公开(公告)号：US3926845A

公开(公告)日：1975-12-16

申请号：US44048374

申请日：1974-02-07

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI ROBERT S

IPC分类号： B01J23/75 ,  B01J23/76 ,  B01J27/18 ,  B01J21/02

CPC分类号： B01J23/75 ,  B01J23/76 ,  B01J27/18 ,  Y10S585/906

摘要： Organic compounds are oxidatively dehydrogenated in the presence of a solid catalyst comprising cobalt, phosphorus, combined oxygen and at least one metal from the group indium, magnesium, aluminum, thorium, yttrium, cadmium, lead, beryllium, zinc, manganese, silver, cerium, zirconium, boron and calcium.

公开(公告)号：US3660514A

公开(公告)日：1972-05-02

申请号：US3660514D

申请日：1970-08-06

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI ROBERT S

IPC分类号： B01J27/187 ,  C07C5/48 ,  C07C5/18

CPC分类号： C07C5/48 ,  B01J27/187 ,  Y10S585/906

摘要： ALKENES, ALKYLPYRIDINES AND ALKYLAROMATICS ARE DEHYDROGENATED BY CONTACT WITH OXYGEN IN THE TEMPERATURE RANGE OF 750 TO 950* F. IN THE PRESENCE OF A CATALYST COMPRISING IRON PHOSPHATE PROMOTED BY RHENIUM.

公开(公告)号：US3873633A

公开(公告)日：1975-03-25

申请号：US38059073

申请日：1973-07-19

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI ROBERT S

IPC分类号： B01J23/843 ,  B01J27/18 ,  C07C5/48 ,  C07C5/18

CPC分类号： C07C5/48 ,  B01J23/8437 ,  B01J27/18 ,  C07C11/12 ,  C07C11/02

摘要： Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst comprising cobalt, phosphorus, oxygen and, optionally, bismuth. Representative of such conversions is the oxidative dehydrogenation of butane to butadiene and isopentane to isoprene in the presence of catalyst comprising bismuth-cobalt-phosphorusoxygen and cobalt-phosphorus-oxygen, respectively. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.

摘要翻译： 通过在含氧气体与含有钴，磷，氧和任选的铋的催化剂的存在下使气相中的原料接触，将有机化合物脱氢成具有较高不饱和度的化合物。 在这种转化的代表是分别在包含铋 - 钴 - 磷 - 氧 - 氧和钴 - 磷 - 氧的催化剂存在下丁二烯和异戊烷到异戊二烯的氧化脱氢。 转化产物是有价值的化合物，其特别可用作制备聚合材料如合成橡胶等的中间体。

公开(公告)号：US3862910A

公开(公告)日：1975-01-28

申请号：US38101973

申请日：1973-07-20

申请人： PHILLIPS PETROLEUM CO

发明人： CICHOWSKI ROBERT S

IPC分类号： B01J23/78 ,  B01J27/16 ,  B01J27/18 ,  B01J27/185 ,  B01J11/82

CPC分类号： B01J27/16 ,  B01J23/78 ,  B01J27/18 ,  B01J27/1853 ,  Y10S585/906

摘要： Oxidative dehydrogenation of organic compounds is carried out in the presence of a potassium/iron/phosphorus/oxygen catalyst composition. A method of preparing the catalyst composition comprising associating potassium with iron and subsequently associating the potassium-iron composite with phosphorus.

摘要翻译： 有机化合物的氧化脱氢在钾/铁/磷/氧催化剂组合物存在下进行。 一种制备催化剂组合物的方法，包括将钾与铁缔合并随后使钾 - 铁复合物与磷相结合。