PILOT PLANT FOR CHEMICAL LOOPING HYDROGEN GENERATION USING SINGLE-COLUMN PACKED BED AND HYDROGEN GENERATION METHOD

    公开(公告)号:US20180002173A1

    公开(公告)日:2018-01-04

    申请号:US15625738

    申请日:2017-06-16

    IPC分类号: C01B3/10 B01J8/06

    摘要: A pilot plant for chemical looping hydrogen generation using a single-column packed bed and hydrogen generation method. The plant has a feeding system, reaction system, tail gas treatment and analysis system, and auxiliary system. The reaction system has a packed bed reactor, inside which a thermal storage layer, oxygen carrier layer and supporting layer are arranged successively from top to bottom. The feeding system has a delivery pipe, metering pump, mass flow controller and fuel mixer. The tail gas treatment and analysis system has a cooler, gas-liquid separator, mass flow meter, gas analyzer and tail gas pipe. The packed bed reactor is subjected to fuel reduction, purge, steam oxidation, purge, air combustion and purge stages successively under control of the feeding system. The pilot plant enables evaluation for oxygen carriers and identification for technological difficulties and can generate high-purity hydrogen without using complex gas purification devices.

    DEVICE AND METHOD FOR GENERATING HIGH-PURITY HYDROGEN BY BIOMASS PYROLYSIS-CHEMICAL LOOPING COMBUSTION

    公开(公告)号:US20180002174A1

    公开(公告)日:2018-01-04

    申请号:US15633076

    申请日:2017-06-26

    摘要: The present invention discloses a device and method for generating high-purity hydrogen by biomass pyrolysis-chemical looping combustion. The device comprises a biomass pyrolysis unit, a chemical looping hydrogen generation unit and a waste heat recovery unit; the biomass pyrolysis unit comprises a vertical bin, a screw feeder, a rotary kiln pyrolysis reactor and a high temperature filter; the chemical looping hydrogen generation unit comprises a path switching system of intake gas end, at least one packed bed reactor and a path switching system of tail gas end, wherein the packed bed reactor is composed of three parallel packed bed reactors I, II and III, which are continuously subjected to fuel reduction-steam oxidation-air combustion stages (steam purging stage) successively; the waste heat recovery unit comprises a waste heat boiler, a cooler and a gas-liquid separator. According to the present invention, a process flow of generating hydrogen from biomass is short, high-purity hydrogen can be obtained by simple condensation and water removal of a hydrogen-containing product that is generated after entrance of a pyrolysis gas into the chemical looping hydrogen generation unit, no complex gas purification device is employed, and the costs for hydrogen generation are low.