公开(公告)号：US07312352B2

公开(公告)日：2007-12-25

申请号：US10984318

申请日：2004-11-08

申请人： Paul William Buckley ,  James Silva ,  David Dardaris

发明人： Paul William Buckley ,  James Silva ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07C68/02 ,  C07C69/96

摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.

摘要翻译： 本发明涉及制备酯取代的二芳基碳酸酯的界面方法。 该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相 和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于 在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为 在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或 高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

公开(公告)号：US07518011B2

公开(公告)日：2009-04-14

申请号：US11858732

申请日：2007-09-20

申请人： Paul William Buckley ,  James Silva ,  David Dardaris

发明人： Paul William Buckley ,  James Silva ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07C68/02 ,  C07C69/96

摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.

摘要翻译： 本发明涉及制备酯取代的二芳基碳酸酯的界面方法。 该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相 和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于 在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为 在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或 高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

公开(公告)号：US20080009646A1

公开(公告)日：2008-01-10

申请号：US11858732

申请日：2007-09-20

申请人： Paul Buckley ,  James Silva ,  David Dardaris

发明人： Paul Buckley ,  James Silva ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07C68/02 ,  C07C69/96

摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.

摘要翻译： 本发明涉及制备酯取代的二芳基碳酸酯的界面方法。 该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相 和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于 在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为 在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或 高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

公开(公告)号：US20050032988A1

公开(公告)日：2005-02-10

申请号：US10638622

申请日：2003-08-08

申请人： James Silva ,  David Dardaris ,  Gary Davis

发明人： James Silva ,  David Dardaris ,  Gary Davis

IPC分类号： C08G64/18 ,  C08G64/24 ,  C08G77/448 ,  C08F283/02

CPC分类号： C08G77/448 ,  C08G64/186 ,  C08G64/24 ,  C08G77/24 ,  C08G77/80

摘要： Copolyorganosiloxanecarbonates are prepared by first preparing an oligomeric aromatic polycarbonate, such as an oligomeric bisphenol A polycarbonate, in the presence of a tertiary amine as the only catalyst species; contacting the oligomeric polycarbonate mixture with a polyorganosiloxane bis(aryl)chloroformate, such as the bischloroformate of hydroxy-terminated eugenol polydimethylsiloxane; and introducing phosgene and/or chain termination agent either continuously or in stages. A feature of the process is the presence of dihydroxyaromatic compound in only one charge, at the beginning. The products have excellent physical properties, including transparency.

摘要翻译： 通过在叔胺作为唯一的催化剂种存在下首先制备低聚芳族聚碳酸酯如低聚双酚A聚碳酸酯来制备共聚有机硅氧烷， 使低聚聚碳酸酯混合物与聚有机硅氧烷二（芳基）氯甲酸酯接触，例如羟基封端的丁子香酚聚二甲基硅氧烷的双氯甲酸酯; 并连续或分阶段引入光气和/或链终止剂。 该方法的特征是在开始时仅在一次充电中存在二羟基芳族化合物。 该产品具有优异的物理性能，包括透明度。

公开(公告)号：US20060084822A1

公开(公告)日：2006-04-20

申请号：US10968773

申请日：2004-10-19

申请人： Gary Davis ,  Joshua Stone ,  James Silva ,  James Mahood ,  David Dardaris

发明人： Gary Davis ,  Joshua Stone ,  James Silva ,  James Mahood ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07D493/04 ,  C07C68/02 ,  C07J9/00 ,  C08G64/1608 ,  C08G64/24 ,  C08G64/28 ,  C07C69/96

摘要： A method for preparing an aliphatic chloroformate comprising, introducing a mixture of at least one aliphatic hydroxyl compound, phosgene, at least one solvent, and optionally at least one organic base into a flow reactor to obtain a unidirectional flowing reaction mixture. The at least one aliphatic hydroxyl compound comprises at least one aliphatic hydroxyl group. The unidirectional flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aliphatic chloroformate.

摘要翻译： 一种制备脂族氯甲酸酯的方法，包括将至少一种脂族羟基化合物，光气，至少一种溶剂和任选的至少一种有机碱的混合物引入流动反应器中以获得单向流动的反应混合物。 所述至少一种脂族羟基化合物包含至少一个脂族羟基。 将单向流动反应混合物保持在约0℃至约60℃之间的温度下，以产生包含脂族氯甲酸酯的单一产物流。

公开(公告)号：US20060025622A1

公开(公告)日：2006-02-02

申请号：US10984318

申请日：2004-11-08

申请人： Paul Buckley ,  James Silva ,  David Dardaris

发明人： Paul Buckley ,  James Silva ,  David Dardaris

IPC分类号： C07C69/96

CPC分类号： C07C68/02 ,  C07C69/96

摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.

公开(公告)号：US20050029194A1

公开(公告)日：2005-02-10

申请号：US10743239

申请日：2003-12-22

申请人： David Hall ,  Thomas Guggenheim ,  James Silva ,  Farid Khouri ,  Matthew Littlejohn ,  Balakrishnan Ganesan ,  Ashok Shyadligeri ,  Pradeep Nadkarni

发明人： David Hall ,  Thomas Guggenheim ,  James Silva ,  Farid Khouri ,  Matthew Littlejohn ,  Balakrishnan Ganesan ,  Ashok Shyadligeri ,  Pradeep Nadkarni

IPC分类号： B01D15/08 ,  B01D61/00 ,  B01D61/02 ,  B01D61/14 ,  C07C277/06

CPC分类号： C02F9/00 ,  B01D61/027 ,  C02F1/281 ,  C02F1/283 ,  C02F1/44 ,  C02F2101/38 ,  C07C277/06 ,  C07C279/04

摘要： Disclosed is a method for removing a neutral or an ionic guanidine compound from an aqueous media optionally comprising an alkali metal halide, wherein the method is selected from the group consisting of (a) adsorption onto a carbonaceous adsorbent, (b) adsorption onto a clay adsorbent, (c) filtration through a nanofiltration membrane, and (d) removal of water and calcination.

摘要翻译： 公开了一种从任选地包含碱金属卤化物的水性介质中除去中性或离子胍化合物的方法，其中所述方法选自（a）吸附到碳质吸附剂上，（b）吸附到粘土上 吸附剂，（c）通过纳滤膜过滤，和（d）去除水和煅烧。

公开(公告)号：US20070238846A1

公开(公告)日：2007-10-11

申请号：US11401171

申请日：2006-04-10

申请人： Gary Davis ,  James Mahood ,  Matthew Pixton ,  Niles Rosenquist ,  James Silva ,  Joshua Stone

发明人： Gary Davis ,  James Mahood ,  Matthew Pixton ,  Niles Rosenquist ,  James Silva ,  Joshua Stone

IPC分类号： C08G77/448 ,  C08L83/04

CPC分类号： C08G64/186 ,  C08G77/448 ,  C08L83/10

摘要： Disclosed herein are polysiloxane-polycarbonate copolymer articles. In one embodiment, a ⅛th inch thick bar formed from the thermoplastic composition has a B-Y ratio of less than or equal to about 1.75. This article, which has a dimension that is greater than or equal to 1.5 cm, comprises the thermoplastic composition which comprises a polysiloxane-polycarbonate copolymer, wherein the copolymer comprises repeating diorganosiloxane units of formula (1): wherein each R is, independently, a C1-13 monovalent organic group; and E has an average value of 20 to 35.

摘要翻译： 本文公开的是聚硅氧烷 - 聚碳酸酯共聚物制品。 在一个实施方案中，由热塑性组合物形成的1/8英寸厚的棒具有小于或等于约1.75的B-Y比。 具有大于或等于1.5cm的尺寸的该制品包含包含聚硅氧烷 - 聚碳酸酯共聚物的热塑性组合物，其中所述共聚物包含重复式（1）的二有机硅氧烷单元：其中每个R独立地为 C 1-13 一价有机基团; E的平均值为20〜35。

公开(公告)号：US20060135731A1

公开(公告)日：2006-06-22

申请号：US11232285

申请日：2005-09-21

申请人： James Silva ,  Farid Khouri

发明人： James Silva ,  Farid Khouri

IPC分类号： C08G8/02

CPC分类号： C07D209/48 ,  C08G73/12

摘要： Bis(halophthalimides) are prepared in a solvent such as ortho-dichlorobenzene or anisole, by a reaction at a temperature of at least 150° C. between at least one diamine compound and at least one halophthalic anhydride in the presence of imidization catalyst. The reaction produces a vapor stream comprising solvent and water formed as a by-product of the imidization reaction. A suitable vapor handling system comprising a partial reflux condenser is used to recycle the solvent, maintain the reactant concentration, conduct the reaction at a higher temperature, and effect more efficient conversion of reactants to product bis(halophthalimides). Reaction conditions disclosed may also be used to prepare organic polyimides.

摘要翻译： 通过在酰亚胺化催化剂存在下，在至少一种二胺化合物和至少一种卤代邻苯二甲酸酐之间的至少150℃的温度下进行反应，在溶剂如邻二氯苯或苯甲醚中制备双（卤代邻苯二酰亚胺）。 反应产生包含作为酰亚胺化反应的副产物形成的溶剂和水的蒸气流。 使用包含部分回流冷凝器的合适的蒸汽处理系统来回收溶剂，保持反应物浓度，在较高温度下进行反应，并且使反应物更有效地转化成产物双（卤代​​邻苯二酰亚胺）。 所公开的反应条件也可用于制备有机聚酰亚胺。

公开(公告)号：US20070161821A1

公开(公告)日：2007-07-12

申请号：US11684882

申请日：2007-03-12

申请人： David Hall ,  Thomas Guggenheim ,  James Silva ,  Farid Khouri ,  Matthew Littlejohn ,  Balakrishnan Ganesan ,  Ashok Shyadligeri ,  Pradeep Nadkarni

发明人： David Hall ,  Thomas Guggenheim ,  James Silva ,  Farid Khouri ,  Matthew Littlejohn ,  Balakrishnan Ganesan ,  Ashok Shyadligeri ,  Pradeep Nadkarni

IPC分类号： C07C277/06

CPC分类号： C02F9/00 ,  B01D61/027 ,  C02F1/281 ,  C02F1/283 ,  C02F1/44 ,  C02F2101/38 ,  C07C277/06 ,  C07C279/04

摘要： Disclosed is a method for removing a neutral or an ionic guanidine compound from aqueous media optionally comprising an alkali metal halide, wherein the method is selected from the group consisting of (a) adsorption onto a carbonaceous adsorbent, (b) adsorption onto a clay adsorbent, (c) filtration through a nanofiltration membrane, and (d) removal of water and calcination.

摘要翻译： 公开了一种从任选地包含碱金属卤化物的水性介质中除去中性或离子胍化合物的方法，其中所述方法选自（a）吸附到含碳吸附剂上，（b）吸附到粘土吸附剂上 ，（c）通过纳滤膜过滤，和（d）去除水和煅烧。