公开(公告)号：US10906869B2

公开(公告)日：2021-02-02

申请号：US15563323

申请日：2016-03-31

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Hiroshi Senoh ,  Toshikatsu Kojima ,  Nobuhiko Takeichi ,  Hisanori Ando

IPC: H01M10/052 ,  H01M10/054 ,  C07C381/00 ,  H01M4/62 ,  H01M4/38 ,  C01B32/75 ,  H01M4/58 ,  H01M4/60 ,  H01M10/0562 ,  C01B32/70 ,  C08L71/02 ,  G01N21/65 ,  H01M10/0525

Abstract: An organic sulfur material comprising carbon, hydrogen, oxygen, and sulfur as constituent elements, and having peaks in the vicinity of 482 cm−1, 846 cm−1, 1066 cm−1, 1279 cm−1, and 1442 cm−1 in a Raman spectrum detected by Raman spectroscopy, the peak in the vicinity of 1442 cm−1 being most intense, has a high capacity and high heat resistance, although a liquid organic starting material is used.

公开(公告)号：US20140332718A1

公开(公告)日：2014-11-13

申请号：US14362800

申请日：2012-10-12

Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Akira Kojima ,  Toshikatsu Kojima ,  Mitsuharu Tabuchi ,  Tetsuo Sakai ,  Takuhiro Miyuki ,  Junichi Niwa ,  Kazuhito Kawasumi ,  Masakazu Murase

IPC: H01M4/36 ,  C01B33/32 ,  H01M4/58

CPC classification number: H01B1/08 ,  C01B33/32 ,  H01M4/1315 ,  H01M4/13915 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: A lithium silicate-based compound according to the present invention is expressed by a general formula, Li(2−a+b)AaMn(1−x−y)CoxMySiO(4+α)Clβ (In the formula: “A” is at least one element selected from the group consisting of Na, K, Rb and Cs; “M” is at least one member selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the respective subscripts appear to be as follows: 0≦“a”

Abstract translation: 本发明的硅酸锂类化合物由通式Li（2-a + b）AaMn（1-x-y）CoxMySiO（4 +α）Cl＆bgr; （式中，“A”为选自Na，K，Rb，Cs中的至少一种元素，“M”为选自Mg，Ca，Al，Ni，Fe ，Nb，Ti，Cr，Cu，Zn，Zr，V，Mo和W;各个下标看起来如下：0＆nlE;“a”<0.2; 0＆nlE;“b”<1; 0 <“x” <1; 0＆nlE;“y”＆nlE; 0.5; -0.25＆nlE;“α”＆nlE; 1.25;和0＆nlE;“＆bgr”“＆nlE; 0.05）。 使用硅酸锂系化合物作为放电平均电压较高的能够吸附和解吸锂离子的二次电池用正极活性物质。

公开(公告)号：US09812702B2

公开(公告)日：2017-11-07

申请号：US14912971

申请日：2014-07-17

Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Yuta Ikeuchi ,  Toshikatsu Kojima ,  Tetsuo Sakai ,  Tatsuya Eguchi ,  Hitoshi Aikiyo ,  Akira Kojima

IPC: H01M4/00 ,  H01M4/131 ,  H01M4/38 ,  H01M4/62 ,  H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M4/36 ,  H01M10/052 ,  H01M4/02

CPC classification number: H01M4/131 ,  H01M4/366 ,  H01M4/386 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

Abstract: To provide a lithium ion secondary battery capable of suppressing thermal run-away when internal short circuiting occurs. The lithium ion secondary battery includes: a positive electrode including a current collector, a positive electrode active material layer that is formed on the current collector and that contains a lithium-containing complex oxide having a layered rock salt structure and being represented by general formula: LiaNibCocMndDeOf (0.2≦a≦1; b+c+d+e=1; 0≦e

公开(公告)号：US09583765B2

公开(公告)日：2017-02-28

申请号：US14247434

申请日：2014-04-08

Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Akira Kojima ,  Kazuhito Kawasumi ,  Junichi Niwa ,  Yuta Ikeuchi ,  Toshikatsu Kojima ,  Tetsuo Sakai

IPC: H01M4/58 ,  H01M4/525 ,  H01M10/054 ,  H01M4/36 ,  H01M4/131 ,  H01M10/0568 ,  H01M4/62

CPC classification number: H01M4/5825 ,  H01M4/131 ,  H01M4/364 ,  H01M4/366 ,  H01M4/525 ,  H01M4/625 ,  H01M10/054 ,  H01M10/0568 ,  Y02E60/122

Abstract: Provided are a positive electrode active material for a sodium ion secondary battery, and a positive electrode and a sodium ion secondary battery using the material. The positive electrode active material for a sodium ion secondary battery comprises a lithium sodium-based compound containing lithium (Li), sodium (Na), iron (Fe), and oxygen (O).

Abstract translation: 提供一种钠离子二次电池用正极活性物质，使用该材料的正极和钠离子二次电池。 作为钠离子二次电池用正极活性物质，可以举出锂（Li），钠（Na），铁（Fe），氧（O）等的锂钠系化合物。

公开(公告)号：US20180065927A1

公开(公告)日：2018-03-08

申请号：US15563323

申请日：2016-03-31

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Hiroshi Senoh ,  Toshikatsu Kojima ,  Nobuhiko Takeichi ,  Hisanori Ando

IPC: C07C381/00 ,  G01N21/65 ,  C01B32/70 ,  H01M10/0525 ,  H01M10/0562 ,  H01M4/60 ,  C08L71/02

CPC classification number: C07C381/00 ,  C01B32/70 ,  C01B32/75 ,  C08L71/02 ,  G01N21/65 ,  H01M4/38 ,  H01M4/5815 ,  H01M4/60 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/0562 ,  Y02P70/54 ,  Y02T10/7011

Abstract: An organic sulfur material comprising carbon, hydrogen, oxygen, and sulfur as constituent elements, and having peaks in the vicinity of 482 cm−1, 846 cm−1, 1066 cm−1, 1279 cm−1, and 1442 cm−1 in a Raman spectrum detected by Raman spectroscopy, the peak in the vicinity of 1442 cm−1 being most intense, has a high capacity and high heat resistance, although a liquid organic starting material is used.

公开(公告)号：US10008722B2

公开(公告)日：2018-06-26

申请号：US15022282

申请日：2014-09-29

Applicant: SUMITOMO RUBBER INDUSTRIES, LTD. ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Kazuo Hochi ,  Tatsuya Kubo ,  Tetsuo Sakai ,  Toshikatsu Kojima

IPC: H01M4/583 ,  H01M10/0525 ,  H01M4/38 ,  H01M4/136 ,  H01M4/36 ,  H01M4/587 ,  H01M4/62 ,  H01M4/04 ,  H01M4/133 ,  H01M4/02

CPC classification number: H01M4/583 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/136 ,  H01M4/364 ,  H01M4/38 ,  H01M4/587 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/028

Abstract: An object of the present invention is to provide a positive-electrode active material comprising a carbon-sulfur structure which has Raman shift peaks at around 500 cm−1, at around 1,250 cm−1 and at around 1,450 cm−1 in a Raman spectrum, and by using the positive-electrode active material, it is possible to greatly improve cycling characteristics of a lithium-ion secondary battery.

公开(公告)号：US20180072665A1

公开(公告)日：2018-03-15

申请号：US15563276

申请日：2016-03-24

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Toshikatsu Kojima ,  Hiroyuki Kageyama

IPC: C07C381/00 ,  H01M4/60 ,  C01B32/70 ,  H01M10/0525 ,  H01M10/0562 ,  C08L71/02

Abstract: The present invention provides an organic sulfur material comprising carbon, hydrogen, and sulfur as constituent elements, and having peaks in the vicinity of 480 cm−1, 1250 cm−1, 1440 cm−1, and 1900 cm−1 in a Raman spectrum detected by Raman spectroscopy. The peak in the vicinity of 1440 cm−1 is the most intense peak. This organic sulfur material, which is produced by using a liquid organic starting material, achieves high capacity. This organic sulfur material preferably does not have peaks in the vicinity of 846 cm−1 or 1066 cm−1.

公开(公告)号：US09590237B2

公开(公告)日：2017-03-07

申请号：US14769750

申请日：2014-01-08

Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Akira Kojima ,  Junichi Niwa ,  Kazuhito Kawasumi ,  Yuta Ikeuchi ,  Masanori Morishita ,  Toshikatsu Kojima ,  Tetsuo Sakai

IPC: H01M2/16 ,  H01M4/36 ,  H01M4/136 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/58 ,  H01M10/0525 ,  H01M4/485 ,  H01M4/587 ,  H01M4/02

CPC classification number: H01M4/364 ,  H01M4/136 ,  H01M4/1395 ,  H01M4/386 ,  H01M4/485 ,  H01M4/5825 ,  H01M4/587 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/028 ,  H01M2220/30 ,  Y02E60/122

Abstract: A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8

Abstract translation: 本发明的锂离子二次电池包括正极，其包括通过使硅酸锂系材料与碳材料复合而形成的正极活性物质复合体，含有硅的负极活性物质的负极和 电解液 锂离子二次电池满足0.8