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    Neutral Metallic Dendrimer Complexes
    6.
    发明申请
    Neutral Metallic Dendrimer Complexes 有权
    中性金属树枝状大分子复合物

    公开(公告)号：US20110127496A1

    公开(公告)日：2011-06-02

    申请号：US12854288

    申请日：2010-08-11

    申请人： Ifor David William Samuel ,  Paul Leslie Burn ,  Shih-Chun Lo

    发明人： Ifor David William Samuel ,  Paul Leslie Burn ,  Shih-Chun Lo

    IPC分类号： H01L51/50 ,  C07F15/00 ,  C09K11/06

    CPC分类号： C07F15/0033 ,  C09K2211/1007 ,  C09K2211/185 ,  H01L51/0037 ,  H01L51/0085 ,  H01L51/5016 ,  Y02E10/549 ,  Y10S428/917

    摘要： A charge-neutral organometallic dendrimer is described, said dendrimer having the formula (I): CORE-[DENDRITE(-Q)a]n  (I) in which CORE represents a group of formula MXXYZ, in which M represents a metal cation, x represents an integer of 1 or more, each X which may be the same or different represents a mono-, bi- or tri-dentate coordinating group, z represents 0 or an integer of 1 or more, and each Y which may be the same or different represents a coordinating group, the total of (b.x)+(c.z) being equal to the number of coordination sites on M, wherein b is the number of coordination sites on X and c is the number of coordination sites on Y; n represents an integer of 2 or more; each DENDRITE which may be the same or different represents a dendritic molecular structure bonded to a group X; a represents 0 or an integer of 1 or more; and each Q which may be the same or different represents a surface group; CORE terminating in the first single bond which is connected to a branching group or branching atom of DENDRITE; which dendrimer has a structure in which no hemisphere of a notional sphere centred on M and containing the dendrimer is devoid of a said first single bond.

    摘要翻译： 描述了电荷中性有机金属树枝状大分子，所述树枝状聚合物具有式（I）：CORE- [DENDRITE（-Q）a] n（I），其中CORE表示式MXXYZ的基团，其中M表示金属阳离子， x表示1或更大的整数，每个X可以相同或不同，表示单，双或三齿配位基，z表示0或1或更大的整数，每个Y可以是 相同或不同的表示协调组，（bx）+（cz）的总和等于M上的协调位置数，其中b是X上的协调位点数，c是Y上的协调位点数; n表示2以上的整数， 每个DENDRITE可以相同或不同，表示与基团X键合的树枝状分子结构; a表示0或1或更大的整数; 并且每个可以相同或不同的Q表示表面基团; CORE终止于连接到DENDRITE的支化基团或支化原子的第一单键; 该树枝状聚合物具有这样的结构，其中以M为中心并且含有树枝状大分子的名义球的半球没有所述第一单键。

    Neutral metallic dendrimer complexes
    8.
    发明授权
    Neutral metallic dendrimer complexes 有权
    中性金属树枝状大分子复合物

    公开(公告)号：US08536333B2

    公开(公告)日：2013-09-17

    申请号：US12854288

    申请日：2010-08-11

    申请人： Ifor David William Samuel ,  Paul Leslie Burn ,  Shih-Chun Lo

    发明人： Ifor David William Samuel ,  Paul Leslie Burn ,  Shih-Chun Lo

    IPC分类号： C07F15/00 ,  H01L51/50

    CPC分类号： C07F15/0033 ,  C09K2211/1007 ,  C09K2211/185 ,  H01L51/0037 ,  H01L51/0085 ,  H01L51/5016 ,  Y02E10/549 ,  Y10S428/917

    摘要： A charge-neutral organometallic dendrimer is described, said dendrimer having the formula (I): CORE-[DENDRITE(-Q)a]n  (I) in which CORE represents a group of formula MXxYz, in which M represents a metal cation, x represents an integer of 1 or more, each X which may be the same or different represents a mono-, bi- or tri-dentate coordinating group, z represents 0 or an integer of 1 or more, and each Y which may be the same or different represents a coordinating group, the total of (b.x)+(c.z) being equal to the number of coordination sites on M, wherein b is the number of coordination sites on X and c is the number of coordination sites on Y; n represents an integer of 2 or more; each DENDRITE which may be the same or different represents a dendritic molecular structure bonded to a group X; a represents 0 or an integer of 1 or more; and each Q which may be the same or different represents a surface group; CORE terminating in the first single bond which is connected to a branching group or branching atom of DENDRITE; which dendrimer has a structure in which no hemisphere of a notional sphere centered on M and containing the dendrimer is devoid of a said first single bond.

    摘要翻译： 描述了电荷中性有机金属树枝状聚合物，所述树枝状聚合物具有式（I）：CORE- [DENDRITE（-Q）a] n（I），其中CORE表示式MXxYz的基团，其中M表示金属阳离子， x表示1或更大的整数，每个X可以相同或不同，表示单，双或三齿配位基，z表示0或1或更大的整数，每个Y可以是 相同或不同的表示协调组，（bx）+（cz）的总和等于M上的协调位置数，其中b是X上的协调位点数，c是Y上的协调位点数; n表示2以上的整数， 每个DENDRITE可以相同或不同，表示与基团X键合的树枝状分子结构; a表示0或1或更大的整数; 并且每个可以相同或不同的Q表示表面基团; CORE终止于连接到DENDRITE的支化基团或支化原子的第一单键; 该树枝状聚合物具有这样的结构，其中以M为中心并且含有树枝状大分子的名义球的半球没有所述第一单键。