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公开(公告)号：US07335802B2
公开(公告)日：2008-02-26
申请号：US10965256
申请日：2004-10-14
IPC分类号： C07C27/22
CPC分类号： C07C29/16 , C07C31/125
摘要： Systems and methods to produced branched aliphatic alcohols are described. Systems may include a dehydrogenation-isomerization unit, an olefin dimerization unit, an olefin isomerization unit, a hydroformylation unit, a dehydrogenation unit, a hydrogenation unit and/or combinations thereof. Methods for producing branched aliphatic alcohols may include isomerization of olefins in a process stream. The isomerized olefins may be hydroformylated to produce aliphatic alcohols. After hydroformylation of the aliphatic alcohols, unreacted components from the hydroformylation process may be separated from the aliphatic alcohols products. The unreacted components from the hydroformylation process may be recycled back into the main process stream or sent to other processing units. Addition of multiple streams to the units may be performed to control reaction conditions in the units.
摘要翻译： 描述了制备支链脂族醇的体系和方法。 系统可以包括脱氢异构化单元，烯烃二聚单元，烯烃异构化单元，加氢甲酰化单元，脱氢单元，氢化单元和/或其组合。 制备支链脂族醇的方法可以包括在工艺流中烯烃的异构化。 异构化的烯烃可以加氢甲酰化以产生脂族醇。 在脂肪醇的加氢甲酰化之后，来自加氢甲酰化过程的未反应组分可以与脂族醇产物分离。 来自加氢甲酰化方法的未反应组分可以循环回到主工艺流中或送到其它处理单元。 可以向单元添加多个流以控制单元中的反应条件。
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公开(公告)号：US07348462B2
公开(公告)日：2008-03-25
申请号：US10789115
申请日：2004-02-27
IPC分类号： C10L5/00 , C10L1/16 , C10M101/02 , C10M107/00 , C10M143/00 , C10M165/00 , C10M167/00 , C10M169/00 , C10M171/00
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.
摘要翻译： 一种制备支链烷基芳烃的方法，该方法包括在烷基化条件下使支链烯烃与芳族烃接触，该支链烯烃已经通过包括使异链烷烃组合物在合适的催化剂上脱氢的方法获得，该催化剂已经通过加氢裂化获得了异链烷烃组合物 和链烷烃蜡的加氢异构化，并且所述异链烷烃组合物包含碳数为7至35的链烷烃，其中至少部分分子的链烷烃是支链的，每个链烷烃分子的平均支链数为至少0.5 并且支链包含甲基和任选的乙基支链; 一种制备（支链 - 烷基）芳基磺酸盐的方法，包括磺化支化烷基芳烃，其中支链烷基芳烃是通过所述制备支链烷基芳烃的方法制备的; 和支链烷基芳烃组合物和（支链 - 烷基）芳基磺酸盐组合物，其可通过如此定义的方法获得。
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公开(公告)号：US06747165B2
公开(公告)日：2004-06-08
申请号：US10075318
申请日：2002-02-14
IPC分类号： C07C30300
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.
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公开(公告)号：US07053257B2
公开(公告)日：2006-05-30
申请号：US10789264
申请日：2004-02-27
IPC分类号： C07C2/68
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.
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5.发明授权Process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant 失效制备支链烯烃的方法，使用支链烯烃制备表面活性剂的方法和表面活性剂公开(公告)号：US06765106B2
公开(公告)日：2004-07-20
申请号：US10075682
申请日：2002-02-14
IPC分类号： C07C30324
CPC分类号： C07C5/3337 , C07C5/3332 , C07C9/00 , C07C11/02 , C07C29/16 , C07C303/24 , C07C2521/04 , C07C2523/26 , C07C2523/42 , C07C2523/44 , C07C2523/745 , C11D1/143 , C11D1/146 , C11D1/29 , C11D1/72 , C07C31/02 , C07C31/125 , C07C305/06
摘要： A process for preparing branched olefins comprising 0.5% or less quaternary aliphatic carbon atoms, which process comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.7 and the branching comprising methyl and optionally ethyl branches, and which isoparaffinic composition may be obtained by hydrocracking and hydroisomerization of a paraffinic wax; a method of using olefins for making an anionic surfactant, a nonionic surfactant or a cationic surfactant, in particular a surfactant sulfate or sulfonate, comprising converting the branched olefins into the surfactant; and an anionic surfactant, a nonionic surfactant or a cationic surfactant which is obtainable by the method of use.
摘要翻译： 一种制备包含0.5％或更少的季脂族碳原子的支链烯烃的方法，该方法包括使异链烷烃组合物在合适的催化剂上脱氢，所述异链烷烃组合物包含碳数为7至35的链烷烃，其中链烷烃至少 分子的一部分是支链的，每个链烷烃分子的平均分支数为至少0.7，支链包含甲基和任选的乙基支链，并且可以通过链烷烃蜡的加氢裂化和加氢异构化获得异链烷烃组合物; 使用烯烃制造阴离子表面活性剂，非离子表面活性剂或阳离子表面活性剂，特别是表面活性剂硫酸盐或磺酸盐的方法，包括将支化烯烃转化为表面活性剂; 以及可通过使用方法获得的阴离子表面活性剂，非离子表面活性剂或阳离子表面活性剂。
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6.发明授权Process for preparing (branched-alkyl) arylsulfonates and a (branched-alkyl) arylsulfonate composition 有权（支链 - 烷基）芳基磺酸盐和（支链 - 烷基）芳基磺酸盐组合物的制备方法公开(公告)号：US07235684B2
公开(公告)日：2007-06-26
申请号：US10789263
申请日：2004-02-27
IPC分类号： C07C303/24
CPC分类号： C10G45/00 , C10G65/043 , C10G69/123 , C10G2300/1085 , C10G2300/1096 , C10G2400/22 , C10G2400/30
摘要： A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.5 and the branching comprising methyl and optionally ethyl branches; a process for preparing (branched-alkyl)arylsulfonates, comprising sulfonating branched alkyl aromatic hydrocarbons which branched alkyl aromatic hydrocarbons have been prepared by the said process for preparing branched alkyl aromatic hydrocarbons; and branched alkyl aromatic hydrocarbon compositions and (branched-alkyl)arylsulfonate compositions which are obtainable by the processes so defined.
摘要翻译： 一种制备支链烷基芳烃的方法，该方法包括在烷基化条件下使支链烯烃与芳族烃接触，该支链烯烃已经通过包括使异链烷烃组合物在合适的催化剂上脱氢的方法获得，该催化剂已经通过加氢裂化获得了异链烷烃组合物 和链烷烃蜡的加氢异构化，并且所述异链烷烃组合物包含碳数为7至35的链烷烃，其中至少部分分子的链烷烃是支链的，每个链烷烃分子的平均支链数为至少0.5 并且支链包含甲基和任选的乙基支链; 一种制备（支链 - 烷基）芳基磺酸盐的方法，包括磺化支化烷基芳烃，其中支链烷基芳烃是通过所述制备支链烷基芳烃的方法制备的; 和支链烷基芳烃组合物和（支链 - 烷基）芳基磺酸盐组合物，其可通过如此定义的方法获得。
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公开(公告)号：US07087777B2
公开(公告)日：2006-08-08
申请号：US10738572
申请日：2003-12-17
IPC分类号： C07C303/24
CPC分类号： C07C5/3337 , C07C5/3332 , C07C9/00 , C07C11/02 , C07C29/16 , C07C303/24 , C07C2521/04 , C07C2523/26 , C07C2523/42 , C07C2523/44 , C07C2523/745 , C11D1/143 , C11D1/146 , C11D1/29 , C11D1/72 , C07C31/02 , C07C31/125 , C07C305/06
摘要： A process for preparing branched olefins comprising 0.5% or less quaternary aliphatic carbon atoms, which process comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.7 and the branching comprising methyl and optionally ethyl branches, and which isoparaffinic composition may be obtained by hydrocracking and hydroisomerization of a paraffinic wax; a method of using olefins for making an anionic surfactant, a nonionic surfactant or a cationic surfactant, in particular a surfactant sulfate or sulfonate, comprising converting the branched olefins into the surfactant; and an anionic surfactant, a nonionic surfactant or a cationic surfactant which is obtainable by the method of use.
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公开(公告)号：US07378549B2
公开(公告)日：2008-05-27
申请号：US11041324
申请日：2005-01-24
申请人： Paul Marie Ayoub
发明人： Paul Marie Ayoub
CPC分类号： C07C67/08 , C07C67/58 , C07C69/716
摘要： A process for the reactive extraction of levulinic acid from an aqueous mixture having levulinic acid, wherein the aqueous mixture is contacted with a liquid esterifying alcohol, the alcohol having at least four carbon atoms and is substantially water-immiscible, at esterification conditions in the presence of a catalyst to form a levulinate ester, wherein the amount of the alcohol is such that the alcohol extracts the levulinate ester from the aqueous mixture. Further, an aqueous phase, having the catalyst and a reduced levulinic acid content, and an organic phase, having the alcohol and the levulinate ester, are formed.
摘要翻译： 一种从具有乙酰丙酸的水性混合物中反应性提取乙酰丙酸的方法，其中所述含水混合物与液体酯化醇接触，所述醇在至少四个碳原子下具有基本上与水不混溶性，在酯化条件下存在 的催化剂以形成乙酰丙酸酯，其中醇的量使得醇从含水混合物中提取乙酰丙酸酯。 此外，形成具有催化剂和乙酰丙酸含量降低的水相和具有醇和乙酰丙酸酯的有机相。
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公开(公告)号：US20100217038A1
公开(公告)日：2010-08-26
申请号：US12600873
申请日：2008-05-21
申请人： Paul Marie Ayoub , Jean-Paul Lange
发明人： Paul Marie Ayoub , Jean-Paul Lange
IPC分类号： C07C51/00
CPC分类号： C07C51/36 , C07C53/126
摘要： A process for converting levulinic acid into pentanoic acid, the process comprising the following steps: (a) contacting a feedstock comprising levulinic acid under hydrogenating conditions, in the presence of hydrogen, with a non-acidic heterogeneous hydrogenation catalyst comprising a hydrogenation metal supported on a solid catalyst carrier to obtain a first effluent comprising gamma valerolactone; (b) contacting at least part of the first effluent under hydrogenating conditions, in the presence of hydrogen, with a strongly acidic catalyst and a hydrogenation metal to obtain a second effluent comprising pentanoic acid, wherein step (b) is operated at a conversion per pass of at most 70 wt % to obtain the second effluent comprising pentanoic acid and unconverted gamma valerolactone, and wherein part of the unconverted gamma valerolactone is recycled to step (a) and/or step (b).
摘要翻译： 一种将乙酰丙酸转化为戊酸的方法，该方法包括以下步骤：（a）在氢存在下，在氢化条件下，将包含乙酰丙酸的原料与非酸性非均相氢化催化剂接触，所述非酸性非均相氢化催化剂包含负载在 固体催化剂载体，以获得包含γ-戊内酯的第一流出物; （b）在氢气条件下，在氢气存在下，与强酸性催化剂和氢化金属接触至少部分第一流出物以获得包含戊酸的第二流出物，其中步骤（b）以每转化率 通过至多70重量％以获得包含戊酸和未转化的γ-戊内酯的第二流出物，并且其中部分未转化的γ-戊内酯再循环至步骤（a）和/或步骤（b）。
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