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公开(公告)号：US5367098A
公开(公告)日：1994-11-22
申请号：US47812
申请日：1993-04-15
申请人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
发明人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
IPC分类号： B01J23/04 , B01J27/232 , C07B61/00 , C07C2/72 , C07C15/44
CPC分类号： B01J27/232 , B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04
摘要： A process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at an .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising a mixture obtained by heat treating metallic sodium together with a mixture of an aluminum oxide and a potassium compound in an inert gas atmosphere. The process produces a commercially useful monoalkenyl aromatic hydrocarbon compounds in a high yields and at a low cost with enhanced safety.
摘要翻译： 一种单链烯基芳族烃化合物的制造方法，其特征在于，将具有至少一个在侧链的α位键合的氢原子（例如二甲苯）的芳香族烃化合物的侧链与具有4或5个碳原子的共轭二烯 在包含通过在惰性气体气氛中将金属钠与氧化铝和钾化合物的混合物一起热处理获得的混合物的催化剂存在下的原子（例如丁二烯）。 该方法以高产率和低成本产生商业上可用的单链烯基芳族烃化合物，具有增强的安全性。
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公开(公告)号：US5344806A
公开(公告)日：1994-09-06
申请号：US011216
申请日：1993-01-29
申请人： Norio Fushimi , Kenji Inamasa , Makoto Takagawa
发明人： Norio Fushimi , Kenji Inamasa , Makoto Takagawa
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/10 , C07C2523/02 , C07C2523/04
摘要： There is disclosed a process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising the mixture obtained by heat treating metallic sodium together with an alkaline earth metal oxide containing a potassium compound in the atmosphere of an inert gas. According to the aforesaid process, a monoalkenyl aromatic hydrocarbon compound such as industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.
摘要翻译： 公开了一种单烯基芳族烃化合物的制造方法，该方法包括使具有至少一个在侧链（例如二甲苯）的α位键合的氢原子的芳族烃化合物的侧链与具有4或 在包含通过在惰性气体气氛中将金属钠与含有钾化合物的碱土金属氧化物一起热处理的混合物的催化剂存在下，将5个碳原子（例如丁二烯）。 根据上述方法，可以以低成本高产率生产工业上可用的单链烯基单链烯基芳烃化合物，从特定的芳族烃化合物和特定的共轭二烯化合物的安全性提高。
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公开(公告)号：US5276230A
公开(公告)日：1994-01-04
申请号：US944363
申请日：1992-09-14
申请人： Kenji Inamasa , Norio Fushimi , Makoto Takagawa
发明人： Kenji Inamasa , Norio Fushimi , Makoto Takagawa
摘要： There is disclosed a process for efficiently producing 2,6-dimethylnaphthalene used for the production of polyethylene naphthalate which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as a starting raw material to cyclization dehydrogenation reaction by the use of a catalyst comprising a platinum component and at least one component selected from the group consisting of alkali metals and alkaline earth metals each being supported on aluminum oxide. The above process enables the production of the objective compound in a high yield at a low cost by using the catalyst having high safety and stability from the widely available starting material, thereby enhancing the industrial significance of the process.
摘要翻译： 公开了一种有效生产用于生产聚萘二甲酸乙二醇酯的2,6-二甲基萘的方法，该方法包括使2-甲基-1-（对甲苯基）丁烯和/或2-甲基-1-（对甲苯基）丁烷 作为起始原料，通过使用包含铂成分和至少一种选自碱金属和碱土金属的组分的催化剂进行环化脱氢反应，所述碱金属和碱土金属各自负载在氧化铝上。 上述方法能够通过使用来自广泛可得的原料的高安全性和稳定性的催化剂以低成本高产率生产目标化合物，从而提高了该方法的工业意义。
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公开(公告)号：US5444172A
公开(公告)日：1995-08-22
申请号：US170493
申请日：1993-12-20
申请人： Makoto Takagawa , Kenji Inamasa , Norio Fushimi , Akio Hashimoto , Takayo Sasaki
发明人： Makoto Takagawa , Kenji Inamasa , Norio Fushimi , Akio Hashimoto , Takayo Sasaki
IPC分类号： B01J23/04 , B01J27/232 , C07B61/00 , C07C2/72 , C07C15/44
CPC分类号： B01J27/232 , B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04 , C07C2527/232 , Y02P20/52
摘要： There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of a basic potassium compound and alumina and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.
摘要翻译： 公开了一种单链烯基苯的制备方法，该方法包括将具有至少一个在侧链（例如二甲苯）的α位键合的氢原子的芳族烃化合物的侧链与具有4或5个碳原子的共轭二烯链烯基化 （例如丁二烯）在通过煅烧碱性钾化合物和氧化铝的混合物产生的催化剂存在下，然后在惰性气体气氛中将煅烧产物与金属钠一起热处理。 根据上述方法，可以低成本，高安全性地以高产率生产工业上有用的单烯基苯。
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公开(公告)号：US5334794A
公开(公告)日：1994-08-02
申请号：US47811
申请日：1993-04-15
申请人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
发明人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/06 , C07C2523/04
摘要： A process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at an .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising a mixture obtained by heat treating metallic sodium together with a mixture of a zirconium oxide and a potassium compound in an inert gas atmosphere. An industrially useful monoalkenyl aromatic hydrocarbon compound is produced in a high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.
摘要翻译： 一种单链烯基芳族烃化合物的制造方法，其特征在于，将具有至少一个在侧链的α位键合的氢原子（例如二甲苯）的芳香族烃化合物的侧链与具有4或5个碳原子的共轭二烯 在包含通过在惰性气体气氛中将金属钠与氧化锆和钾化合物的混合物一起热处理获得的混合物的催化剂存在下的原子（例如丁二烯）。 以低成本高产率生产工业上有用的单链烯基芳烃化合物，从特定芳烃化合物和特定共轭二烯化合物的安全性提高。
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公开(公告)号：US5321178A
公开(公告)日：1994-06-14
申请号：US6807
申请日：1993-01-21
申请人： Kenji Inamasa , Norio Fushimi , Makoto Takagawa
发明人： Kenji Inamasa , Norio Fushimi , Makoto Takagawa
CPC分类号： C07C5/417
摘要： A process for efficiently producing 2,6-dimethylnaphthalene which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as the starting raw material to a cyclization dehydrogenation reaction in the presence of a catalyst comprising (a) a palladium component, (b) an alkali or alkaline earth metal compound and (c) aluminum oxide. The process enables the production of highly pure 2,6-dimethylnaphthalene in a high yield at a low cost. The catalyst used in the process affords high safety and stability.
摘要翻译： 一种有效生产2,6-二甲基萘的方法，包括使2-甲基-1-（对甲苯基）丁烯和/或2-甲基-1-（对甲苯基）丁烷作为起始原料进行环化脱氢反应 在包含（a）钯组分，（b）碱金属或碱土金属化合物和（c）氧化铝的催化剂的存在下。 该方法能够以低成本高产率生产高纯度2,6-二甲基萘。 在该方法中使用的催化剂提供高安全性和稳定性。
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公开(公告)号：US5599981A
公开(公告)日：1997-02-04
申请号：US590598
申请日：1996-01-24
申请人： Norio Fushimi , Kenichi Nakamura , Makoto Takagawa
发明人： Norio Fushimi , Kenichi Nakamura , Makoto Takagawa
摘要： Provided is a process for producing alkylbenzoyl chloride which comprises reacting alkylbenzaldehyde with chlorine at a temperature of -10.degree. to 80.degree. C. under a pressure of 5 kg/cm.sup.2 or below in a liquid phase, whereby alkylbenzoyl chloride can be produced in a high yield and at a low price.
摘要翻译： 本发明提供烷基苯甲酰氯的制造方法，其特征在于，在液相中，在压力为5kg / cm 2以下的压力下，在-10℃〜80℃的温度下使烷基苯甲醛与氯反应，由此能够高效地生成烷基苯甲酰氯 收益率低廉。
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公开(公告)号：US06504069B1
公开(公告)日：2003-01-07
申请号：US09504042
申请日：2000-02-14
申请人： Youichi Kyuuko , Norio Fushimi , Makoto Takagawa
发明人： Youichi Kyuuko , Norio Fushimi , Makoto Takagawa
IPC分类号： C07C1328
CPC分类号： C07C5/31 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2527/054 , C07C2527/173 , C07C2529/04 , C07C13/48
摘要： 5-Tolyl-pent-2-ene is cyclized in liquid phase in the present of an aliphatic hydrocarbon to produce the corresponding dimethyltetralin. The use of the aliphatic hydrocarbon effectively prevents a side reaction such as dimerization of 5-tolyl-pent-2-ene to provide dimethyltetralin in a high yield. Also, 5-tolyl-pent-2-ene is cyclized in liquid phase or vapor phase in the presence of a catalyst comprising a carrier supporting sulfate ions to produce the corresponding dimethyltetralin. The catalyst supporting sulfate ions shows a high catalytic activity event at low temperatures. Therefore, the cyclization of 5-tolyl-pent-2-ene is conducted in a wide temperature range from low temperatures to high temperatures.
摘要翻译： 在脂肪族烃的存在下，5-甲苯基戊-2-烯在液相中环化，生成相应的二甲基儿茶素。 脂肪烃的使用有效地防止了5-甲苯基戊-2-烯的二聚反应，从而提供高产率的二甲基儿茶素。 此外，5-甲苯基戊-2-烯在含有支持硫酸根离子的载体的催化剂存在下在液相或气相中环化，生成相应的二甲基四氢化萘。 支持硫酸根离子的催化剂在低温下显示出高催化活性。 因此，5-甲苯基戊-2-烯的环化在从低温到高温的宽温度范围内进行。
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公开(公告)号：US5659097A
公开(公告)日：1997-08-19
申请号：US371301
申请日：1995-01-11
申请人： Norio Fushimi , Makoto Takagawa
发明人： Norio Fushimi , Makoto Takagawa
CPC分类号： C07C15/40 , B01J23/04 , B01J31/00 , C07C2/72 , C07C2521/04 , C07C2521/06 , C07C2521/18 , C07C2523/02 , C07C2523/04 , C07C2527/167 , C07C2527/232
摘要： A process for producing a monoalkenyl aromatic hydrocarbon which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom at the .alpha.-position of a side chain (such as o-xylene) with a conjugated diene having 4 or 5 carbon atoms in the presence of a catalyst slurry prepared by adding an aromatic hydrocarbon compound to a catalyst comprising a alkali metal and an alkali metal compound. In the aforementioned process, it is particularly effective that the catalyst slurry is prepared by adding the aromatic hydrocarbon compound after the aromatic hydrocarbon compound has been deoxygenated and dehydrated by distillation, and the catalyst slurry thus prepared is supplied to the reaction system. According to the aforementioned process, an industrially useful monoalkenyl aromatic hydrocarbon compound, such as a monoalkenylbenzene, can be produced at a high selectivity, in a high yield, and with enhanced safety and stability for a long time.
摘要翻译： 一种单链烯基芳族烃的制造方法，其包括在侧链（例如邻二甲苯）的α-位上具有至少一个氢原子的芳族烃化合物的侧链与具有4或5个碳原子的共轭二烯链烯基化 在通过将芳族烃化合物加入到包含碱金属和碱金属化合物的催化剂中制备的催化剂浆料存在下进行。 在上述方法中，特别有效的是，通过在芳烃化合物已经脱氧并通过蒸馏脱水之后，通过加入芳族烃化合物制备催化剂浆料，并将由此制备的催化剂浆料供应到反应体系。 根据上述方法，工业上可用的单链烯基芳烃化合物如单烯基苯可以高选择性，高产率，长时间提高安全性和稳定性而制备。
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公开(公告)号：US5436381A
公开(公告)日：1995-07-25
申请号：US170495
申请日：1993-12-20
申请人： Makoto Takagawa , Kinji Kato , Norio Fushimi , Ko Kedo
发明人： Makoto Takagawa , Kinji Kato , Norio Fushimi , Ko Kedo
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04
摘要： There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of potassium hydroxide and aluminum hydroxide and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.
摘要翻译： 公开了一种单链烯基苯的制备方法，该方法包括将具有至少一个在侧链（例如二甲苯）的α位键合的氢原子的芳族烃化合物的侧链与具有4或5个碳原子的共轭二烯链烯基化 （例如丁二烯）在通过煅烧氢氧化钾和氢氧化铝的混合物产生的催化剂存在下，然后在惰性气体气氛中与金属钠一起热处理煅烧产物。 根据上述方法，可以低成本，高安全性地以高产率生产工业上有用的单烯基苯。
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