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公开(公告)号：US4532370A
公开(公告)日：1985-07-30
申请号：US652555
申请日：1984-09-20
CPC分类号： B01J31/2208 , B01J31/0212 , B01J31/143 , C07C2/30 , B01J2531/46 , C07C2531/02 , C07C2531/12 , C07C2531/14
摘要： Process for synthesizing 1-butene by dimerization of ethylene, in the presence of a catalyst formed by reacting, in a hydrocarbon medium, a trialkylaluminum with a mixture of an alkyl titanate with an ether. The activity and the selectivity are improved when adding the ether to a pre-formed mixture of alkyl titanate with trialkylaluminum.
摘要翻译： 在通过在烃介质中使三烷基铝与钛酸烷基酯与醚的混合物反应形成的催化剂存在下，通过乙烯的二聚合成合成1-丁烯的方法。 当将醚加入预先形成的钛酸三烷基酯与三烷基铝的混合物时，活性和选择性得到改善。
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2.发明授权
公开(公告)号：US4615998A
公开(公告)日：1986-10-07
申请号：US728901
申请日：1985-04-30
CPC分类号： B01J31/2208 , B01J31/0212 , B01J31/143 , C07C2/30 , B01J2531/46 , C07C2531/02 , C07C2531/12 , C07C2531/14
摘要： A catalyst is formed by reacting, in a hydrocarbon medium, a trialkylaluminum with a mixture of an alkyl titanate with an ether. The activity and the selectivity are improved when adding the trialkylaluminum to a pre-formed mixture of alkyl titanate with ether.
摘要翻译： 在烃介质中使三烷基铝与钛酸烷基酯与醚的混合物反应形成催化剂。 当将三烷基铝加入预先形成的钛酸烷基酯与醚的混合物时，活性和选择性得到改善。
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公开(公告)号：US4005047A
公开(公告)日：1977-01-25
申请号：US547032
申请日：1975-02-04
CPC分类号： C08G61/08
摘要： New catalytic composition of improved activity in the process of polymerizing cycloolefins, comprising a carbonyl compound or a carbonyl-metal-carbenic compound of molybdenum or tungsten and titanium tetrachloride, said composition being preferably subjected to an irradiation with rays of a wave length from 180 to 700 nanometers during or before use.
摘要翻译： 在包含钼或钨和四氯化钛的羰基化合物或羰基 - 金属 - 碳化合物的环烯烃聚合过程中改进的活性的新催化组合物，所述组合物优选经受从180至 使用期间或之前700纳米。
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4.发明授权
公开(公告)号：US4613726A
公开(公告)日：1986-09-23
申请号：US749166
申请日：1985-06-27
IPC分类号： C10G57/02 , B01J31/00 , B01J31/22 , B01J31/40 , C07B61/00 , C07C1/00 , C07C2/32 , C07C7/00 , C07C7/10 , C07C7/148 , C07C11/02 , C07C67/00 , C10G50/00
CPC分类号： C07C11/02 , C07C7/005 , C07C7/14858 , C07C7/14875
摘要： Nickel, aluminum and chlorine derivatives which remain dissolved in olefin oligomers, after oligomerization in the presence of a nickel, aluminum, and chlorine-containing catalysts, are removed by successive treatments with:(a) anhydrous ammonia,(b) an aqueous solution of alkali metal hydroxide, a treatment with an aqueous solution containing at least one hydroxy-acid or at least one alkali metal salt of said hydroxyacid being performed after treatment (a) and before or after or simultaneously with treatment (b), and preferably a treatment with oxygen or with an oxygen-containing gas being performed before or after treatments (a) and (b) or simultaneously with these treatments. Preferably, tartaric acid or an alkali metal tartrate is used.
摘要翻译： 在镍，铝和含氯催化剂存在下，低聚后，仍然溶解在烯烃低聚物中的镍，铝和氯衍生物通过以下步骤被除去：（a）无水氨，（b） 碱金属氢氧化物，在处理（a）之后和在处理（b）之前或之后进行处理，含有至少一种羟基酸或至少一种所述羟基酸的碱金属盐的水溶液，优选处理 在处理（a）和（b）之前或之后或与这些处理同时进行氧气或含氧气体。 优选使用酒石酸或酒石酸碱金属。
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公开(公告)号：US5059571A
公开(公告)日：1991-10-22
申请号：US560960
申请日：1990-08-01
IPC分类号： B01J31/02 , B01J31/04 , B01J31/14 , B01J31/16 , B01J31/22 , C07B61/00 , C07C2/26 , C07C2/30 , C07C2/32 , C07C11/02 , C08F4/607
CPC分类号： C07C2/32 , B01J31/0201 , B01J31/04 , B01J31/143 , B01J31/2234 , C07C2/30 , B01J2231/20 , B01J2531/847 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/22
摘要： The invention concerns a catalytic composition resulting from placing at least one divalent nickel compound into contact with at least one hydrocarbylaluminum halide and at least one epoxy compound, in any order. It also concerns the use of the catalytic composition in a process of oligomerizing monoolefins.
摘要翻译： 本发明涉及通过将至少一种二价镍化合物以任何顺序与至少一种烃基卤化铝和至少一种环氧化合物接触而得到的催化组合物。 它还涉及催化组合物在单烯烃低聚方法中的应用。
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公开(公告)号：US5095162A
公开(公告)日：1992-03-10
申请号：US732001
申请日：1991-07-18
IPC分类号： B01J31/02 , B01J31/04 , B01J31/14 , B01J31/16 , B01J31/22 , C07B61/00 , C07C2/26 , C07C2/30 , C07C2/32 , C07C11/02 , C08F4/607
CPC分类号： C07C2/32 , B01J31/0201 , B01J31/04 , B01J31/143 , B01J31/2234 , C07C2/30 , B01J2231/20 , B01J2531/847 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/22
摘要： The invention concerns a catalytic composition resulting from placing at least one divalent nickel compound into contact with at least one hydrocarbylaluminum halide and at least one epoxy compound, in any order. It also concerns the use of the catalytic composition in a process of oligomerizing monoolefins.
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公开(公告)号：US4362650A
公开(公告)日：1982-12-07
申请号：US261819
申请日：1981-05-08
申请人： Yves Chauvin , Dominique Commereuc , Gerard Leger , Jean Gaillard , Nhu H. Phung
发明人： Yves Chauvin , Dominique Commereuc , Gerard Leger , Jean Gaillard , Nhu H. Phung
IPC分类号： C07C2/26 , B01J31/14 , B01J31/22 , B01J31/28 , C07B61/00 , C07C1/00 , C07C2/30 , C07C2/32 , C07C11/02 , C07C67/00 , B01J31/04
CPC分类号： B01J31/2234 , B01J31/0231 , B01J31/04 , B01J31/143 , C07C2/30 , C07C2/32 , B01J2231/20 , B01J2531/847 , B01J31/0225 , C07C2531/04 , C07C2531/14 , C07C2531/22
摘要： An improved catalyst composition is obtained by contacting at least one bivalent nickel compound with at least one hydrocarbyl aluminum halide, at least one Bronsted organic acid and at least one anhydride of a carboxylic acid. The composition can be used as a catalyst for olefin oligomerization.
摘要翻译： 通过使至少一种二价镍化合物与至少一种烃基铝卤化物，至少一种Bronsted有机酸和至少一种羧酸酐接触来获得改进的催化剂组合物。 该组合物可用作烯烃低聚催化剂。
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公开(公告)号：US4283305A
公开(公告)日：1981-08-11
申请号：US102488
申请日：1979-12-11
IPC分类号： C08F4/00 , B01J31/04 , B01J31/14 , C07B61/00 , C07C1/00 , C07C2/30 , C07C11/02 , C07C67/00 , C08F4/60
CPC分类号： C07C2/30 , B01J31/0231 , B01J31/04 , B01J31/143 , B01J2231/20 , C07C2531/04 , C07C2531/14
摘要： Catalyst composition for oligomerizing olefins, obtained by contacting (a) a bivalent nickel compound with (b) a hydrocarbylaluminum compound of the formula AIRCl.sub.2 where R is a monovalent hydrocarbon radical, and (c) a Bronsted acid consisting preferably of a halogenocarboxylic acid of the formula R.sub.1 COOH in which R.sub.1 is a halogenoalkyl radical of the formula C.sub.m H.sub.p X.sub.q, X being halogen, m an integer from 1 to 3, p being zero or an integer and q being an integer, the condition p+q=2m+1 being fulfilled. A preferred Bronsted acid is of the formula R.sub.2 COOH in which R.sub.2 is a halogenomethyl group of the formula CX.sub.n H.sub.3-n, X being halogen and n an integer from 1 to 3.
摘要翻译： 通过使（a）二价镍化合物与（b）式为AIRCl2的烃基铝化合物（其中R是一价烃基）接触获得的催化剂组合物，和（c）优选由以下组分的卤代羧酸组成的布朗斯台德酸 式R1COOH，其中R1是式CmHpXq的卤代烷基，X是卤素，m是1至3的整数，p是0或整数，q是整数，条件p + q = 2m + 1被满足 。 优选的布朗斯台德酸是式R 2 COOH，其中R 2是式CX n H 3-n的卤代甲基，X是卤素，n是1至3的整数。
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9.发明授权Process for the production of light alpha olefins by oligomerization of ethylene 失效通过乙烯低聚生产轻质α-烯烃的方法
公开(公告)号：US5345023A
公开(公告)日：1994-09-06
申请号：US88508
申请日：1993-07-09
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/38 , Y02P20/52
摘要： Process for oligomerizing ethylene into light alpha olefins, mainly 1-butene, 1-hexene, 1-octene and 1-decene, in which the ethylene is contacted with a catalyst obtained by mixing a zirconium compound with an organic compound chosen from within the class of acetals and ketals and with a chlorine or bromine-containing compound of aluminum hydrocarbyl.
摘要翻译： 将乙烯低聚成轻质α-烯烃，主要是1-丁烯，1-己烯，1-辛烯和1-癸烯的方法，其中乙烯与通过混合锆化合物与选自类中的有机化合物获得的催化剂接触 的缩醛和缩酮以及含有氯或溴的铝盐化合物。
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10.发明授权Non-aqueous liquid composition with an ionic character and its use as a solvent 失效非水性液体组合物，具有离子性，并作为溶剂使用
公开(公告)号：US5104840A
公开(公告)日：1992-04-14
申请号：US672236
申请日：1991-03-20
申请人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/24 , B01J31/28 , C07B61/00 , C07C2/32 , C07C11/02 , C07C15/12 , C07F5/06 , C08F10/00
CPC分类号： B01J31/24 , B01J31/0284 , B01J31/0288 , B01J31/1805 , C07F5/06 , C07F5/064 , C08F10/00 , B01J2231/20 , B01J2531/847 , B01J31/0239 , B01J31/0268 , B01J31/2234
摘要： A non-aqueous liquid composition with an ionic character resulting from the contacting of at least one alkylaluminum dihalide with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, said composition being liquid below 80.degree. C., for example, between -70.degree. and +40.degree. C., is useful as a solvent of catalysts for the dimerization, codimerization and oligomerization of olefins.
摘要翻译： 由至少一种烷基铝二卤化物与至少一种季铵卤化物和/或至少一种季鏻卤化物接触而产生的具有离子性质的非水性液体组合物，所述组合物在低于80℃的液体下，例如， 在-70℃至+ 40℃之间，可用作烯烃二聚，共聚和低聚的催化剂溶剂。
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