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公开(公告)号:US20240387861A1
公开(公告)日:2024-11-21
申请号:US18696465
申请日:2022-09-22
Inventor: Ryohei Miyamae , Akira Kano , Shinichiro Kondo
IPC: H01M10/0525 , H01M4/134 , H01M4/38 , H01M10/0568 , H01M50/414 , H01M50/431 , H01M50/446 , H01M50/451 , H01M50/491
Abstract: A disclosed lithium secondary battery includes a positive electrode (11), a negative electrode (12), a separator (50) disposed between the positive electrode (11) and the negative electrode (12), and a non-aqueous electrolyte having lithium ion conductivity. The negative electrode (12) is an electrode on which lithium metal is deposited during charging and from which the lithium metal dissolves during discharging. The separator (50) includes a substrate (51), a heat-resistant layer (52), and a spacer (53). The heat-resistant layer (52) is formed on at least one main surface selected from two main surfaces of the substrate (51). The spacer (53) is disposed on the negative electrode (12) side with respect to the substrate (51) and the heat-resistant layer (52). An average height of the spacer (53) is larger than a sum of an average thickness of the substrate and an average thickness of the heat-resistant layer.
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2.
公开(公告)号:US10978692B2
公开(公告)日:2021-04-13
申请号:US16386758
申请日:2019-04-17
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Kensuke Nakura
Abstract: A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A1X/A1 is less than a ratio A2X/A2. A1X is a sum of projected areas of the first protrusions on the first surface. A1 is an area of the first surface. A2X is a sum of projected areas of the second protrusions on the second surface. A2 is an area of the second surface.
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公开(公告)号:US10777805B2
公开(公告)日:2020-09-15
申请号:US15869047
申请日:2018-01-12
Inventor: Go Tei , Ryohei Miyamae , Akira Kano
IPC: H01M4/133 , H01M4/38 , H01M10/052 , H01M4/02 , H01M10/0525
Abstract: A negative electrode active material contains a graphite material represented by a formula CaxByC1-y, where x and y satisfy 0
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公开(公告)号:US20240429562A1
公开(公告)日:2024-12-26
申请号:US18694576
申请日:2022-09-22
Inventor: Ryohei Miyamae , Akira Kano , Shinichiro Kondo
IPC: H01M50/474 , H01M10/052 , H01M50/431 , H01M50/443 , H01M50/46
Abstract: A disclosed lithium secondary battery includes a positive electrode (11), a negative electrode (12), a separator (50) disposed between the positive electrode (11) and the negative electrode (12), and a non-aqueous electrolyte having lithium ion conductivity. The negative electrode (12) is an electrode on which lithium metal is deposited during charging and from which the lithium metal dissolves during discharging. The separator (50) includes a substrate (51) and a spacer (53). The spacer (53) is disposed on the negative electrode (12) side with respect to the substrate (51). The spacer (53) includes line-shaped protrusions arranged in a mesh pattern. The mesh pattern includes a lacking part connecting regions within adjacent meshes.
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公开(公告)号:US20240128780A1
公开(公告)日:2024-04-18
申请号:US18274342
申请日:2022-01-21
Inventor: Ryohei Miyamae , Akira Kano , Takahiro Fukuoka
IPC: H02J7/00 , H01M10/052 , H01M10/44 , H01M10/46
CPC classification number: H02J7/00712 , H01M10/052 , H01M10/44 , H01M10/46 , H02J7/0048
Abstract: A method of charging a secondary battery, the battery including a positive electrode in which a lithium ion is stored during discharging and released during charging, a negative electrode in which a lithium metal deposits during charging and dissolves during discharging, and a non-aqueous electrolyte having a lithium ion conductivity, wherein the method includes a step of charging the secondary battery according to a first charging profile. In the secondary battery, a surface of the negative electrode is covered with a protection layer. In the first charging profile, charging starts from a first charging step in which charging is performed at a constant current with a first electric current density I1, and following the first charging step, a second charging step is performed in which charging is performed at a constant current with a second electric current density I2 that is larger than the first electric current density I1.
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6.
公开(公告)号:US11251437B2
公开(公告)日:2022-02-15
申请号:US16389038
申请日:2019-04-19
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Kensuke Nakura
IPC: H01M4/70 , H01M4/134 , H01M4/38 , H01M4/66 , H01M10/052 , H01M10/0587 , H01M4/02
Abstract: A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. In at least the first surface or the second surface, a first area rate is larger than a second area rate.
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公开(公告)号:US20250141051A1
公开(公告)日:2025-05-01
申请号:US18835506
申请日:2023-02-08
Inventor: Rikiya Okimoto , Ryohei Miyamae
IPC: H01M50/491 , H01M10/052 , H01M10/0587 , H01M50/403 , H01M50/449
Abstract: A secondary battery includes a positive plate, a negative plate, a porous separator, and a non-aqueous electrolyte. In the secondary battery, lithium metal deposits on the negative plate during charging, and lithium metal dissolves in the non-aqueous electrolyte during discharge. The secondary battery includes: a spacer interposed between at least one of electrode plates of the negative plate and the positive plate and the separator to form a space between the electrode plate and the separator; and a low porosity portion that has a smaller porosity than the separator and that is fitted into the separator in an area where the separator and the spacer overlap when viewed from a laminating direction of the separator and the electrode plate.
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公开(公告)号:US20240347864A1
公开(公告)日:2024-10-17
申请号:US18292678
申请日:2022-07-27
Inventor: Shinichiro Kondo , Ryohei Miyamae , Akira Kano
IPC: H01M50/477 , H01M10/0525 , H01M10/0587 , H01M50/474 , H01M50/486
CPC classification number: H01M50/477 , H01M10/0525 , H01M10/0587 , H01M50/474 , H01M50/486
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode facing the positive electrode, a separator disposed between the positive electrode and the negative electrode, a nonaqueous electrolyte having lithium ion conductivity, and a spacer disposed between the negative electrode and the separator. Lithium metal deposits on the negative electrode during charging and the lithium metal dissolves from the negative electrode during discharging. The spacer has a plurality of spot-like projection portions.
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公开(公告)号:US20220407047A1
公开(公告)日:2022-12-22
申请号:US17638545
申请日:2020-07-28
Inventor: Akira Kano , Ryohei Miyamae
IPC: H01M4/134 , H01M4/62 , H01M10/0569 , H01M10/0525
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, a lithium ion conductive nonaqueous electrolyte, and a separator disposed between the positive electrode and the negative electrode. On the negative electrode, lithium metal deposits during charging, and the lithium metal is dissolved during discharging; the negative electrode includes a negative electrode current collector, and a plurality of layers stacked on the negative electrode current collector; the plurality of layers include a first layer, a second layer, and a third layer; of the first to third layers, the first layer is closest to the negative electrode current collector, and the third layer is farthest from the negative electrode current collector; the first layer contains a material capable of storing lithium ions; the second layer contains lithium metal, and the third layer has an insulation property and a lithium ion permeability.
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10.
公开(公告)号:US11177481B2
公开(公告)日:2021-11-16
申请号:US16392573
申请日:2019-04-23
Inventor: Ryohei Miyamae , Akira Kano , Kensuke Nakura
IPC: H01M4/70 , H01M4/66 , H01M10/052 , H01M4/02
Abstract: A lithium secondary battery includes a positive electrode, negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. The positive electrode contains a positive electrode active material containing lithium. The negative electrode faces the positive electrode. The separator is disposed between the positive and negative electrodes. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes a layer having a first surface, and protrusions protruding from the first surface. The first surface is a surface on which lithium metal is deposited during charge. The protrusions do not divide the first surface into parts.
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