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    Organometallic complexes
    1.
    发明申请
    Organometallic complexes 失效
    有机金属配合物

    公开(公告)号：US20100264380A1

    公开(公告)日：2010-10-21

    申请号：US11654773

    申请日：2007-01-18

    申请人： Norman Herron ,  Steven W. Shuey ,  Jeffrey A. Merlo

    发明人： Norman Herron ,  Steven W. Shuey ,  Jeffrey A. Merlo

    IPC分类号： H01B1/12 ,  C07F15/00

    CPC分类号： H01L51/5016 ,  C09K11/06 ,  C09K2211/186 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5048 ,  H05B33/20

    摘要： The present disclosure relates to organometallic complexes and electronic devices containing the complexes. The complexes have the formula MYnZ, where n is 1, 2, or 3; M is a metal in a +2, +3, or +4 oxidation state, Y is selected from an 8-hydroxyquinolate and a substituted 8-hydroxyquinolate, and Z is a phenolate. At least one Y is a substituted 8-hydroxyquinolate having the formula where: R1 and R2 are the same or different at each occurrence and each represents one or more of a substituent selected from the group consisting of H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkylaryl, alkoxy, aryloxy, fluoroalkoxy, fluoroaryloxy, heteroalkyl, fluoroheteroalkyl, heteroaryl, fluoroheteroaryl, heteroalkylaryl, heteroalkoxy, heteroaryloxy, fluoroheteroalkoxy, fluoroheteroaryloxy, a solvent-solubilizing group, and a Tg enhancing group, wherein at least one of R1 and R2 is a solvent-solubilizing or Tg enhancing group; and R3 is selected from the group consisting of H, an alkyl group, and a substituted alkyl group.

    摘要翻译： 本公开涉及含有该配合物的有机金属配合物和电子装置。 络合物具有式MYnZ，其中n为1,2或3; M是+2，+3或+4氧化态的金属，Y选自8-羟基喹啉酸盐和取代的8-羟基喹喔啉，Z是酚盐。 至少一个Y是具有下式的取代的8-羟基喹诺酸盐：其中：R1和R2在每次出现时相同或不同，并且各自表示一个或多个选自H，烷基，氟代烷基，芳基，氟代芳基 烷基芳基，烷氧基，芳氧基，氟代烷氧基，氟芳氧基，杂烷基，氟杂芳基，杂芳基，氟杂芳基，杂烷基芳基，杂烷氧基，杂芳氧基，氟代杂环氧基，氟代杂芳基氧基，溶剂增溶基团和Tg增强基团，其中R1和R2中的至少一个是 溶剂增溶或Tg增强基团; 并且R 3选自H，烷基和取代的烷基。

    Organometallic complexes
    2.
    发明授权
    Organometallic complexes 失效
    有机金属配合物

    公开(公告)号：US08470208B2

    公开(公告)日：2013-06-25

    申请号：US11654773

    申请日：2007-01-18

    申请人： Norman Herron ,  Steven W. Shuey ,  Jeffrey A. Merlo

    发明人： Norman Herron ,  Steven W. Shuey ,  Jeffrey A. Merlo

    IPC分类号： H01B1/12 ,  H01L29/08 ,  H01J1/62 ,  C09K11/06 ,  C07D215/30

    CPC分类号： H01L51/5016 ,  C09K11/06 ,  C09K2211/186 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5048 ,  H05B33/20

    摘要： The present disclosure relates to organometallic complexes and electronic devices containing the complexes. The complexes have the formula MYnZ, where n is 1, 2, or 3; M is a metal in a +2, +3, or +4 oxidation state, Y is selected from an 8-hydroxyquinolate and a substituted 8-hydroxyquinolate, and Z is a phenolate. At least one Y is a substituted 8-hydroxyquinolate having the formula where: R1 and R2 are the same or different at each occurrence and each represents one or more of a substituent selected from the group consisting of H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkylaryl, alkoxy, aryloxy, fluoroalkoxy, fluoroaryloxy, heteroalkyl, fluoroheteroalkyl, heteroaryl, fluoroheteroaryl, heteroalkylaryl, heteroalkoxy, heteroaryloxy, fluoroheteroalkoxy, fluoroheteroaryloxy, a solvent-solubilizing group, and a Tg enhancing group, wherein at least one of R1 and R2 is a solvent-solubilizing or Tg enhancing group; and R3 is selected from the group consisting of H, an alkyl group, and a substituted alkyl group.

    摘要翻译： 本公开涉及含有该配合物的有机金属配合物和电子装置。 络合物具有式MYnZ，其中n为1,2或3; M是+2，+3或+4氧化态的金属，Y选自8-羟基喹啉酸盐和取代的8-羟基喹喔啉，Z是酚盐。 至少一个Y是具有下式的取代的8-羟基喹诺酸盐：其中：R1和R2在每次出现时相同或不同，并且各自表示一个或多个选自H，烷基，氟代烷基，芳基，氟代芳基 烷基芳基，烷氧基，芳氧基，氟代烷氧基，氟芳氧基，杂烷基，氟杂芳基，杂芳基，氟杂芳基，杂烷基芳基，杂烷氧基，杂芳氧基，氟代杂环氧基，氟代杂芳基氧基，溶剂增溶基团和Tg增强基团，其中R1和R2中的至少一个是 溶剂增溶或Tg增强基团; 并且R 3选自H，烷基和取代的烷基。

    ELECTRONIC DEVICE INCLUDING PHENANTHROLINE DERIVATIVE
    9.
    发明申请
    ELECTRONIC DEVICE INCLUDING PHENANTHROLINE DERIVATIVE 失效
    包括苯并噻吩衍生物的电子器件

    公开(公告)号：US20100207108A1

    公开(公告)日：2010-08-19

    申请号：US12644362

    申请日：2009-12-22

    申请人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

    发明人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

    IPC分类号： H01L51/54 ,  C07D471/04

    CPC分类号： C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

    摘要： There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R2═R3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R2 is H or phenyl; and R3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R1 are phenyl, R2 and R3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

    摘要翻译： 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 并且符合以下条件之一：（i）R 2 = R 3且为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。