公开(公告)号：US08088834B2

公开(公告)日：2012-01-03

申请号：US12874786

申请日：2010-09-02

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Kumar Dhawan ,  Robert Russell Galucci ,  Ganesh Kannan, Sr. ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Kumar Dhawan ,  Robert Russell Galucci ,  Ganesh Kannan, Sr. ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

IPC分类号： C08J11/04

CPC分类号： C08J11/24 ,  C08G63/181 ,  C08G63/78 ,  C08J2367/02 ,  Y02W30/706

摘要： The invention relates to a process for making modified polybutylene terephththalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.

摘要翻译： 本发明涉及一种由聚对苯二甲酸乙二醇酯组分制备改性聚对苯二甲酸丁二酯无规共聚物的方法。 本发明涉及一种三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应; 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由该方法制备的组合物。

公开(公告)号：US20070208160A1

公开(公告)日：2007-09-06

申请号：US11626674

申请日：2007-01-24

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

IPC分类号： C08G63/02

CPC分类号： C08J11/24 ,  C08G63/181 ,  C08G63/78 ,  C08J2367/02 ,  Y02W30/706

摘要： The invention relates to a process for making modified polybutylene terephththalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.

摘要翻译： 本发明涉及一种由聚对苯二甲酸乙二醇酯组分制备改性聚对苯二甲酸丁二酯无规共聚物的方法。 本发明涉及一种三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应; 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由该方法制备的组合物。

公开(公告)号：US07799836B2

公开(公告)日：2010-09-21

申请号：US11626674

申请日：2007-01-24

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Deepak Ramaraju ,  Gomatam Raghavan Ravi ,  Dhaval Shah

IPC分类号： C08J11/04

CPC分类号： C08J11/24 ,  C08G63/181 ,  C08G63/78 ,  C08J2367/02 ,  Y02W30/706

摘要： The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.

摘要翻译： 本发明涉及一种由聚对苯二甲酸乙二醇酯组分制备改性聚对苯二甲酸丁二醇酯无规共聚物的方法。 本发明涉及一种三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应; 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由该方法制备的组合物。

公开(公告)号：US08680167B2

公开(公告)日：2014-03-25

申请号：US11627091

申请日：2007-01-25

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Sung Dug Kim ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Sung Dug Kim ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08J11/04 ,  C08L67/02 ,  C08K3/04 ,  C08K3/08 ,  C08K3/22 ,  C08K3/34

CPC分类号： C08L67/02 ,  C08K3/013 ,  C08L69/00 ,  C08L2666/18 ,  C08L2666/02

摘要： The invention relates to a composition comprising (a) from 5 to 99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) has at least one residue derived from the polyethylene terephthalate component, and (b) at least 1 wt % of a filler component. In one embodiment, the invention relates to an article molded from the above-mentioned molding composition. In another embodiment, the invention relates to methods for making and methods for using the molding composition.

摘要翻译： 本发明涉及一种组合物，其包含（a）5至99重量％的改性聚对苯二甲酸丁二醇酯无规共聚物，其（1）衍生自聚对苯二甲酸乙二醇酯组分，其选自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物，和（2）具有 至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基，和（b）至少1重量％的填料组分。 在一个实施方案中，本发明涉及由上述模塑组合物模制的制品。 在另一个实施方案中，本发明涉及制备方法和使用该模塑组合物的方法。

公开(公告)号：US07902263B2

公开(公告)日：2011-03-08

申请号：US11626684

申请日：2007-01-24

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08J11/04

CPC分类号： C08G63/183 ,  C08J11/24 ,  C08J2367/02 ,  Y02W30/706

摘要： The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from processes of the invention.

摘要翻译： 本发明涉及一种由聚对苯二甲酸乙二醇酯组分制备改性聚对苯二甲酸丁二醇酯无规共聚物的方法。 在一个实施方案中，本发明涉及二步法，其中1,4-丁二醇组分在聚对苯二甲酸乙二醇酯组分解聚熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应，并将熔融混合物置于低于大气压的条件下 生产改性聚对苯二甲酸丁二醇酯无规共聚物。 在另一个实施方案中，本发明涉及三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以使聚对苯二甲酸乙二醇酯组分解聚为第一 熔融混合物 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由本发明的方法制备的组合物。

公开(公告)号：US08138233B2

公开(公告)日：2012-03-20

申请号：US13021093

申请日：2011-02-04

申请人： Parminder Agarwal ,  Kristen Cohoon-Brister ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon-Brister ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08J11/04

CPC分类号： C08G63/183 ,  C08J11/24 ,  C08J2367/02 ,  Y02W30/706

摘要： In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from processes of the invention.

摘要翻译： 在一个实施方案中，本发明涉及二步法，其中1,4-丁二醇组分在聚对苯二甲酸乙二醇酯组分解聚熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应，并将熔融混合物置于低于大气压的条件下 生产改性聚对苯二甲酸丁二醇酯无规共聚物。 在另一个实施方案中，本发明涉及三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一 熔融混合物 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由本发明的方法制备的组合物。

公开(公告)号：US20110124821A1

公开(公告)日：2011-05-26

申请号：US13021093

申请日：2011-02-04

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Sandeep Dhawan ,  Robert Russell Gallucci ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08G63/91

CPC分类号： C08G63/183 ,  C08J11/24 ,  C08J2367/02 ,  Y02W30/706

摘要： In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from processes of the invention.

摘要翻译： 在一个实施方案中，本发明涉及二步法，其中1,4-丁二醇组分在聚对苯二甲酸乙二醇酯组分解聚熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应，并将熔融混合物置于低于大气压的条件下 生产改性聚对苯二甲酸丁二醇酯无规共聚物。 在另一个实施方案中，本发明涉及三步法，其中选自乙二醇，丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一 熔融混合物 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合，随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由本发明的方法制备的组合物。

公开(公告)号：US07807745B2

公开(公告)日：2010-10-05

申请号：US11626557

申请日：2007-01-24

申请人： Parminder Agarwal ,  Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Parminder Agarwal ,  Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08K3/10

CPC分类号： C08L67/02 ,  C08L51/00 ,  C08L53/00 ,  C08L55/00 ,  C08L69/00 ,  C08L2666/02

摘要： A molding composition comprising: (a) from 5 to 90 wt. % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) has at least one residue derived from the polyethylene terephthalate component, and (b) from 5 to 90 wt. % of a polycarbonate component; and from at least 1 wt. % of an impact modifier component, wherein the modified polybutylene terephthalate random copolymer, the polycarbonate component, the impact modifier, and optionally at least one additive, have a combined weight % of 100 wt %. The invention also encompasses methods for making the composition and articles made from the composition.

摘要翻译： 一种成型组合物，其包含：（a）5-90wt。 （1）衍生自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分的改性聚对苯二甲酸丁二醇酯无规共聚物的％;（2）至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基，（b） 5至90wt。 ％的聚碳酸酯组分; 和至少1wt。 ％的抗冲改性剂组分，其中改性聚对苯二甲酸丁二醇酯无规共聚物，聚碳酸酯组分，抗冲改性剂和任选的至少一种添加剂具有100重量％的组合重量％。 本发明还包括制备由组合物制成的组合物和制品的方法。

公开(公告)号：US07923506B2

公开(公告)日：2011-04-12

申请号：US11626105

申请日：2007-01-23

申请人： Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Kayoko Onda ,  Dhaval Shah

发明人： Kristen Cohoon ,  Shellie Virginia Gasaway ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Kayoko Onda ,  Dhaval Shah

IPC分类号： C08L67/03

CPC分类号： C08L67/02 ,  C08K5/0008 ,  C08L23/0884 ,  C08L25/14 ,  C08L33/068 ,  C08L63/00 ,  C08L101/02 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02 ,  C08L2666/22 ,  C08L2666/18

摘要： A molding composition comprising: (a) from 40 to 99.99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) has at least one residue derived from the polyethylene terephthalate component, and (b) from 0.01 to 20 wt. % of a carboxy reactive component; wherein the modified polybutylene terephthalate random copolymer, the carboxy reactive component, and optionally at least one additive, are present in a total amount of 100 wt %.

摘要翻译： 一种模塑组合物，其包含：（a）40至99.99重量％的改性聚对苯二甲酸丁二醇酯无规共聚物，其（1）衍生自选自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分，和（2）至少具有 衍生自聚对苯二甲酸乙二醇酯组分的一个残基，和（b）0.01至20重量％ ％的羧基反应性组分; 其中改性聚对苯二甲酸丁二醇酯无规共聚物，羧基反应性组分和任选的至少一种添加剂的总量为100重量％。

公开(公告)号：US07855238B2

公开(公告)日：2010-12-21

申请号：US11627454

申请日：2007-01-26

申请人： Kristen Cohoon ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

发明人： Kristen Cohoon ,  Ganesh Kannan ,  Kenneth Frederick Miller ,  Dhaval Shah

IPC分类号： C08J11/04

CPC分类号： C08L55/02 ,  B29B7/7495 ,  C08K3/013 ,  C08K5/0008 ,  C08L51/04 ,  C08L51/08 ,  C08L67/02 ,  C08L101/02 ,  C08L2666/14 ,  C08L2666/02 ,  C08L2666/18

摘要： A molding composition comprising (a) from 5 to 90 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) at least one residue derived from the polyethylene terephthalate component, and (b) from 5 to 40 wt % of a polyalkylene terephthalate component; wherein the modified polybutylene terephthalate random copolymer, the polyalkylene terephthalate component, and optionally, at least one additive, have a combined weight % of 100 wt %. Methods for making the composition and articles made from the composition.

摘要翻译： 一种模塑组合物，其包含（a）5-90重量％的改性聚对苯二甲酸丁二醇酯无规共聚物，其中（1）衍生自聚对苯二甲酸乙二醇酯组分，其选自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物，和（2）至少一个残基 衍生自聚对苯二甲酸乙二醇酯组分，和（b）5-40重量％的聚对苯二甲酸亚烷基酯组分; 其中所述改性聚对苯二甲酸丁二醇酯无规共聚物，聚对苯二甲酸亚烷基酯组分和任选的至少一种添加剂具有100重量％的组合重量％。 制备由组合物制成的组合物和制品的方法。