公开(公告)号：US20110217656A1

公开(公告)日：2011-09-08

申请号：US13040972

申请日：2011-03-04

Applicant: Yoshinori TAGUCHI ,  Noriaki WATANABE ,  Norio AOSHIMA

Inventor： Yoshinori TAGUCHI ,  Noriaki WATANABE ,  Norio AOSHIMA

IPC: G03F7/004 ,  G03F7/20

CPC classification number: G03F7/091 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  G03F7/095 ,  G03F7/11 ,  G03F7/12 ,  G03F7/322

Abstract: A positive-working lithographic printing plate precursor for infrared laser is provided that includes, layered sequentially above a support, a lower layer and an upper layer, the lower layer and/or the upper layer including an infrared absorbing agent, either the lower layer comprising an alkali-soluble group-containing graft copolymer or the upper layer comprising a sulfonamide group-, active imide group-, and/or amide group-containing graft copolymer, and the graft copolymer being a polyurethane resin having as a graft chain an ethylenically unsaturated monomer-derived constitutional unit. There is also provided a process for making a lithographic printing plate, the process including in sequence an exposure step of imagewise exposing by means of an infrared laser the positive-working lithographic printing plate precursor for infrared laser and a development step of developing using an aqueous alkali solution with a pH of 8.5 to 10.8.

Abstract translation: 提供一种用于红外激光的正性平版印刷版原版，其包括在支撑体，下层和上层之上顺序层叠，下层和/或上层包括红外线吸收剂，下层包含 含有碱溶性基团的接枝共聚物或含有磺酰胺基，活性酰亚胺基和/或酰胺基的接枝共聚物的上层，所述接枝共聚物是具有作为接枝链的烯属不饱和基团的聚氨酯树脂 单体衍生的结构单元。 还提供了一种制备平版印刷版的方法，该方法依次包括通过红外激光成像曝光的曝光步骤，用于红外激光的正性平版印刷版原版和使用水性显影的显影步骤 pH为8.5〜10.8的碱溶液。

公开(公告)号：US20160054654A1

公开(公告)日：2016-02-25

申请号：US14449166

申请日：2014-08-01

Applicant: Norio AOSHIMA

Inventor： Norio AOSHIMA

IPC: G03F7/30 ,  G03F7/20

CPC classification number: G03F7/30 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  G03F7/20 ,  G03F7/322

Abstract: Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R11, R12, and R13 each represent an alkyl group; R14 represents an alkylene group; and R15 represents a single bond or a divalent linking group containing a hetero atom; and R21, R22, and R23 each represent an alkyl group.

公开(公告)号：US20080229956A1

公开(公告)日：2008-09-25

申请号：US12051874

申请日：2008-03-20

Applicant: Norio AOSHIMA ,  Katsumi ARAKI

Inventor： Norio AOSHIMA ,  Katsumi ARAKI

IPC: B41M5/00

CPC classification number: B41C1/1008 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24

Abstract: A lithographic printing plate precursor, which is on-press developable by supplying an oily ink and an aqueous component, includes an image forming layer that has, in an exposed area thereof at 25° C., a water content change rate of 2.0 mass % or less when relative humidity is changed from 30% to 50%.

Abstract translation: 通过供给油性油墨和水性成分可压印显影的平版印刷版原版包括图像形成层，其曝光区域在25℃下的含水率变化率为2.0质量％ 或更低，当相对湿度从30％变为50％时。

公开(公告)号：US20160033868A1

公开(公告)日：2016-02-04

申请号：US14449165

申请日：2014-08-01

Applicant: Norio AOSHIMA

Inventor： Norio AOSHIMA

IPC: G03F7/30 ,  G03F7/20

CPC classification number: G03F7/30 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  G03F7/20 ,  G03F7/322

Abstract: Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R11, R12, and R13 each represent an alkyl group; R14 represents an alkylene group; and R15 represents a single bond or a divalent linking group containing a hetero atom; and R21, R22, and R23 each represent an alkyl group.

Abstract translation: 提供一种平版印刷版的制造方法，其特征在于，包括：对具有支撑体和正图像记录层的平版印刷版原版进行成像曝光; 并使用含有特定化合物的碱性水溶液显影，pH为8.5〜10.8。 记录层具有：含有水不溶性和碱溶性树脂和红外线吸收剂的下层; 和含有水不溶性和碱溶性聚氨酯树脂和聚有机硅氧烷的上层。 特定化合物是非离子或阴离子表面活性剂，或至少一种式（1）或（2）表示的化合物，其中R 11，R 12和R 13各自表示烷基; R14表示亚烷基; R 15表示单键或含有杂原子的二价连接基团; R 21，R 22和R 23各自表示烷基。

公开(公告)号：US20090246688A1

公开(公告)日：2009-10-01

申请号：US12412871

申请日：2009-03-27

Applicant: Norio AOSHIMA ,  Yu IWAI

Inventor： Norio AOSHIMA ,  Yu IWAI

IPC: G03F7/00

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  Y10S430/111 ,  Y10S430/145

Abstract: A negative-working lithographic printing plate precursor is disclosed that can be developed on the press without going through a development processing step, and a method of lithographic printing is also disclosed that uses this negative-working lithographic printing plate precursor. A negative-working lithographic printing plate precursor is provided that exhibits excellent on-press developability, nonimage area fine line reproducibility and printing durability and that resists the production of scum during on-press development. The negative-working lithographic printing plate precursor has a hydrophilic support and has thereon a photopolymerizable layer that contains at least one selected from the group consisting of a polymer compound that has an ethylenically unsaturated bond in the side chain position, a hydrophilic group and a sulfonamide group and a polymer compound that has an ethylenically unsaturated bond in the side chain position, a hydrophilic group and a cyclic structure derived from a maleimide. The method of lithographic printing uses this negative-working lithographic printing plate precursor.

Abstract translation: 公开了一种负性平版印刷版原版，其可以在印刷机上显影而不经过显影处理步骤，并且还公开了使用该负性平版印刷版原版的平版印刷方法。 提供了一种负性平版印刷版原版，其具有优异的印刷显影性，非图像区细线再现性和印刷耐久性，并且抵抗了印刷机中的浮渣的生成。 负性平版印刷版原版具有亲水性载体，并且具有可光聚合层，该光聚合层含有选自侧链位置具有烯属不饱和键的高分子化合物，亲水基和磺酰胺中的至少一种 基团和在侧链位置具有烯键式不饱和键的聚合物化合物，亲水基团和衍生自马来酰亚胺的环状结构。 平版印刷方法使用这种负性平版印刷版原版。

公开(公告)号：US20080286685A1

公开(公告)日：2008-11-20

申请号：US12119123

申请日：2008-05-12

Applicant: Norio AOSHIMA

Inventor： Norio AOSHIMA

IPC: G03F7/20

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22

Abstract: The invention provides a planographic printing plate precursor having at least: a support; and an image recording layer that is provided on the support, the image recording layer comprising: an infrared ray absorbing agent (A); a polymerization initiator (B); a polymerizable compound (C); and a compound (D) represented by the following Formula (I). In Formula (I), at least one of R1 to R3 represents —(CH2CH2O)n—R4, while the remainder of R1 to R3 respectively independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or R5—COOH; R4 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; n represents an integer of 1 to 20; and R5 represents an alkylene group having 1 to 6 carbon atoms. The invention further provides a printing method using the planographic printing plate precursor and performing on-press development.

Abstract translation: 本发明提供一种至少具有：支持体的平版印刷版前体， 以及设置在所述支撑体上的图像记录层，所述图像记录层包括：红外线吸收剂（A）; 聚合引发剂（B）; 可聚合化合物（C）; 和由下式（I）表示的化合物（D）。 在式（I）中，R 1至R 3中的至少一个表示 - （CH 2 CH 2 CH 2） 其中R 1〜R 3的其余部分分别独立地表示氢原子，R 1，R 2，R 3， ，具有1至4个碳原子的烷基或R 5 -COOH; R 4表示氢原子或具有1至4个碳原子的烷基; n表示1〜20的整数， R 5表示碳原子数1〜6的亚烷基。 本发明还提供一种使用平版印刷版原版的印刷方法，并进行印刷机的显影。

公开(公告)号：US20110200943A1

公开(公告)日：2011-08-18

申请号：US13027282

申请日：2011-02-15

Applicant: Norio AOSHIMA

Inventor： Norio AOSHIMA

IPC: G03F7/20

CPC classification number: G03F7/30 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  G03F7/20 ,  G03F7/322

Abstract: Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R11, R12, and R13 each represent an alkyl group; R14 represents an alkylene group; and R15 represents a single bond or a divalent linking group containing a hetero atom; and R21, R22, and R23 each represent an alkyl group.

Abstract translation: 提供一种平版印刷版的制造方法，其特征在于，包括：对具有支撑体和正图像记录层的平版印刷版原版进行成像曝光; 并使用含有特定化合物的碱性水溶液显影，pH为8.5〜10.8。 记录层具有：含有水不溶性和碱溶性树脂和红外线吸收剂的下层; 和含有水不溶性和碱溶性聚氨酯树脂和聚有机硅氧烷的上层。 特定化合物是非离子或阴离子表面活性剂，或至少一种式（1）或（2）表示的化合物，其中R 11，R 12和R 13各自表示烷基; R14表示亚烷基; R 15表示单键或含有杂原子的二价连接基团; R 21，R 22和R 23各自表示烷基。

公开(公告)号：US20100055613A1

公开(公告)日：2010-03-04

申请号：US12549549

申请日：2009-08-28

Applicant: Norio AOSHIMA ,  Kazuo MAEMOTO

Inventor： Norio AOSHIMA ,  Kazuo MAEMOTO

IPC: G03F7/20 ,  G03F7/004 ,  G03F7/26

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24

Abstract: A negative-working lithographic printing plate precursor is disclosed that can be developed on the press without going through a development processing step, and a method of lithographic printing is also disclosed that uses this negative-working lithographic printing plate precursor. Also disclosed are a negative-working lithographic printing plate precursor that can be developed by a water-soluble resin-containing aqueous solution and a method of lithographic printing that uses this negative-working lithographic printing plate precursor. A negative-working lithographic printing plate precursor is provided that exhibits an excellent fine line reproducibility in nonimage areas even when printing is performed using ultraviolet-curing ink (UV ink). Also provided is a negative-working lithographic printing plate precursor that exhibits an excellent combination of fine line reproducibility and printing durability and that resists the production of scum during on-press development. The negative-working lithographic printing plate precursor has a support and has thereon a photopolymerizable layer that contains a polymer compound that has the urea bond in the main chain and a hydrophilic group and a carboxylic acid content less than 0.05 meq/g. The method of lithographic printing uses this negative-working lithographic printing plate precursor.

Abstract translation: 公开了一种负性平版印刷版原版，其可以在印刷机上显影而不经过显影处理步骤，并且还公开了使用该负性平版印刷版原版的平版印刷方法。 还公开了可以通过含水溶性树脂的水溶液显影的负性平版印刷版原版和使用该负性平版印刷版原版的平版印刷法。 即使在使用紫外线固化油墨（UV油墨）进行印刷的情况下，也提供了在非图像区域中表现出优异的细线再现性的负性平版印刷版原版。 还提供了一种负极平版印刷版原版，其显示细线再现性和印刷耐久性的优异组合，并且抵抗了印刷机中的浮渣的生成。 负性平版印刷版原版具有支撑体，在其上具有包含在主链中具有尿素键的亲水性基团和羧酸含量小于0.05meq / g的高分子化合物的光聚合性层。 平版印刷方法使用这种负性平版印刷版原版。

公开(公告)号：US20080233516A1

公开(公告)日：2008-09-25

申请号：US12053780

申请日：2008-03-24

Applicant: Yu IWAI ,  Norio AOSHIMA

Inventor： Yu IWAI ,  Norio AOSHIMA

IPC: G03F7/12 ,  G03F7/004

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/033 ,  G03F7/3035

Abstract: A negative lithographic printing plate precursor includes a support; and a photo-polymerization layer containing a polymer compound having at least one of a sulfonamido group and a cyclic structure derived from maleimide, and further having a hydrophilic group in a molecule thereof

Abstract translation: 负版印刷版原版包括载体; 以及光聚合层，其含有具有亚磺酰氨基和由马来酰亚胺衍生的环状结构中的至少一种的高分子化合物，并且在其分子中还具有亲水基团