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公开(公告)号：US5091507A
公开(公告)日：1992-02-25
申请号：US509845
申请日：1990-04-17
CPC分类号： C08G67/02
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon of at least 3 carbon atoms employs a novel catalyst composition formed from a palladium compound, the anion of a strong non-hydrohalogenic acid, an aliphatic bidentate ligand of phosphorus and a polyalkoxyalkane.
摘要翻译： 用于生产一氧化碳和至少一种具有至少3个碳原子的至少一种烯属不饱和烃的线性交替聚合物的改进方法使用由钯化合物，强非氢卤酸的阴离子，脂族二齿 磷配体和聚烷氧基烷烃。
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2.发明授权Polymerization of co/olefin with diphosphine/hydrocarbyl palladium salt complex catalyst 失效co /烯烃与二膦/烃基钯盐配合物催化剂的聚合
公开(公告)号：US5066777A
公开(公告)日：1991-11-19
申请号：US474959
申请日：1990-02-05
CPC分类号： C07F15/006 , C08G67/02
摘要： An improved process for the production of linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises the use as a catalyst composition of a novel complex containing a diphosphine/hydrocarbylpalladium cation and an anion of a non-hydrohalogenic acid having a pKa below 2. The polymers are useful as engineering thermoplastics.
摘要翻译： 用于生产一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物的改进方法包括用作含有二膦/烃基钯阳离子和具有低于pKa的非氢卤酸的阴离子的催化剂组合物的用途 聚合物可用作工程热塑性塑料。
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公开(公告)号：US5004844A
公开(公告)日：1991-04-02
申请号：US372577
申请日：1989-06-28
IPC分类号： B01J31/12 , C07B61/00 , C07C29/141 , C07C29/145 , C07C31/10 , C07C31/12 , C07C33/14 , C07C35/08
CPC分类号： C07C29/145 , C07C29/141 , C07C2101/14 , C07C2101/16 , C07C2102/42
摘要： A process for the preparation of a primary or secondary alcohol, which comprises hydrogenating respectively an aldehyde or ketone in the presence of a catalyst system comprising a platinum compound, an acid having a pKa in the range from about 2 to about 10.5 and a phosphorus compound of the formula R.sup.1 R.sup.2 POH, wherein R.sup.1 and R.sup.2 each independently represents an alkyl group or a phenyl group, at a temperature in the range from about 20.degree. to about 150.degree. C. and at a pressure in the range from about 1 to about 100 bar.
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公开(公告)号：US5145823A
公开(公告)日：1992-09-08
申请号：US680443
申请日：1991-04-04
CPC分类号： B01J31/2409 , B01J31/24 , C08G67/02 , B01J2231/10 , B01J2531/824
摘要： Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, useful as premium thermoplastics, are produced by contacting the carbon monoxide and hydrocarbon reactants under polymerization conditions in the presence of a catalyst complex of hydrocarbylpalladium halide and a bidentate ligand of phosphorus. The catalyst complex is produced by contacting a complex of palladium dihalide and the bidentate phosphorus ligand with a tetrahydrocarbyltin.
摘要翻译： 通过在烃基钯卤化物和磷二配位体的催化剂络合物的存在下，在聚合条件下使一氧化碳和烃反应物接触来制备一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物，其可用作优质热塑性塑料。 通过使二卤化钯和二齿磷配体的络合物与四氢碳原子苯接触来制备催化剂络合物。
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公开(公告)号：US4330678A
公开(公告)日：1982-05-18
申请号：US213971
申请日：1980-12-08
CPC分类号： B01J31/185 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J2540/225 , B01J31/1895
摘要： A process for the hydroformylation of an olefin which comprises reacting an olefin with carbon monoxide and hydrogen in the process of a complex of rhodium with a compound of the formula:L(OR.sup.1)(OR.sup.2)(OR.sup.3)wherein L is P or As and R.sup.1, R.sup.2 and R.sup.3 are (dis)similar alkyl, aryl, alkaryl or aralkyl groups, provided that at least one of R.sup.1, R.sup.2 or R.sup.3 represents a group --CH.sub.n [CFXY].sub.3-n, wherein n is 1 or 2 and either(a) X and Y both represent F, or(b) one of X and Y represents F and the other represents H or Cl or an (un)substituted (ar)alkyl group, or(c) X represents H or Cl or an (un)substituted (ar)alkyl group and Y represents an (ar)alkyl group whose connecting carbon atom carries at least one F.
摘要翻译： 一种烯烃加氢甲酰化的方法，其包括在铑络合物与下式化合物：L（OR1）（OR2）（OR3）（其中L为P或As）的化合物的过程中使烯烃与一氧化碳和氢反应，和 R 1，R 2和R 3是（dis）相似的烷基，芳基，烷芳基或芳烷基，条件是R 1，R 2或R 3中的至少一个表示基团-CH n [CFXY] 3-n，其中n为1或2， （a）X和Y都表示F或（b）X和Y之一表示F，另一个表示H或Cl或（un）取代的（芳）烷基，或（c）X表示H或Cl或 （取代）（芳基）烷基，Y表示连接碳原子携带至少一个F.
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6.发明授权
公开(公告)号：US5010172A
公开(公告)日：1991-04-23
申请号：US458251
申请日：1989-12-28
CPC分类号： C08G67/02 , B01J31/1875 , B01J31/24 , B01J31/2409 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting the reactants in the presence of a catalyst composition formed from a palladium salt, a bidentate phosphorus ligand, and a tertiary monophosphine or a secondary phosphine oxide present in specified quantity.
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公开(公告)号：US4408078A
公开(公告)日：1983-10-04
申请号：US399161
申请日：1982-07-16
CPC分类号： B01J31/2495 , B01J31/1875 , B01J31/2404 , C07C45/50 , B01J2231/321 , B01J2531/828 , B01J31/18 , B01J31/226 , B01J31/2291 , B01J31/2295
摘要： Process for the hydroformylation of olefins with carbon monoxide and hydrogen in the presence of a ligand stabilized, platinum-containing catalytic system comprising at least one secondary phosphine oxide moiety.
摘要翻译： 在含有至少一个次级氧化膦部分的配位体稳定的含铂催化体系的存在下，用一氧化碳和氢气进行烯烃加氢甲酰化的方法。
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公开(公告)号：US5354340A
公开(公告)日：1994-10-11
申请号：US150934
申请日：1993-11-10
CPC分类号： C08G67/02
摘要： A process for the preparation of copolymers of carbon monoxide and one or more ethylenically unsaturated compounds by contacting the monomers, under polymerization conditions, with a catalyst system comprising a) a source of cations of one or more metals of Group VIII of the Periodic Table and b) a bidentate ligand, and c) a minor amount of a compound containing a hydride moiety. Copolymers made by this process generally have low molecular weights.
摘要翻译： 一种制备一氧化碳和一种或多种烯键式不饱和化合物的共聚物的方法，其通过使聚合条件下的单体与催化剂体系接触，所述催化剂体系包括：a）周期表第VIII族的一种或多种金属的阳离子源，以及 b）二齿配体，和c）少量含有氢化物部分的化合物。 通过该方法制备的共聚物通常具有低分子量。
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9.发明授权Catalytic polymerization of CO/olefin with ortho polar substituted aryl bidentate p ligand 失效邻苯基取代芳基二齿配位体CO /烯烃的催化聚合
公开(公告)号：US4843145A
公开(公告)日：1989-06-27
申请号：US89373
申请日：1987-08-26
CPC分类号： C08G67/02 , B01J31/2409 , B01J2531/824 , B01J31/1895
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting under polymerization conditions the carbon monoxide and hydrocarbon in the presence of a catalyst composition formed from a compound of certain Group VIII metals, e.g., palladium, an anion of a non-hydrohalogenic acid having a pKa above about 2 but below about 6, and a bidentate ligand of phosphorus wherein at least one of the monovalent phosphorus substituents is aromatic and substituted in a position ortho to the phosphorus with a polar substitutent.
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10.发明授权
公开(公告)号：US4859764A
公开(公告)日：1989-08-22
申请号：US88169
申请日：1987-08-21
CPC分类号： B01J31/189 , B01J31/0225 , B01J31/04 , B01J31/2239 , C08G67/02 , B01J2231/10 , B01J2531/824 , B01J31/1805 , B01J31/181 , B01J31/2404
摘要： Polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, e.g., ethylene, are produced in the presence of novel catalyst compositions formed from a palladium compound, an anion of a non-hydrohalogenic acid having a pKa less than about 2 and certain bidentate ligands containing atoms of phosphorus and nitrogen.
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