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1.发明授权Optical waveguide with an essentially fluorine-free polymer core and a fluorine-containing polymer jacket 失效具有基本上无氟聚合物芯和含氟聚合物护套的光波导
公开(公告)号：US4863236A
公开(公告)日：1989-09-05
申请号：US21469
申请日：1987-03-04
CPC分类号： B05D7/02 , D01F8/10 , G02B6/02033
摘要： Optical waveguides of plastic usually consist of a core and a jacket, the core material having a higher refractive index than the jacket material. A suitable core material is a fluorine-free polymer and a suitable jacket material is a fluorine-containing polymer, which can also contain deuterium. The optical waveguides can be produced by passing a polymer rod through a solution of the jacket polymer and then removing the solvent. The optical waveguides are particularly suitable for the transmission of data with the aid of light waves with a wavelength of 500 to 750 nm.
摘要翻译： 塑料的光波导通常由芯和护套组成，芯材的折射率高于护套材料。 合适的芯材是无氟聚合物，合适的护套材料是也可含有氘的含氟聚合物。 光波导可以通过使聚合物棒穿过夹套聚合物的溶液然后除去溶剂来制备。 光波导特别适合于借助波长为500至750nm的光波传输数据。
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公开(公告)号：US5198925A
公开(公告)日：1993-03-30
申请号：US837768
申请日：1992-02-18
IPC分类号： C07C51/34 , C07C51/377 , C07C51/60 , C08F20/22
CPC分类号： C08F20/22 , C07C51/34 , C07C51/377 , C07C51/60
摘要： Esters of .alpha.-fluoroacrylic acid are accessible by hydrolysis of an .alpha.-hydroxymethyl-.alpha.-fluoromalonic acid ester, decarboxylation and dehydration of the hydrolysis product and subsequent esterification of the resulting .alpha.-fluoroacrylic acid with an alcohol. The esters are polymerizable and are suitable for use as a starting material for preparing fluoropolymers which in turn are usable as materials for manufacturing transparent articles. The polymers are high-molecular and non-crystalline and have softening temperatures of above 100.degree. C.
摘要翻译： α-氟代丙烯酸的酯可以通过α-羟甲基-α-氟丙酸酯的水解，水解产物的脱羧和脱水以及所得的α-氟丙烯酸与醇的酯化反应来获得。 酯是可聚合的，并且适合用作制备含氟聚合物的起始原料，其可用作制造透明制品的材料。 聚合物是高分子和非结晶的，并具有高于100℃的软化温度。
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3.发明授权Core/shell optical waveguides with cores comprising halogenated phenyl acrylate or methacrylate 失效具有包含卤化苯基丙烯酸酯或甲基丙烯酸酯的芯的芯/壳光波导
公开(公告)号：US5129031A
公开(公告)日：1992-07-07
申请号：US587960
申请日：1990-09-25
CPC分类号： D01F8/10 , G02B6/02033
摘要： Optical waveguides of very good heat resistance and good light conductivity are composed of polymers which are derived from halogenated phenyl acrylates or phenyl methacrylates.
摘要翻译： 具有非常好的耐热性和良好光导率的光波导由衍生自丙烯酸卤代苯基酯或甲基丙烯酸苯酯的聚合物组成。
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4.发明授权Transparent thermoplastic molding compound made of 2,3-difluoroacrylic acid esters 失效2,3-二氟丙烯酸酯的透明热塑性塑料复合物
公开(公告)号：US5175790A
公开(公告)日：1992-12-29
申请号：US768905
申请日：1991-12-12
IPC分类号： C08F20/02 , C08F16/14 , C08F20/10 , C08F20/22 , C08F214/26 , C08F216/14 , G02B1/04 , G02B6/00
摘要： Transparent thermoplastic molding compound made of 2,3-difluoroacrylic acid esters. A thermoplastic molding compound consisting of units of 2,3-difluoroacrylic acid esters or their deuterated derivatives, or containing units of these esters, is distinguished by a high glass transition temperature and a high transparency. It is therefore suitable for the manufacture of beam waveguides for long transmission distances and high continuous use temperatures.
摘要翻译： PCT No.PCT / EP90 / 00587第 371日期1991年12月12日 102（e）日期1991年12月12日PCT提交1990年4月12日PCT公布。 出版物WO90 / 12040 日期：1990年10月18日。由2,3-二氟丙烯酸酯制成的透明热塑性模塑料。 由2,3-二氟丙烯酸酯或它们的氘代衍生物或含有这些酯单元的单元组成的热塑性模塑料的特征在于高玻璃化转变温度和高透明度。 因此，适用于制造长波长传输距离和高连续使用温度的光束波导。
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公开(公告)号：US5319131A
公开(公告)日：1994-06-07
申请号：US21282
申请日：1993-02-22
IPC分类号： C07C51/34 , C07C51/377 , C07C51/60 , C08F20/22 , C07C69/62
CPC分类号： C08F20/22 , C07C51/34 , C07C51/377 , C07C51/60
摘要： Esters of .alpha.-fluoroacrylic acid are accessible by hydrolysis of an .alpha.-hydroxymethyl-.alpha.-fluoromalonic acid ester, decarboxylation and dehydration of the hydrolysis product and subsequent esterification of the resulting .alpha.-fluoroacrylic acid with an alcohol. The esters are polymerizable and are suitable for use as a starting material for preparing fluoropolymers which in turn are usable as materials for manufacturing transparent articles. The polymers are high-molecular and non-crystalline and have softening temperatures of above 100.degree. C.
摘要翻译： α-氟代丙烯酸的酯可以通过α-羟甲基-α-氟丙酸酯的水解，水解产物的脱羧和脱水以及所得的α-氟丙烯酸与醇的酯化反应来获得。 酯是可聚合的，并且适合用作制备含氟聚合物的起始原料，其可用作制造透明制品的材料。 聚合物是高分子和非结晶的，并具有高于100℃的软化温度。
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6.发明授权Transplant thermoplastic molding compound made of 2,3-difluoroacrylic acid esters 失效移植热塑性模塑料由2,3-二氟丙烯酸酯制成
公开(公告)号：US5283303A
公开(公告)日：1994-02-01
申请号：US941138
申请日：1992-11-03
IPC分类号： C08F20/02 , C08F16/14 , C08F20/10 , C08F20/22 , C08F214/26 , C08F216/14 , G02B1/04 , G02B6/00 , C08F18/20
摘要： A thermoplastic molding compound consisting of units of 2,3-difluoroacrylic acid esters or their deuterated derivatives, or containing units of these esters, is distinguished by a high glass transition temperature and a high transparency. It is therefore suitable for the manufacture of beam waveguides for long transmission distances and high continuous use temperatures.
摘要翻译： 由2,3-二氟丙烯酸酯或它们的氘代衍生物或含有这些酯单元的单元构成的热塑性模塑料的特征在于高玻璃化转变温度和高透明度。 因此，适用于制造长波长传输距离和高连续使用温度的光束波导。
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公开(公告)号：US5032654A
公开(公告)日：1991-07-16
申请号：US113469
申请日：1987-10-23
IPC分类号： G02B6/00 , B29D11/00 , C08F2/02 , C08F20/22 , C08F220/22
CPC分类号： C08F20/22
摘要： A transparent material of very good heat resistance and very good light conductivity is essentially composed of a polymer derived mainly from bromophenyl acrylates or bromophenyl methacrylates.
摘要翻译： 具有非常好的耐热性和非常好的光导率的透明材料基本上由主要由溴苯基丙烯酸酯或溴代苯基甲基丙烯酸酯衍生的聚合物组成。
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8.发明授权Transparent thermoplastic molding composition, process for its preparation and its use 失效透明热塑性成型组合物及其制备方法及其应用
公开(公告)号：US5187769A
公开(公告)日：1993-02-16
申请号：US840324
申请日：1992-02-24
申请人： Werner Groh , Rudolf Heumuller , Gerald Schutze , Roland Stern , Gerhard Wieners
发明人： Werner Groh , Rudolf Heumuller , Gerald Schutze , Roland Stern , Gerhard Wieners
IPC分类号： C08F220/18 , C08F20/10 , C08F220/10 , C08F220/22 , G02B1/04 , G02B6/00
CPC分类号： C08F220/22 , G02B1/045
摘要： Transparent thermoplastic molding composition of a polymer containinga) 10 to 95% by weight of units which are derived from a compound of the formula (I)R.sub.2.sup.1 C.dbd.CF--COO--C(CF.sub.3).sub.2 R.sup.2 (I)b) 90 to 5% by weight of units which are derived from one or more compounds of the formula (II) ##STR1## and c) 0 to 85% by weight of units which are derived from a compound of the formula (III)R.sub.2.sup.7 C.dbd.CF--COO--CR.sub.3.sup.8 (III)The molding composition is used for the production of optical objects, in particular for the production of optical fibers.
摘要翻译： 聚合物的透明热塑性模塑组合物，其含有a）10至95重量％的衍生自式（I）化合物的单元R 21 C = CF-COO-C（CF 3）2 R 2（I）b）90至5重量％ 衍生自一种或多种式（II）的化合物的单元（ⅰ）和c）0至85重量％的衍生自式（Ⅳ）化合物的单元R 27 C = CF -COO-CR38（III）模塑组合物用于制造光学物体，特别是用于生产光纤。
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9.发明授权Transparent thermoplastic molding composition, process for its preparation and its use 失效透明热塑性成型组合物，其制备方法及其用途
公开(公告)号：US5239027A
公开(公告)日：1993-08-24
申请号：US992082
申请日：1992-12-17
申请人： Werner Groh , Rudolf Heumuller , Gerald Schutze , Roland Stern , Gerhard Wieners
发明人： Werner Groh , Rudolf Heumuller , Gerald Schutze , Roland Stern , Gerhard Wieners
IPC分类号： C08F220/18 , C08F20/10 , C08F220/10 , C08F220/22 , G02B1/04 , G02B6/00
CPC分类号： C08F220/22 , G02B1/045
摘要： Transparent thermoplastic molding composition of a polymer containinga) 10 to 95% by weight of units which are derived from a compound of the formula (I)R.sup.1.sub.2 C.dbd.CF--COO--C(CF.sub.3).sub.2 R.sup.2 (I)b) 90 to 5% by weight of units which are derived from one or more compounds of the formula (II) ##STR1## and c) 0 to 85% by weight of units which are derived from a compound of the formula (III)R.sup.7.sub.2 C.dbd.CF--COO--CR.sup.8.sub.3 (III)The molding composition is used for the production of optical objects, in particular for the production of optical fibers.
摘要翻译： 聚合物的透明热塑性成型组合物，其含有a）10〜95重量％的衍生自式（I）化合物的单元R12C = CF-COO-C（CF3）2R2（I）b）90〜5％ （II）的化合物和c）0至85重量％的衍生自式（III）的化合物的单元R 72 C = CF -COO-CR83（III）模塑组合物用于制造光学物体，特别是用于生产光纤。
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公开(公告)号：US5301254A
公开(公告)日：1994-04-05
申请号：US768778
申请日：1991-11-07
IPC分类号： C08F16/14 , C08F214/26 , C08F216/14 , C08L27/18 , G02B1/04 , G02B6/00
CPC分类号： C08F216/14 , C08F214/262 , G02B1/045
摘要： A transparent thermoplastic molding compound consisting of 40 to 90% by weight of units derived from tetrafluoroethylene, and 60 to 10% by weight of units derived from compounds of formula I or II:CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.m --(CF.sub.2).sub.n --CF.sub.3 (I)CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.p --(CF.sub.2).sub.q --COO--R (II)is particularly suitable for manufacturing the sheath of beam waveguides whose core has a higher transparency than polymethyl methacrylate.
摘要翻译： PCT No.PCT / EP90 / 00585第 371日期1991年11月7日 102（e）1991年11月7日PCT PCT 1990年4月13日提交PCT公布。 出版物WO90 / 12043 日本1990年10月18日。由40〜90重量％衍生自四氟乙烯的单元和60〜10重量％衍生自式I或II化合物的单元组成的透明热塑性模塑料：CF 2 = CF-O- （CF2-CF（CF3）-O）m-（CF2）n-CF3（I）CF2 = CF-O-（CF2-CF（CF3）-O）对 - （CF2）q-COO-R 特别适用于制造其核心具有比聚甲基丙烯酸甲酯更高透明度的光束波导鞘。
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