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公开(公告)号：US08242312B2
公开(公告)日：2012-08-14
申请号：US12944802
申请日：2010-11-12
IPC分类号： C07C317/00 , C07C31/00 , E21B43/22
CPC分类号： C07C271/20 , C07C271/14 , C07C275/14 , C07C309/08
摘要： The present invention comprises a compound of a compound of Formula 1 wherein Rf is a C2 to C12 perfluoroalkyl optionally interrupted by one to four moieties each independently selected from the group consisting of —CH2—, —O—, —S—, —S(O)—, and —S(O)2—; n is 1 to 6; m is 0 to 2, provided that m is less than or equal to n. X and Y are each independently O or NR, R is hydrogen or C1 to C6 alkyl; R1, and R2 are each independently C1 to C6 alkyl, optionally containing one or more oxygen atoms and may form a ring selected from the group of piperidine, pyrrolidine, and morpholine; and R3 is O−, (CH2)pC(O)O−, (CH2)pCH(OH)(CH2)SO3−, and (CH2)qSO3−; p is 1 to 4; and q is 2 to 4 which is useful as a surfactant.
摘要翻译： 本发明包括式1化合物的化合物，其中R f是任选地被一至四个部分间隔的C 2至C 12全氟烷基，其各自独立地选自-CH 2 - ， - O - ， - S - ， - S（ O） - 和-S（O）2 - ; n为1至6; m为0〜2，条件是m小于或等于n。 X和Y各自独立地为O或NR，R为氢或C 1至C 6烷基; R1和R2各自独立地为C1-C6烷基，任选地含有一个或多个氧原子，并且可以形成选自哌啶，吡咯烷和吗啉的环; 并且R 3是O-，（CH 2）p C（O）O-，（CH 2）p CH（OH）（CH 2）SO 3 - 和（CH 2）q SO 3 - ; p为1〜4; q为2〜4，可用作表面活性剂。
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公开(公告)号：US20120122999A1
公开(公告)日：2012-05-17
申请号：US12944802
申请日：2010-11-12
IPC分类号： C07C269/00 , C07C273/02 , C08K5/17 , C09D7/00 , C09D11/00 , C11D3/26 , C09K3/14 , C25D9/00 , C09K15/20 , C09K13/00 , A01N25/02 , B23K35/34 , C09K8/60 , C09K8/22 , C09K3/00 , C07C229/02
CPC分类号： C07C271/20 , C07C271/14 , C07C275/14 , C07C309/08
摘要： The present invention comprises a compound of a compound of Formula 1 wherein Rf is a C2 to C12 perfluoroalkyl optionally interrupted by one to four moieties each independently selected from the group consisting of —CH2—, —O—, —S—, —S(O)—, and —S(O)2—; n is 1 to 6; m is 0 to 2, provided that m is less than or equal to n. X and Y are each independently O or NR, R is hydrogen or C1 to C6 alkyl; R1, and R2 are each independently C1 to C6 alkyl, optionally containing one or more oxygen atoms and may form a ring selected from the group of piperidine, pyrrolidine, and morpholine; and R3 is O−, (CH2)pC(O)O−, (CH2)pCH(OH)(CH2)SO3−, and (CH2)qSO3−; p is 1 to 4; and q is 2 to 4 which is useful as a surfactant.
摘要翻译： 本发明包括式1化合物的化合物，其中R f是任选地被一至四个部分间隔的C 2至C 12全氟烷基，其各自独立地选自-CH 2 - ， - O - ， - S - ， - S（ O） - 和-S（O）2 - ; n为1至6; m为0〜2，条件是m小于或等于n。 X和Y各自独立地为O或NR，R为氢或C 1至C 6烷基; R1和R2各自独立地为C1-C6烷基，任选地含有一个或多个氧原子，并且可以形成选自哌啶，吡咯烷和吗啉的环; 并且R 3是O-，（CH 2）p C（O）O-，（CH 2）p CH（OH）（CH 2）SO 3 - 和（CH 2）q SO 3 - ; p为1〜4; q为2〜4，可用作表面活性剂。
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公开(公告)号：US20100099837A1
公开(公告)日：2010-04-22
申请号：US12254954
申请日：2008-10-21
IPC分类号： C08F22/10
CPC分类号： C08G65/007 , C08G65/331 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diester surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 to about 43, X is O, S, or SCH2CH2O, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf[OCF2CF2]r(CgH2g)—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—; or RfOY—; Y is CFHCF2O(CH2CH2O)v—(CgH2g)—; CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; each Rf is independently CcF(2c+1) wherein c is 1 to about 6; d is 1 to about 3; g is 1 to about 4; s is 0 or 1; r is 1 to about 4; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—is from about 8 to about 22; v is 1 to about 4; and w is from about 2 to about 12.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酯表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜约43，X为O，S或SCH 2 CH 2 O，Ra为Rf（CH 2 CF 2）d - （CgH2g） - ; Rf [OCF2CF2] r（CgH2g） - ; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; 或RfOY-; Y是CFHCF2O（CH2CH2O）v-（CgH2g） - ; CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 每个Rf独立地为CcF（2c + 1），其中c为1至约6; d为1〜3; g为1至约4; s为0或1; r为1〜4; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 条件是Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-中的碳原子总数为约8至约22; v为1至约4; w为约2至约12。
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公开(公告)号：US08026289B2
公开(公告)日：2011-09-27
申请号：US12255067
申请日：2008-10-21
CPC分类号： C08G65/33306 , C08G65/324 , C08G65/326 , C08G65/33317 , C08G65/33334 , C08G65/3348 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diamide surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 about 43, each X is independently NR, SCH2CH2NR, SO2NRCH2CH2NR, or SO2CH2CH2NR; R is hydrogen, or a linear or branched alkyl group CbH(2b+1) wherein b is 1 to about 18, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf(OCF2CF2)r—(CgH2g)—; RfOY—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—; Rf(CgH2g)—; or H(CcF2c)—(CgH2g)—; Y is CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; and each Rf is independently CcF(2c+1) wherein c is 1 to about 6.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酰胺表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜43，各X独立地为NR，SCH2CH2NR，SO2NRCH2CH2NR或SO2CH2CH2NR; R为氢，或直链或支链烷基CbH（2b + 1），其中b为1至约18，Ra为Rf（CH2CF2）d-（CgH2g） - ; Rf（OCF2CF2）r-（CgH2g） - ; RfOY-; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; Rf（CgH2g） - ; 或H（CcF2c） - （CgH2g） - ; Y为CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 并且每个Rf独立地为CcF（2c + 1），其中c为1至约6。
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公开(公告)号：US08022107B2
公开(公告)日：2011-09-20
申请号：US12254954
申请日：2008-10-21
CPC分类号： C08G65/007 , C08G65/331 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diester surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 to about 43, X is O, S, or SCH2CH2O, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf[OCF2CF2]r(CgH2g)—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k-; or RfOY—; Y is CFHCF2O(CH2CH2O)v-(CgH2g)—; CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; each Rf is independently CcF(2c+1) wherein c is 1 to about 6; d is 1 to about 3; g is 1 to about 4; or 1; r is 1 to about 4; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k— is from about 8 to about 22; v is 1 to about 4; and w is from about 2 to about 12.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酯表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜约43，X为O，S或SCH 2 CH 2 O，Ra为Rf（CH 2 CF 2）d - （CgH2g） - ; Rf [OCF2CF2] r（CgH2g） - ; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; 或RfOY-; Y是CFHCF2O（CH2CH2O）v-（CgH2g） - ; CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 每个Rf独立地为CcF（2c + 1），其中c为1至约6; d为1〜3; g为1至约4; 或1; r为1〜4; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 条件是Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-中的碳原子总数为约8至约22; v为1至约4; w为约2至约12。
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公开(公告)号：US08318877B2
公开(公告)日：2012-11-27
申请号：US12154082
申请日：2008-05-20
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译： 共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） y（CH 2 CH 2）z] mLC（O）-C（R）= CH 2（I）其中R是H，Cl，F或CH 3，L是O，S，NH，S-（CH 2） ）R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％ ％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是 C1至C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。
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公开(公告)号：US20090291222A1
公开(公告)日：2009-11-26
申请号：US12154082
申请日：2008-05-20
IPC分类号： B05D1/02 , C08G16/00 , C08G63/06 , C08G12/00 , C08G18/71 , C08G75/00 , C08G63/682 , B05D1/18 , B05D1/28 , C08F214/18 , C08L75/06 , C08G63/685 , C08L33/04 , C08L77/00
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译： 共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） 其中R为H，Cl，F或CH 3，L为O，S，NH，S-（CH 2）r O，S-（CH 2） ）R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％ ％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-OC（O）-C（R）-CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是C1至 C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。
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公开(公告)号：US08212064B2
公开(公告)日：2012-07-03
申请号：US12152312
申请日：2008-05-14
IPC分类号： C07C331/02 , C07C19/16 , C07C31/34 , C07C213/00 , C07C69/62
CPC分类号： C08F214/262 , C08F210/02 , C08F214/26 , C08F2/34
摘要： An oligomer of the formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]mG (I) wherein G is an I; OH; OC(O)CH═CH2; OC(O)CCH3═CH2; OC(O)CCl═CH2; NR1H; N3; NCO; SQ wherein Q is H, alkyl, (CH2)nOH, (CH2)nNH2, (CH2)nOC(O)C(Me)=CH2, or (CH2)nNHC(O)C(Me)=CH2; SCN; COOH; SO3H; NHCOCH═CH2; NHCOC(CH3)═CH2); OC(O)NHCH2CH2OC(O)C(CH3)═CH2; or OC(O)NHCH2CH2OC(O)C(CH3)═CH2; subscript n is an integer from 1 to about 6, subscript x is an integer from 1 to about 6, subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof, the total number of carbons in said formula (I) excluding G ranges from about 8 to about 22, and a process for preparation thereof.
摘要翻译： 式（I）的低聚物：CnF2n + 1（CH2）x [（CF2CF2）y（CH2CH2）z] mG（I）其中G是I; 哦; OC（O）CH = CH 2; OC（O）CCH 3 = CH 2; OC（O）CCl = CH 2; NR1H; N3; NCO; SQ其中Q是H，烷基，（CH2）nOH，（CH2）nNH2，（CH2）nOC（O）C（Me）= CH2或（CH2）nNHC（O）C（Me）= CH2; SCN; COOH; SO3H; NHCOCH = CH2; NHCOC（CH 3）= CH 2）; OC（O）NHCH 2 CH 2 OC（O）C（CH 3）= CH 2; 或OC（O）NHCH 2 CH 2 OC（O）C（CH 3）= CH 2; 下标n是1至约6的整数，下标x是1至约6的整数，下标y，z和m各自独立地为1,2或3，或其混合物，所述式中的碳总数 （I），其中不包括G范围为约8至约22，及其制备方法。
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公开(公告)号：US08128711B2
公开(公告)日：2012-03-06
申请号：US13108507
申请日：2011-05-16
IPC分类号： D06M15/423 , B32B27/40 , B32B27/00
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—xH (I) wherein Rf is a perfluoroalkyl group having 1 to about 6 carbon atoms; the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22; and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译： 具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R1）r-xH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; 和（ii）任选地与（c）水，连接剂或其混合物反应。
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公开(公告)号：US20110217506A1
公开(公告)日：2011-09-08
申请号：US13108507
申请日：2011-05-16
CPC分类号： C08G18/2885 , C08G18/2825 , C08G18/283 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T428/3154 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569 , Y10T428/31573
摘要： A polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2)x[(CF2CF2)y(CH2CH2)z]m(R1)r—XH (I) wherein Rf is a perfluoroalkyl group having 1 to about 6 carbon atoms; subscript x is 1 to about 6; subscripts y, z and m are each independently 1, 2 or 3, or a mixture thereof; subscript r is 0 or 1; the total number of carbons in said formula (I) excluding (R1)r—XH ranges from about 8 to about 22; X is —O—, —NR—, —S—, —S(CH2)tO—, or —S(CH2)tNR—; subscript t is from 1 to about 10; R is H or C1-4 alkyl; R1 is certain divalent radicals; n is 2 to 4; s is 1 to about 50; R2, R3, and R4 are each independently hydrogen or a C1-C6 alkyl group; and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof.
摘要翻译： 具有至少一个氨基甲酸酯键的聚合物：（i）使（a）至少一种二异氰酸酯，多异氰酸酯或其混合物反应，和（b）至少一种选自式（I）的氟化化合物：Rf（CH 2） x [（CF 2 CF 2）y（CH 2 CH 2）z] m（R 1）r -XH（I）其中Rf是具有1至约6个碳原子的全氟烷基; 下标x为1〜6; 下标y，z和m各自独立地为1,2或3，或其混合物; 下标r为0或1; 除（R1）r-XH以外的所述式（I）中的碳数总计为约8至约22; X是-O-，-NR - ， - S - ， - S（CH 2）t O-或-S（CH 2）t NR-; 下标t为1〜10; R是H或C 1-4烷基; R1是一定的二价基团; n为2〜4; s为1至约50; R2，R3和R4各自独立地为氢或C1-C6烷基; 和（ii）任选地与（c）水，连接剂或其混合物反应。
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