Stabilized aqueous alkyldiketene emulsions
    1.
    发明授权
    Stabilized aqueous alkyldiketene emulsions 失效
    稳定的水性氨基酸乳化剂

    公开(公告)号:US5154763A

    公开(公告)日:1992-10-13

    申请号:US639093

    申请日:1991-01-09

    摘要: Stabilized aqueous C.sub.14 -C.sub.22 -alkyldiketene emulsions containing, as essential components:(a) from 10 to 60% w/w of at least one C.sub.14 -C.sub.22 -alkyldiketene,(b) from 1 to 10% w/w of at least one protective colloid and(c) from 0.1 to 20% w/w of at least one ester of formula I ##STR1## in which R.sup.1 and R.sup.2 each denote C.sub.14 -C.sub.22 -alkyl, R.sup.1 differing in this case from R.sup.2 by at least 4 carbon atoms in the alkyl chain, and/or the same or different C.sub.14 -C.sub.22 -alkenyl groups, or at least one ester of the formula R.sup.3 --O--CO--O--R.sup.4 (II), in which R.sup.3 and R.sup.4 are alkyl or alkenyl radicals of from 2 to 22 carbon atoms or at least one urethane of formula III ##STR2## in which R.sup.5, R.sup.6 and R.sup.7 are the same or different alkyl or alkenyl radicals of from 2 to 22 carbon atoms and one of the substituents R.sup.5, R.sup.6 and R.sup.7 contains at least 12 carbon atoms,and showing a ratio of emulsified components (a):(c) from 200:1 to 1:1 and the use of compounds of formulae I to III as stabilizers for the preparation of alkyldiketene emulsions containing at least 10% w/w and preferably from 16 to 40% w/w of emulsified alkyldiketene.

    摘要翻译: 含有作为必要组分的稳定的C14-C22-烷基二乙烯基水乳液:(a)10至60%w / w的至少一种C14-C22-烷基二乙烯基,(b)1至10%w / w的至少一种 保护胶体和(c)0.1至20%w / w的至少一种式I(I)的酯,其中R 1和R 2各自表示C 14 -C 22 - 烷基,R 1在这种情况下不同于R 2, 烷基链中至少4个碳原子,和/或相同或不同的C 14 -C 22 - 烯基或至少一个式R 3 -O-CO-O-R 4(II)的酯,其中R 3和R 4是 具有2至22个碳原子的烷基或烯基或至少一个式III的氨基甲酸酯其中R 5,R 6和R 7是相同或不同的具有2至22个碳原子的烷基或烯基,一个 的取代基R 5,R 6和R 7含有至少12个碳原子,并且显示出乳化组分(a):(c)的比例为200:1至1:1,并且使用式I至III的化合物作为稳定剂 烷基染料的制备 含有至少10%w / w,优选16至40%w / w的乳化的烷基染料的乳液。

    Preparation of carbonyl chlorides
    2.
    发明授权
    Preparation of carbonyl chlorides 失效
    碳氟化合物的制备

    公开(公告)号:US5245063A

    公开(公告)日:1993-09-14

    申请号:US757388

    申请日:1991-09-10

    IPC分类号: C07C51/60

    CPC分类号: C07C51/60

    摘要: A process for preparing carbonyl chlorides of the formula I ##STR1## where R is C.sub.1 -C.sub.30 -alkyl, C.sub.2 -C.sub.30 -alkenyl or C.sub.2 -C.sub.30 -alkynyl, from essentially equimolar amounts of a carboxylic acid of the formula II ##STR2## where R has the abovementioned meanings, and phosgene COCl.sub.2 (III), in the presence of a catalytic adduct of phosgene and N,N-disubstituted formamide or the hydrochlorides thereof, of the formula IV where R.sup.1 and R.sup.2 are each, independently of one another, C.sub.1 -C.sub.3 -alkyl or together are a C.sub.4 -C.sub.5 -alkylene chain which may be interrupted by oxygen or by nitrogen which carries C.sub.1 -C.sub.3 -alkyl or CHO, and n is 0, 1 or 2, wherein the reaction is carried out with a stationary phase of the catalytic adduct, is described.

    摘要翻译: 制备式I的羰基氯的方法(I)其中R是C 1 -C 30 - 烷基,C 2 -C 30 - 烯基或C 2 -C 30 - 炔基,基本上等摩尔量的式II的羧酸 (IV)的光气和N,N-二取代的甲酰胺或其盐酸盐的催化加合物存在下,其中R具有上述含义的光学(II)和光气COCl 2(III) 其中R 1和R 2各自独立地为C 1 -C 3 - 烷基或一起为可被氧或携带C 1 -C 3烷基或CHO的氮中断的C 4 -C 5 - 亚烷基链,并且n为0 ,1或2,其中所述反应用催化加合物的固定相进行。

    Preparation of carbonyl halides of more than 7 carbon atoms
    4.
    发明授权
    Preparation of carbonyl halides of more than 7 carbon atoms 失效
    制备大于7个碳原子的羰基卤化物

    公开(公告)号:US4900479A

    公开(公告)日:1990-02-13

    申请号:US205160

    申请日:1988-06-10

    CPC分类号: C07C51/60

    摘要: Carbonyl halides of the general formula I ##STR1## where R is an organic radical of more than 7 carbon atoms and X is chlorine or bromine, are prepared by reacting carboxylic acids of the general formula II ##STR2## where R has the abovementioned meaning, with phosphorus chlorides or bromides by treating these reaction mixtures with carboxamide/hydrochloride or hydrobromide mixtures which are not homogeneously miscible with the carbonyl halides I and then separating off the carboxamide hydrochloride or hydrobromide phase.

    摘要翻译: 其中R是大于7个碳原子的有机基团,X是氯或溴的通式I(I)的羰基酰卤是通过使通式II的羧酸(II) R具有上述含义,用氯化磷或溴化物,通过用羧酰胺/盐酸盐或氢溴酸盐混合物处理这些反应混合物,其与羰基卤化物I不能均匀混溶,然后分离羧酰胺盐酸盐或氢溴酸盐相。