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公开(公告)号：US08148465B2
公开(公告)日：2012-04-03
申请号：US12517723
申请日：2007-12-04
申请人： Oliver Minge , Peter Ball , Martin Bortenschlager
发明人： Oliver Minge , Peter Ball , Martin Bortenschlager
摘要： The invention relates to a process for free-radically initiated heterophase polymerization, in which the polymerization of ethylenically monomers proceeds in a phase dispersed in the continuous phase, characterized in that one or more additives which are soluble in the continuous phase and insoluble in the disperse phase and stop the polymerization of the ethylenically unsaturated monomers in the continuous phase is/are added before or during the polymerization.
摘要翻译： 本发明涉及一种自由基引发的异相聚合方法，其中烯键式单体的聚合在分散在连续相中的相中进行，其特征在于一种或多种可溶于连续相并且不溶于分散体的添加剂 在聚合之前或聚合过程中加入相和停止烯键式不饱和单体在连续相中的聚合。
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公开(公告)号：US20100081765A1
公开(公告)日：2010-04-01
申请号：US12517723
申请日：2007-12-04
申请人： Oliver Minge , Peter Ball , Martin Bortenschlager
发明人： Oliver Minge , Peter Ball , Martin Bortenschlager
摘要： The invention relates to a process for free-radically initiated heterophase polymerization, in which the polymerization of ethylenically monomers proceeds in a phase dispersed in the continuous phase, characterized in that one or more additives which are soluble in the continuous phase and insoluble in the disperse phase and stop the polymerization of the ethylenically unsaturated monomers in the continuous phase is/are added before or during the polymerization.
摘要翻译： 本发明涉及一种自由基引发的异相聚合方法，其中烯键式单体的聚合在分散在连续相中的相中进行，其特征在于一种或多种可溶于连续相并且不溶于分散体的添加剂 在聚合之前或聚合过程中加入相和停止烯键式不饱和单体在连续相中的聚合。
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公开(公告)号：US20100331483A1
公开(公告)日：2010-12-30
申请号：US12918590
申请日：2009-01-30
IPC分类号： C09D183/06
摘要： Polymer blends containing polymers or low molecular weight compounds containing groups of the formula ≡Si—O—C(R1)(R2)(R3) where R1, R2, and R3 are hydrogen, halogen, or an organic radical, not more than two of which are hydrogen, may be cured thermally or photochemically to produce solvent resistant polymers. The curing may take place in the absence of water.
摘要翻译： 含有含≡Si-O-C（R1）（R2）（R3）基团的聚合物或低分子量化合物的聚合物共混物，其中R 1，R 2和R 3为氢，卤素或有机基团，不大于2 其中的氢可以热或光化学固化以产生耐溶剂聚合物。 固化可能在没有水的情况下进行。
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公开(公告)号：US09074032B2
公开(公告)日：2015-07-07
申请号：US13262170
申请日：2010-03-23
IPC分类号： B01D61/00 , B01D39/00 , B01D39/14 , D01D5/06 , D01D5/24 , D01F6/14 , C08F216/08 , B01D61/36 , B01D67/00 , B01D71/38 , B01D71/70 , C08F230/08
CPC分类号： C08F216/08 , B01D61/362 , B01D67/0006 , B01D71/38 , B01D71/70 , B01D2323/30 , C08F230/08
摘要： The invention relates to the use of silane-modified polyvinyl alcohols for producing membranes, characterized in that the silane-modified polyvinyl alcohols can be obtained by a) radically initiated copolymerization of one or more vinyl esters from unbranched or branched carboxylic acids having 1 to 15 C-atoms and one or more ethylenically unsaturated silane compounds selected from the group comprising compounds of the general formulae CR2=CR—B—Si(OR′)3-n(R″)n (1), or CR2=CRC(═O)-D-B—Si(OR′)3-n(R″)n (2), wherein B is an aryl, heteroaryl or (CR2) m residue, wherein one or more non-neighboring CR2 groups can be replaced by heteroatoms as applicable, D is a heteroatom, R is a hydrogen atom, an alkyl or aryl residue or a heteroatom that is substituted as applicable by a hydrogen atom or an alkyl, aryl residue, OR is an alkoxy, alkylcarboxy or arylcarboxy residue, R″ is an alkyl or aryl residue and n 0, 1 or 2 and in 0 to 15, and b) subsequent saponification of the silane-modified vinyl ester copolymerizate obtained in step a).
摘要翻译： 本发明涉及硅烷改性的聚乙烯醇用于生产膜的用途，其特征在于，硅烷改性的聚乙烯醇可以通过以下方式获得：a）一种或多种乙烯基酯从1至15的无支链或支链羧酸的自由引发共聚 （OR'）3-n（R“）n（1）的化合物或CR2 = CRC（= 0）的一种或多种烯键式不饱和硅烷化合物，所述硅烷化合物选自通式为CR2 = CR-B-Si O）-DB-Si（OR'）3-n（R“）n（2），其中B是芳基，杂芳基或（CR 2）m残基，其中一个或多个不相邻的CR 2基团可被杂原子 如适用的，D是杂原子，R是氢原子，烷基或芳基残基或被氢原子或烷基，芳基残基所适用的取代的杂原子，OR是烷氧基，烷基羧基或芳基羧基残基，R“ 是烷基或芳基残基，n 0，1或2，0至15，b）随后皂化硅烷 - 在步骤a）中获得的改性乙烯基酯共聚物。
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公开(公告)号：US08748553B2
公开(公告)日：2014-06-10
申请号：US13813872
申请日：2011-08-08
IPC分类号： C08G77/08
CPC分类号： C08K5/09 , C08G77/12 , C08G77/14 , C08G77/20 , C08K11/00 , C08L83/04 , Y10T428/31663 , C08L83/00
摘要： Composite materials contain a silicone addition crosslinkable silicone elastomer composition comprising an organopolysiloxane having aliphatic unsaturation, an Si—H functional cyclic organopolysiloxane, a hydrosilylation catalyst, together with specific adhesion promoters, applied to a substrate material.
摘要翻译： 复合材料包含硅氧烷添加的可交联硅氧烷弹性体组合物，其包含具有脂肪族不饱和键的有机聚硅氧烷，Si-H官能的环状有机聚硅氧烷，氢化硅烷化催化剂以及施加到基材的特定的粘合促进剂。
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公开(公告)号：US20130130041A1
公开(公告)日：2013-05-23
申请号：US13813872
申请日：2011-08-08
CPC分类号： C08K5/09 , C08G77/12 , C08G77/14 , C08G77/20 , C08K11/00 , C08L83/04 , Y10T428/31663 , C08L83/00
摘要： Composite materials contain a silicone addition crosslinkable silicone elastomer composition comprising an organopolysiloxane having aliphatic unsaturation, an Si—H functional cyclic organopolysiloxane, a hydrosilylation catalyst, together with specific adhesion promoters, applied to a substrate material.
摘要翻译： 复合材料包含硅氧烷添加的可交联硅氧烷弹性体组合物，其包含具有脂肪族不饱和键的有机聚硅氧烷，Si-H官能的环状有机聚硅氧烷，氢化硅烷化催化剂以及施加到基材的特定的粘合促进剂。
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公开(公告)号：US20120031843A1
公开(公告)日：2012-02-09
申请号：US13262170
申请日：2010-03-23
CPC分类号： C08F216/08 , B01D61/362 , B01D67/0006 , B01D71/38 , B01D71/70 , B01D2323/30 , C08F230/08
摘要： The invention relates to the use of silane-modified polyvinyl alcohols for producing membranes, characterized in that the silane-modified polyvinyl alcohols can be obtained by a) radically initiated copolymerization of one or more vinyl esters from unbranched or branched carboxylic acids having 1 to 15 C-atoms and one or more ethylenically unsaturated silane compounds selected from the group comprising compounds of the general formulae CR2═CR—B—Si(OR′)3-n(R″)n (1), or CR2═CRC (═0)-D-B—Si(OR′)3-n(R″)n (2), wherein B is an aryl, heteroaryl or (CR2)m residue, wherein one or more non-neighboring CR2 groups can be replaced by heteroatoms as applicable, D is a heteroatom, R is a hydrogen atom, an alkyl or aryl residue or a heteroatom that is substituted as applicable by a hydrogen atom or an alkyl, aryl residue, OR′ is an alkoxy, alkylcarboxy or arylcarboxy residue, R″ is an alkyl or aryl residue and n 0, 1 or 2 and in 0 to 15, and b) subsequent saponification of the silane-modified vinyl ester copolymerisate obtained in step a).
摘要翻译： 本发明涉及硅烷改性的聚乙烯醇用于生产膜的用途，其特征在于，硅烷改性的聚乙烯醇可以通过以下方式获得：a）一种或多种乙烯基酯从1至15的无支链或支链羧酸的自由引发共聚 碳原子和一个或多个烯属不饱和硅烷化合物，其选自通式为CR 2 = CR-B-Si（OR'）3-n（R“）n（1）的化合物或CR 2 = CRC（= 0）-DB-Si（OR'）3-n（R“）n（2），其中B是芳基，杂芳基或（CR 2）m残基，其中一个或多个不相邻的CR 2基团可被杂原子 如适用的，D是杂原子，R是氢原子，烷基或芳基残基或被氢原子或烷基，芳基残基可以被取代的杂原子，OR'是烷氧基，烷基羧基或芳基羧基残基，R “是烷基或芳基残基，n 0，1或2，0至15，和b）随后的皂化 在步骤a）中获得的硅烷改性的乙烯基酯共聚物。
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