin, an aliphatic polyester resin, a surface-treated metal hydrate, and a carbodiimide compound, or second compositions containing a polysiloxane-mixed polyester resin, a phosphorus-containing flame retardant, a metal hydrate and a fluorine-containing polymer in specific ratios.
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公开(公告)号：US10982009B2
公开(公告)日：2021-04-20
申请号：US15766116
申请日：2016-08-29
申请人： NEC CORPORATION
摘要： To provide a cellulose derivative excellent in thermoplasticity, water resistance and strength (elastic modulus, impact strength), a cellulose derivative, which is obtained by introducing a short-chain organic group (acetyl group), a medium-chain organic group having 3 to 5 carbon atoms and a long-chain organic group having 6 to 30 carbon atoms at the following substitution degrees DSs into a cellulose, is used: Short-chain organic group: 0.7≤DSSH≤1.5; Medium-chain organic group: 0.5≤DSME≤2.0; Long-chain organic group: 0.1≤DSLO
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10.发明授权公开(公告)号：US10934368B2
公开(公告)日：2021-03-02
申请号：US16066521
申请日：2016-12-09
申请人： NEC CORPORATION
发明人： Shukichi Tanaka , Midori Shimura , Masatoshi Iji
摘要： A cellulose resin formed by substituting hydrogen atoms of hydroxy groups of a cellulose with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component being an acyl group having 2 or 3 carbon atoms, in which a degree of substitution with the long-chain component (DSLo) and a degree of substitution with the short-chain component (DSSh) satisfy conditional expressions (1) and (2) shown below: DSLo+DSSh≥2.1 (1) 4≤DSSh/DSLo≤12 (2).
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