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1.发明授权Process for producing vinyl ester polymer and process for producing vinyl alcohol polymer 失效制备乙烯基酯聚合物的方法和生产乙烯醇聚合物的方法
公开(公告)号：US5331055A
公开(公告)日：1994-07-19
申请号：US928774
申请日：1992-08-17
IPC分类号： C08F2/24 , C08F8/12 , C08F263/00 , C08F2/30
CPC分类号： C08F263/00 , C08F8/12 , C08J5/18
摘要： There are disclosed a process for producing a vinyl ester polymer having a high degree of polymerization at a high efficiency, which process comprises subjecting a vinyl ester monomer to seed polymerization by the use of a vinyl ester polymer emulsion as a seed emulsion under the conditions in which the charge of a water-soluble initiator per unit volume (1 liter) of reactant liquid charge is 1.times.10.sup.-8 to 2.times.10.sup.-4 mol, and the charge of the water-soluble initiator per one particle of the vinyl ester polymer particles in the seed emulsion is 1.times.10.sup.-28 to 1.times.10.sup.-20 mol, and a process for producing a vinyl alcohol polymer at a high efficiency from the vinyl ester polymer thus obtained.According to these processes of the present invention, both a vinyl ester polymer and vinyl alcohol polymer each having a higher degree of polymerization can be produced with ease on an industrial scale.
摘要翻译： 公开了一种以高效率生产高聚合度的乙烯基酯聚合物的方法，该方法包括使乙烯基酯单体通过使用乙烯基酯聚合物乳液作为种子乳液进行种子聚合， 其中每单位体积（1升）反应物液体电荷的水溶性引发剂的电荷为1×10 -8至2×10 -4摩尔，并且每1个乙烯基酯聚合物颗粒中的水溶性引发剂的电荷 种子乳液为1×10-28至1×10-20mol，以及由此获得的乙烯基酯聚合物以高效率生产乙烯醇聚合物的方法。 根据本发明的这些方法，可以容易地以工业规模生产各自具有较高聚合度的乙烯基酯聚合物和乙烯醇聚合物。
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2.发明授权
公开(公告)号：US5308911A
公开(公告)日：1994-05-03
申请号：US28181
申请日：1993-03-09
摘要： There are disclosed a secondary suspending agent for suspension polymerization of a vinyl compound (vinyl chloride, etc.) which comprises an aqueous dispersion comprising as the dispersoid, a polyvinyl ester having a degree of hydrolysis of 60 mol% or less, an average degree of polymerization of 4000 or more and an average particle diameter of 100 .mu.m or less; a suspension stabilizing agent comprising 5 to 70% by weight of the secondary suspending agent (PVA, etc.) and 30 to 95% by weight of a water-soluble high molecular compound having a degree of polymerization of 500 or more, the agent being used for suspension polymerization of a vinyl compound; and a process for producing a vinyl polymer (PVC, etc.) comprising suspension polymerizing a vinyl compound by the use of the above suspension stabilizing agent. Both the agents are well suited for producing vinyl polymer granules enhanced in absorption rate of plasticizer, bulk density, removality of residual monomer and porosity.
摘要翻译： 公开了一种乙烯基化合物（氯乙烯等）的悬浮聚合用二次悬浮剂，其包含含有分散体的水分散体，水解度为60摩尔％以下的聚乙烯基酯， 聚合4000以上，平均粒径为100μm以下; 包含5〜70重量％的二次悬浮剂（PVA等）和30〜95重量％的聚合度为500以上的水溶性高分子化合物的悬浮稳定剂，试剂为 用于乙烯基化合物的悬浮聚合; 以及包含通过使用上述悬浮稳定剂使乙烯基化合物悬浮聚合的乙烯基聚合物（PVC等）的制造方法。 这两种试剂都非常适合生产提高增塑剂吸收速率，堆积密度，残留单体去除率和孔隙率的乙烯基聚合物颗粒。
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公开(公告)号：US5599870A
公开(公告)日：1997-02-04
申请号：US407670
申请日：1995-03-21
申请人： Masato Nakamae , Naoki Fujiwara , Kazutoshi Terada , Daisuke Miyake , Ken Yuki , Toshiaki Sato , Hitoshi Maruyama
发明人： Masato Nakamae , Naoki Fujiwara , Kazutoshi Terada , Daisuke Miyake , Ken Yuki , Toshiaki Sato , Hitoshi Maruyama
IPC分类号： B01F17/52 , C08F2/30 , C08L29/00 , C09J133/04 , C08L29/04
CPC分类号： C08F2/30 , C09J133/04 , C08L29/00 , Y10S516/06 , Y10S526/911 , Y10S526/912
摘要： The present invention relates to an aqueous emulsion comprising a dispersant of a modified polyvinyl alcohol with an ethylene unit content of 2 to 9 mol % and a degree of hydrolysis of at least 95 mol %, a dispersoid of a polymer of an ethylenically unsaturated monomer, and a ratio (.eta.2 rpm/.eta.20 rpm) of Brookfield viscosity at 30.degree. C., 2 rpm (.eta.2 rpm) as against Brookfield viscosity at 30.degree. C., 20 rpm (.eta.20 rpm) being 1 to 1.8 when the latter viscosity (.eta.20 rpm) is adjusted to 5,000 to 10,000 mPa.multidot.S.The aqueous emulsion according to the present invention is excellent in structural viscosity (flowability, high speed application performance), provides coated layers with high water resistance and low-temperature stability, and can be suitably used extensively as an adhesive for paper, wood and plastics, as a binder for impregnated paper and non-woven products, as an additive for mortar, as a paint, and in paper and fiber processings.
摘要翻译： 本发明涉及含有乙烯单元含量为2〜9mol％，水解度为95mol％以上的改性聚乙烯醇的分散剂，烯键式不饱和单体的聚合物的分散体， 并且在30℃下，Brookfield粘度在30℃，2rpm（eta 2rpm）下的Brookfield粘度与20℃下的Brookfield粘度（20rpm）的比（η2rpm /η20rpm）为1至1.8当 将后一粘度（η20rpm）调节至5,000至10,000mPaxS。 本发明的水性乳液的结构粘度（流动性，高速涂布性）优异，可提供耐水性和低温稳定性的涂布层，可广泛适用于纸，木材，塑料的粘合剂 作为浸渍纸和无纺布产品的粘合剂，作为砂浆添加剂，作为涂料，以及纸和纤维加工。
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公开(公告)号：US5527852A
公开(公告)日：1996-06-18
申请号：US465891
申请日：1995-06-06
IPC分类号： D21H19/20 , D21H19/60 , D21H21/52 , C08F116/06
CPC分类号： D21H19/20 , D21H19/60 , D21H21/52 , Y10T428/2982 , Y10T428/31938
摘要： A coating agent comprising a particulate PVA having an average particle diameter of 0.01 to 1 .mu.m has excellent applicability through blade coaters or roll coaters.
摘要翻译： 包含平均粒径为0.01〜1μm的粒状PVA的涂布剂通过刮刀涂布机或辊涂机具有优异的适用性。
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公开(公告)号：US5102950A
公开(公告)日：1992-04-07
申请号：US735687
申请日：1991-07-29
IPC分类号： C08J5/18 , C08F8/12 , C08F16/02 , C08F216/02
摘要： Provided are water soluble films comprising a modified polyvinyl alcohol containing 2-pyrrolidone ring. The films have excellent water solubility, which can be maintained over a long period of time and under the condition of being contacted with an alkaline or acid substance, and at the same time have an appropriate touch and flexibility.
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公开(公告)号：US08912264B2
公开(公告)日：2014-12-16
申请号：US11719807
申请日：2005-11-25
CPC分类号： C08L23/0861 , C08L23/0876 , C08L23/16 , C08L29/04 , C08L2205/02 , C08L2205/03 , C08L2666/06 , C08L2666/04
摘要： It is an object of the present invention to provide an aqueous ethylene-vinyl alcohol-based copolymer dispersion which is excellent in long-term storage stability and in film-forming properties even when subjected to low-temperature or short-time drying or applied to give thick coats and can give coatings showing high gas barrier performance. The prevent invention is an aqueous ethylene/vinyl alcohol-based copolymer dispersion, which comprises: (A) an ethylene/vinyl alcohol-based copolymer with an ethylene content of 15-65 mole percent and a degree of saponification of not lower than 80 mole percent, (B) a base-neutralized ethylene/α,β-unsaturated carboxylic acid-based copolymer and (C) a polyvinyl alcohol with a degree of saponification of 75-100 mole percent and a degree of polymerization of 100-3500, the content of the polyvinyl alcohol (C) being 0.5-100 parts by weight per 100 parts by weight of the ethylene/vinyl alcohol-based copolymer (A).
摘要翻译： 本发明的目的是提供一种乙烯 - 乙烯醇系共聚物分散液，其即使在经受低温或短时间干燥时也具有优异的长期保存稳定性和成膜性， 得到厚涂层，并可以赋予显示出高阻气性能的涂层。 防止发明是乙烯/乙烯醇系共聚物水分子分散体，其包含：（A）乙烯含量为15〜65摩尔％，皂化度为80摩尔以上的乙烯/乙烯醇系共聚物 百分比，（B）碱中和乙烯/α，不饱和羧酸基共聚物和（C）皂化度为75-100摩尔％，聚合度为100-3500的聚乙烯醇， 聚乙烯醇（C）的含量相对于100重量份乙烯/乙烯醇系共聚物（A）为0.5〜100重量份。
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公开(公告)号：US20090149593A1
公开(公告)日：2009-06-11
申请号：US11719807
申请日：2005-11-25
CPC分类号： C08L23/0861 , C08L23/0876 , C08L23/16 , C08L29/04 , C08L2205/02 , C08L2205/03 , C08L2666/06 , C08L2666/04
摘要： It is an object of the present invention to provide an aqueous ethylene-vinyl alcohol-based copolymer dispersion which is excellent in long-term storage stability and in film-forming properties even when subjected to low-temperature or short-time drying or applied to give thick coats and can give coatings showing high gas barrier performance. The prevent invention is an aqueous ethylene/vinyl alcohol-based copolymer dispersion, which comprises: (A) an ethylene/vinyl alcohol-based copolymer with an ethylene content of 15-65 mole percent and a degree of saponification of not lower than 80 mole percent, (B) a base-neutralized ethylene/α,β-unsaturated carboxylic acid-based copolymer and (C) a polyvinyl alcohol with a degree of saponification of 75-100 mole percent and a degree of polymerization of 100-3500, the content of the polyvinyl alcohol (C) being 0.5-100 parts by weight per 100 parts by weight of the ethylene/vinyl alcohol-based copolymer (A).
摘要翻译： 本发明的目的是提供一种乙烯 - 乙烯醇系共聚物分散液，其即使在经受低温或短时间干燥时也具有优异的长期保存稳定性和成膜性， 得到厚涂层，并可以赋予显示出高阻气性能的涂层。 防止发明是乙烯/乙烯醇系共聚物水分子分散体，其包含：（A）乙烯含量为15〜65摩尔％，皂化度为80摩尔以上的乙烯/乙烯醇系共聚物 百分比，（B）碱中和的乙烯/α，β-不饱和羧酸基共聚物和（C）皂化度为75-100摩尔％，聚合度为100-3500的聚乙烯醇， 聚乙烯醇（C）的含量相对于100重量份乙烯/乙烯醇系共聚物（A）为0.5〜100重量份。
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8.发明授权Multiphase structured polymer particles, method of manufacturing same, and uses thereof 有权多相结构聚合物颗粒，其制造方法及其用途公开(公告)号：US06348542B1
公开(公告)日：2002-02-19
申请号：US09678735
申请日：2000-10-04
IPC分类号： C08L5104
CPC分类号： C08F285/00 , C08F220/14
摘要： This invention relates to multiphase structured polymer particles comprising at least two rubber component phases (I) formed by copolymerization of monomer mixtures comprising an acrylate ester and a polyfunctional monomer, a thermoplastic resin component phase (II) formed by copolymerization of a monomer mixture comprising a methacrylate ester and other monomers, and satisfying the following conditions (1)-(5). (1) The number average molecular weight of the thermoplastic resin component forming the outermost phase is 30,000 or less. (2) The weight ratio of phase (I)/phase (II) is 30/70-80/20. (3) Of the adjacent phases (1), a specific relation holds regarding the solubility in water of the monomer mixtures forming the nth and n+1th phases. (4) A specific relation holds between the refractive index of phase (I) and the refractive index of phase (II). (5) The average particle size is 150 nm or less. When the multiphase structured polymer particles according to this invention are used alone to form molded products, molded products having excellent transparency and elastic recovery properties can be obtained.
摘要翻译： 本发明涉及多相结构聚合物颗粒，其包含由包含丙烯酸酯和多官能单体的单体混合物的共聚形成的至少两个橡胶组分相（I），通过单体混合物共聚形成的热塑性树脂组分相（II） 甲基丙烯酸酯等单体，满足下列条件（1） - （5）。 （1）形成最外相的热塑性树脂成分的数均分子量为30,000以下。 （2）相（I）/相（II）的重量比为30 / 70-80 / 20。 （3）在相邻相（1）中，关于形成第n相和第n + 1相的单体混合物在水中的溶解度的特定关系。 （4）相（I）的折射率和相（II）的折射率之间的具体关系成立。 （5）平均粒径为150nm以下。 当本发明的多相结构化聚合物颗粒单独使用以形成模塑产品时，可以获得具有优异的透明性和弹性恢复性的模塑产品。
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9.发明申请Curable resin composition, method for manufacture of laminate using the composition, transfer material, method for manufacture thereof and transferred product 审中-公开可固化树脂组合物，使用该组合物的制造层压体的方法，转印材料，其制造方法和转印产品公开(公告)号：US20050222293A1
公开(公告)日：2005-10-06
申请号：US11136368
申请日：2005-05-25
申请人： Takahiro Kitano , Hirokazu Suzuki , Keiji Kubo , Masayasu Ogushi , Kazutoshi Terada , Tsuneo Kawabata , Masaki Kojima
发明人： Takahiro Kitano , Hirokazu Suzuki , Keiji Kubo , Masayasu Ogushi , Kazutoshi Terada , Tsuneo Kawabata , Masaki Kojima
CPC分类号： C09J4/06 , C08F265/04
摘要： A curable resin composition with excellent thermal adhesiveness is constituted of the following components (A) to (C): (A) a thermoadhesive polymer; (B) an ethylenic unsaturated compound polymerizable by active energy radiation; and (C) a polymerization initiator, wherein the relationships represented by the following formulas (1) and (2) are satisfied: 0.1≦(Awt)/{(Awt)+(Bwt)}≦0.6 (1) 0.4≦(Bwt)/{(Awt)+(Bwt)}≦0.9 (2) where (Awt) stands for a compounded amount (parts by weight) of component (A), and (Bwt) stands for a compounded amount (parts by weight) of component (B).
摘要翻译： 热粘合性优异的固化性树脂组合物由以下成分（A）〜（C）构成：（A）热粘合性聚合物; （B）通过活性能量辐射可聚合的烯属不饱和化合物; 和（C）聚合引发剂，其中满足由下式（1）和（2）表示的关系：<？in-line-formula description =“In-line formula”end =“lead”？> 0.1 < =（Awt）/ {（Awt）+（Bwt）} <= 0.6（1）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> 0.4 <=（Bwt）/ {（Awt）+（Bwt）} <= 0.9（2）<？in-line-formula description = “end =”tail“？>其中（Awt）表示组分（A）的配混量（重量份），（Bwt）表示组分（B）的配混量（重量份）。
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