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公开(公告)号：US08242312B2
公开(公告)日：2012-08-14
申请号：US12944802
申请日：2010-11-12
IPC分类号： C07C317/00 , C07C31/00 , E21B43/22
CPC分类号： C07C271/20 , C07C271/14 , C07C275/14 , C07C309/08
摘要： The present invention comprises a compound of a compound of Formula 1 wherein Rf is a C2 to C12 perfluoroalkyl optionally interrupted by one to four moieties each independently selected from the group consisting of —CH2—, —O—, —S—, —S(O)—, and —S(O)2—; n is 1 to 6; m is 0 to 2, provided that m is less than or equal to n. X and Y are each independently O or NR, R is hydrogen or C1 to C6 alkyl; R1, and R2 are each independently C1 to C6 alkyl, optionally containing one or more oxygen atoms and may form a ring selected from the group of piperidine, pyrrolidine, and morpholine; and R3 is O−, (CH2)pC(O)O−, (CH2)pCH(OH)(CH2)SO3−, and (CH2)qSO3−; p is 1 to 4; and q is 2 to 4 which is useful as a surfactant.
摘要翻译： 本发明包括式1化合物的化合物，其中R f是任选地被一至四个部分间隔的C 2至C 12全氟烷基，其各自独立地选自-CH 2 - ， - O - ， - S - ， - S（ O） - 和-S（O）2 - ; n为1至6; m为0〜2，条件是m小于或等于n。 X和Y各自独立地为O或NR，R为氢或C 1至C 6烷基; R1和R2各自独立地为C1-C6烷基，任选地含有一个或多个氧原子，并且可以形成选自哌啶，吡咯烷和吗啉的环; 并且R 3是O-，（CH 2）p C（O）O-，（CH 2）p CH（OH）（CH 2）SO 3 - 和（CH 2）q SO 3 - ; p为1〜4; q为2〜4，可用作表面活性剂。
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公开(公告)号：US08026289B2
公开(公告)日：2011-09-27
申请号：US12255067
申请日：2008-10-21
CPC分类号： C08G65/33306 , C08G65/324 , C08G65/326 , C08G65/33317 , C08G65/33334 , C08G65/3348 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diamide surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 about 43, each X is independently NR, SCH2CH2NR, SO2NRCH2CH2NR, or SO2CH2CH2NR; R is hydrogen, or a linear or branched alkyl group CbH(2b+1) wherein b is 1 to about 18, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf(OCF2CF2)r—(CgH2g)—; RfOY—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—; Rf(CgH2g)—; or H(CcF2c)—(CgH2g)—; Y is CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; and each Rf is independently CcF(2c+1) wherein c is 1 to about 6.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酰胺表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜43，各X独立地为NR，SCH2CH2NR，SO2NRCH2CH2NR或SO2CH2CH2NR; R为氢，或直链或支链烷基CbH（2b + 1），其中b为1至约18，Ra为Rf（CH2CF2）d-（CgH2g） - ; Rf（OCF2CF2）r-（CgH2g） - ; RfOY-; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; Rf（CgH2g） - ; 或H（CcF2c） - （CgH2g） - ; Y为CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 并且每个Rf独立地为CcF（2c + 1），其中c为1至约6。
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公开(公告)号：US08022107B2
公开(公告)日：2011-09-20
申请号：US12254954
申请日：2008-10-21
CPC分类号： C08G65/007 , C08G65/331 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diester surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 to about 43, X is O, S, or SCH2CH2O, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf[OCF2CF2]r(CgH2g)—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k-; or RfOY—; Y is CFHCF2O(CH2CH2O)v-(CgH2g)—; CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; each Rf is independently CcF(2c+1) wherein c is 1 to about 6; d is 1 to about 3; g is 1 to about 4; or 1; r is 1 to about 4; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k— is from about 8 to about 22; v is 1 to about 4; and w is from about 2 to about 12.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酯表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜约43，X为O，S或SCH 2 CH 2 O，Ra为Rf（CH 2 CF 2）d - （CgH2g） - ; Rf [OCF2CF2] r（CgH2g） - ; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; 或RfOY-; Y是CFHCF2O（CH2CH2O）v-（CgH2g） - ; CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 每个Rf独立地为CcF（2c + 1），其中c为1至约6; d为1〜3; g为1至约4; 或1; r为1〜4; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 条件是Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-中的碳原子总数为约8至约22; v为1至约4; w为约2至约12。
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公开(公告)号：US20100099837A1
公开(公告)日：2010-04-22
申请号：US12254954
申请日：2008-10-21
IPC分类号： C08F22/10
CPC分类号： C08G65/007 , C08G65/331 , C08G65/337
摘要： A fluorinated polyoxyalkylene glycol diester surfactant of formula 1 B—X—COCH2O—[—CpH2pO—]n—CH2CO—X—Ra (1) wherein B is M or Ra, M is an ionizable hydrogen, ammonium, alkali metal, or alkaline earth metal, p is from about 2 to about 4, n is from about 5 to about 43, X is O, S, or SCH2CH2O, Ra is Rf(CH2CF2)d—(CgH2g)—; Rf[OCF2CF2]r(CgH2g)—; Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—; or RfOY—; Y is CFHCF2O(CH2CH2O)v—(CgH2g)—; CFHCF2O(CwH2w)—; or CF(CF3)CONH—(CgH2g)—; each Rf is independently CcF(2c+1) wherein c is 1 to about 6; d is 1 to about 3; g is 1 to about 4; s is 0 or 1; r is 1 to about 4; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k—is from about 8 to about 22; v is 1 to about 4; and w is from about 2 to about 12.
摘要翻译： 式1的氟化聚氧亚烷基二醇二酯表面活性剂B-X-COCH2O - [ - CpH2pO-] n-CH2CO-X-Ra（1）其中B是M或Ra，M是可电离的氢，铵，碱金属或碱 p为约2〜约4，n为约5〜约43，X为O，S或SCH 2 CH 2 O，Ra为Rf（CH 2 CF 2）d - （CgH2g） - ; Rf [OCF2CF2] r（CgH2g） - ; Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-; 或RfOY-; Y是CFHCF2O（CH2CH2O）v-（CgH2g） - ; CFHCF2O（CwH2w） - ; 或CF（CF 3）CONH-（CgH2g） - ; 每个Rf独立地为CcF（2c + 1），其中c为1至约6; d为1〜3; g为1至约4; s为0或1; r为1〜4; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 条件是Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k-中的碳原子总数为约8至约22; v为1至约4; w为约2至约12。
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公开(公告)号：US08318877B2
公开(公告)日：2012-11-27
申请号：US12154082
申请日：2008-05-20
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译： 共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） y（CH 2 CH 2）z] mLC（O）-C（R）= CH 2（I）其中R是H，Cl，F或CH 3，L是O，S，NH，S-（CH 2） ）R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％ ％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-O-C（O）-C（R）= CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是 C1至C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。
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公开(公告)号：US20090291222A1
公开(公告)日：2009-11-26
申请号：US12154082
申请日：2008-05-20
IPC分类号： B05D1/02 , C08G16/00 , C08G63/06 , C08G12/00 , C08G18/71 , C08G75/00 , C08G63/682 , B05D1/18 , B05D1/28 , C08F214/18 , C08L75/06 , C08G63/685 , C08L33/04 , C08L77/00
CPC分类号： C08F14/18 , C08F220/24 , C08F220/34 , C08F220/36 , C08F220/38 , C09D133/16 , C09D133/26 , Y10T428/2395 , Y10T428/23986 , Y10T428/3154
摘要： A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)═CH2 (I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)═CH2 (II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
摘要翻译： 共聚物组合物，其包含以以下重量百分比共聚的单体：（a）约20％至约95％的式（I）的单体或单体混合物：CnF2n + 1（CH2）x [（CF2CF2） 其中R为H，Cl，F或CH 3，L为O，S，NH，S-（CH 2）r O，S-（CH 2） ）R NH，OC（O）NH-CH 2 CH 2 O，NHC（O）NHCH 2 CH 2 O，S-（CH 2）r OC（O）NHCH 2 CH 2 O或S（CH 2）r NHC（O）NHCH 2 CH 2 O，和（b）约5％ ％的至少一种：（i）具有约6至约18个碳原子的直链，支链或环状烷基的（甲基）丙烯酸烷基酯单体; 或（II）式（II）的单体（R2）2N-R3-OC（O）-C（R）-CH2（Ⅱ）其中R是H，Cl，F或CH3，每个R2独立地是C1至 C4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40％至100％盐碱化; 或（iii）其混合物。
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公开(公告)号：US07816005B2
公开(公告)日：2010-10-19
申请号：US12774979
申请日：2010-05-06
CPC分类号： D06M15/263 , C08F8/44 , C09D135/00 , D06M15/227 , D06M15/233 , D06M15/285 , D06M15/29 , D06M15/295 , D06M15/3562 , D06M2200/01 , Y10T428/23986 , Y10T428/2933 , Y10T428/2938 , Y10T428/2967 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31909 , Y10T428/31928 , Y10T442/2279 , C08F8/32 , C08F212/08 , C08F222/06 , C08F210/14
摘要： A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
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公开(公告)号：US07815690B2
公开(公告)日：2010-10-19
申请号：US12620773
申请日：2009-11-18
IPC分类号： D06M15/263 , D06M15/277 , D06M15/285
CPC分类号： D06M15/295 , C08F8/00 , Y10T428/23986 , Y10T428/2933 , Y10T428/31725 , Y10T428/31786 , Y10T442/20 , C08F222/06
摘要： A composition which provides stain resistance and soil resistance to substrates comprising a copolymer of Formula 1 is disclosed, wherein D, M, R, Rf, x, k, h, i and j are defined as in claim 1.
摘要翻译： 公开了一种对包含式1的共聚物的基材提供抗污性和耐污性的组合物，其中D，M，R，R f，x，k，h，i和j如权利要求1中所定义。
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公开(公告)号：US20100004482A1
公开(公告)日：2010-01-07
申请号：US12165824
申请日：2008-07-01
申请人： Peter Michael Murphy , Tracy Hewat
发明人： Peter Michael Murphy , Tracy Hewat
IPC分类号： C07C69/63
CPC分类号： C07C69/65 , C07C69/657 , C07C235/08
摘要： A compound comprising Formula 2A, 2B, or 2C (Ra—O—CO—)2Y Formula 2A Ra—O—CO—Y—CO—O—(CH2CH2)Rf Formula 2B Ra—O—CO—Y—CO—O—R Formula 2C wherein Ra is the group (i) Rf(CH2CF2)d—(CgH2g)—; (ii) RfOCF2CF2—(CgH2g)—; (iii) RfOCFHCF2O(CH2CH2O)v—(CgH2g)—; (iv) RfOCFHCF2O(CwH2w)—; (v) RfOCF(CF3)CONH—(CgH2g)—; or (vi) Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k; each Rf is independently CcF(2c+1); c is 2 to about 6; d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; Y is a linear or branched diradical having olefinic unsaturation of the formula —CeH(2e−2)— wherein e is 2 or 3; R is H or a linear or branched alkyl group CbH(2b+1)—; and b is from 1 to about 18.
摘要翻译： 包含式2A，2B或2C（Ra-O-CO-）2Y的化合物式2A Ra-O-CO-Y-CO-O-（CH2CH2）Rf式2B Ra-O-CO-Y-CO-OR 式（Ⅱ）其中Ra是基团（ⅰ）Rf（CH2CF2）d-（CgH2g） - ; （ⅱ）RfOCF2CF2-（CgH2g） - ; （iii）RfOCFHCF2O（CH2CH2O）v-（CgH2g） - ; （iv）RfOCFHCF2O（CwH2w） - ; （v）RfOCF（CF 3）CONH-（CgH2g） - ; 或（vi）Rf（CH 2）h [（CF 2 CF 2）i（CH 2 CH 2）j] k; 每个Rf独立地为CcF（2c + 1）; c为2至约6; d为1〜3; g为1〜4; v为1至约4; w为约3至约12; h为1〜6; i，j和k各自独立地为1,2或3，或其混合物; 组（vi）中的碳原子总数为约8至约22; Y是具有式-CeH（2e-2） - 烯烃不饱和键的直链或支链双基，其中e为2或3; R是H或直链或支链烷基CbH（2b + 1） - ; b为1至约18。
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公开(公告)号：US07592064B2
公开(公告)日：2009-09-22
申请号：US10913914
申请日：2004-08-06
IPC分类号： B32B3/02 , B32B5/02 , B32B27/00 , B32B27/02 , B32B27/04 , B32B27/12 , B32B27/40 , D03D27/00 , D04H11/00 , D05C17/00 , D02G3/00 , B05D3/02 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/7831 , C08G18/2885 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/249991 , Y10T428/2938 , Y10T428/2967 , Y10T428/31551 , Y10T428/31562 , Y10T442/2189 , Y10T442/2197 , Y10T442/2238 , Y10T442/2246 , Y10T442/2893
摘要： Carpet protectants comprising an aqueous dispersion comprising A. a partially fluorinated urethane polymer having at least one urea linkage, which compound is the product of the reaction of: (1) at least one organic polyisocyanate containing at least three isocyanate groups; (2) at least one fluorochemical compound which contains per molecule (a) a single functional group having one or more Zerewitinoff hydrogen atoms and (b) at least two carbon atoms, each of which is attached to at least two fluorine atoms; and (3) water in an amount sufficient to react with from about 5% to about 60% of the isocyanate groups in said polyisocyanate; B. a non-fluorinated cationic surfactant; and C. a non-fluorinated nonionic surfactant are disclosed.
摘要翻译： 地毯保护剂包含水分散体，其包含A.具有至少一个脲键的部分氟化的聚氨酯聚合物，该化合物是以下物质的反应产物：（1）至少一种含有至少三个异氰酸酯基团的有机多异氰酸酯; （2）至少一种含氟化合物，其每分子含有（a）具有一个或多个Zerewitinoff氢原子的单官能团和（b）至少两个碳原子，每个碳原子连接至少两个氟原子; 和（3）足以与所述多异氰酸酯中的约5％至约60％的异氰酸酯基反应的水; B.非氟化阳离子表面活性剂; 和C.一种非氟化非离子表面活性剂。
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