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公开(公告)号：US5225386A
公开(公告)日：1993-07-06
申请号：US783593
申请日：1991-10-28
IPC分类号： C08G67/02
CPC分类号： C08G67/02
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon of at least 3 carbon atoms employs a novel catalyst composition formed from a palladium compound, the anion of a strong non-hydrohalogenic acid, an aliphatic bidentate ligand of phosphorus and a polyalkoxyalkane.
摘要翻译： 用于生产一氧化碳和至少一种具有至少3个碳原子的至少一种烯属不饱和烃的线性交替聚合物的改进方法使用由钯化合物，强非氢卤酸的阴离子，脂族二齿 磷配体和聚烷氧基烷烃。
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公开(公告)号：US5091507A
公开(公告)日：1992-02-25
申请号：US509845
申请日：1990-04-17
CPC分类号： C08G67/02
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon of at least 3 carbon atoms employs a novel catalyst composition formed from a palladium compound, the anion of a strong non-hydrohalogenic acid, an aliphatic bidentate ligand of phosphorus and a polyalkoxyalkane.
摘要翻译： 用于生产一氧化碳和至少一种具有至少3个碳原子的至少一种烯属不饱和烃的线性交替聚合物的改进方法使用由钯化合物，强非氢卤酸的阴离子，脂族二齿 磷配体和聚烷氧基烷烃。
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3.发明授权Polymerization of co/olefin with diphosphine/hydrocarbyl palladium salt complex catalyst 失效co /烯烃与二膦/烃基钯盐配合物催化剂的聚合
公开(公告)号：US5066777A
公开(公告)日：1991-11-19
申请号：US474959
申请日：1990-02-05
CPC分类号： C07F15/006 , C08G67/02
摘要： An improved process for the production of linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises the use as a catalyst composition of a novel complex containing a diphosphine/hydrocarbylpalladium cation and an anion of a non-hydrohalogenic acid having a pKa below 2. The polymers are useful as engineering thermoplastics.
摘要翻译： 用于生产一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物的改进方法包括用作含有二膦/烃基钯阳离子和具有低于pKa的非氢卤酸的阴离子的催化剂组合物的用途 聚合物可用作工程热塑性塑料。
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公开(公告)号：US5004844A
公开(公告)日：1991-04-02
申请号：US372577
申请日：1989-06-28
IPC分类号： B01J31/12 , C07B61/00 , C07C29/141 , C07C29/145 , C07C31/10 , C07C31/12 , C07C33/14 , C07C35/08
CPC分类号： C07C29/145 , C07C29/141 , C07C2101/14 , C07C2101/16 , C07C2102/42
摘要： A process for the preparation of a primary or secondary alcohol, which comprises hydrogenating respectively an aldehyde or ketone in the presence of a catalyst system comprising a platinum compound, an acid having a pKa in the range from about 2 to about 10.5 and a phosphorus compound of the formula R.sup.1 R.sup.2 POH, wherein R.sup.1 and R.sup.2 each independently represents an alkyl group or a phenyl group, at a temperature in the range from about 20.degree. to about 150.degree. C. and at a pressure in the range from about 1 to about 100 bar.
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公开(公告)号：US4166076A
公开(公告)日：1979-08-28
申请号：US869563
申请日：1978-01-16
IPC分类号： B01J31/00 , C07B61/00 , C07C1/00 , C07C2/46 , C07C2/52 , C07C13/20 , C07C13/263 , C07C67/00 , C07F9/141 , C07C3/21 , C07C3/035
CPC分类号： C07C2/465 , C07C2/52 , C07F9/1411 , C07C2101/16 , C07C2101/18 , C07C2531/02
摘要： 1,5-Dimethyl-1,5-cyclooctadiene and 1,4-dimethyl-4-vinyl-1-cyclohexene are prepared by contacting isoprene with a catalyst obtained by mixing a nickel compound, a reducing agent capable of reducing the nickel to zerovalent nickel, and a trihydrocarbyl phosphite, arsenite or antimonite wherein at least one of the three hydrocarbyl groups is a substituted hydrocarbyl group CF.sub.3 --(CF.sub.2).sub.n C(H)(R)--, in which n.gtoreq.0 and R is an optionally substituted hydrocarbyl group. Only very small amounts of the undesired 1,6-dimethyl-1,5-cyclooctadiene are formed.
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6.发明授权Polymerization of CO/olefin with Hydrocarbyl-Pd halide/bidentate P ligand catalyst complex 失效用烃基 - Pd卤化物/二齿配位体P配体催化剂络合物对CO /烯烃进行聚合
公开(公告)号：US5025091A
公开(公告)日：1991-06-18
申请号：US466559
申请日：1990-01-17
CPC分类号： B01J31/2409 , B01J31/24 , C08G67/02 , B01J2231/10 , B01J2531/824
摘要： Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, useful as premium thermoplastics, are produced by contacting the carbon monoxide and hydrocarbon reactants under polymerization conditions in the presence of a catalyst complex of hydrocarbylpalladium halide and a bidentate ligand of phosphorus. The catalyst complex is produced by contacting a complex of palladium dihalide and the bidentate phosphorus ligand with a tetrahydrocarbyltin.
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公开(公告)号：US4467116A
公开(公告)日：1984-08-21
申请号：US323595
申请日：1981-11-20
IPC分类号： C07C45/50
CPC分类号： C07C45/50
摘要： A process for the hydroformylation of less reactive olefins with hydrogen and carbon monoxide in the presence of a Group VIII-metal hydroformylation catalyst which has been modified by a ligand of formula L(OR.sup.1) (OR.sup.2)(OR.sup.3), wherein L represents P or As and R.sup.1, R.sup.2 and R.sup.3 are similar or dissimilar aryl groups provided that at least one of R.sup.1, R.sup.2, R.sup.3 is a group ##STR1## wherein Q represents a group ##STR2## or a group ##STR3## wherein R.sup.4 is an optionally fluorine-substituted hydrocarbyl group, R.sup.5 is H or R.sup.4, R.sup.6 is H or an inert substituent on the metal and/or the para position of the ring, X is O or S and n is 0 or 1 and R.sup.7 represents a hydrogen atom or an inert substituent. Less reactive olefins such as limonene can be hydroformylated with very good results.
摘要翻译： 在由式L（OR1）（OR2）（OR3）的配体修饰的VIII族金属加氢甲酰化催化剂存在下，用氢和一氧化碳加氢甲酰化较少反应性烯烃的方法，其中L代表P或 As和R 1，R 2和R 3是相似或不同的芳基，条件是R 1，R 2，R 3中的至少一个是基团，其中Q表示基团或其中R 1是任选的氟 取代的烃基，R 5是H或R 4，R 6是H或环上的金属和/或对位上的惰性取代基，X是O或S，n是0或1，而R7代表氢原子或 惰性取代基。 较少的反应性烯烃如柠檬烯可以加氢甲酰化，结果非常好。
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公开(公告)号：US5145823A
公开(公告)日：1992-09-08
申请号：US680443
申请日：1991-04-04
CPC分类号： B01J31/2409 , B01J31/24 , C08G67/02 , B01J2231/10 , B01J2531/824
摘要： Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, useful as premium thermoplastics, are produced by contacting the carbon monoxide and hydrocarbon reactants under polymerization conditions in the presence of a catalyst complex of hydrocarbylpalladium halide and a bidentate ligand of phosphorus. The catalyst complex is produced by contacting a complex of palladium dihalide and the bidentate phosphorus ligand with a tetrahydrocarbyltin.
摘要翻译： 通过在烃基钯卤化物和磷二配位体的催化剂络合物的存在下，在聚合条件下使一氧化碳和烃反应物接触来制备一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物，其可用作优质热塑性塑料。 通过使二卤化钯和二齿磷配体的络合物与四氢碳原子苯接触来制备催化剂络合物。
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公开(公告)号：US4330678A
公开(公告)日：1982-05-18
申请号：US213971
申请日：1980-12-08
CPC分类号： B01J31/185 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J2540/225 , B01J31/1895
摘要： A process for the hydroformylation of an olefin which comprises reacting an olefin with carbon monoxide and hydrogen in the process of a complex of rhodium with a compound of the formula:L(OR.sup.1)(OR.sup.2)(OR.sup.3)wherein L is P or As and R.sup.1, R.sup.2 and R.sup.3 are (dis)similar alkyl, aryl, alkaryl or aralkyl groups, provided that at least one of R.sup.1, R.sup.2 or R.sup.3 represents a group --CH.sub.n [CFXY].sub.3-n, wherein n is 1 or 2 and either(a) X and Y both represent F, or(b) one of X and Y represents F and the other represents H or Cl or an (un)substituted (ar)alkyl group, or(c) X represents H or Cl or an (un)substituted (ar)alkyl group and Y represents an (ar)alkyl group whose connecting carbon atom carries at least one F.
摘要翻译： 一种烯烃加氢甲酰化的方法，其包括在铑络合物与下式化合物：L（OR1）（OR2）（OR3）（其中L为P或As）的化合物的过程中使烯烃与一氧化碳和氢反应，和 R 1，R 2和R 3是（dis）相似的烷基，芳基，烷芳基或芳烷基，条件是R 1，R 2或R 3中的至少一个表示基团-CH n [CFXY] 3-n，其中n为1或2， （a）X和Y都表示F或（b）X和Y之一表示F，另一个表示H或Cl或（un）取代的（芳）烷基，或（c）X表示H或Cl或 （取代）（芳基）烷基，Y表示连接碳原子携带至少一个F.
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公开(公告)号：US5137858A
公开(公告)日：1992-08-11
申请号：US644353
申请日：1991-01-23
CPC分类号： C08G67/02 , B01J31/1875 , B01J31/24 , B01J31/2409 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting the reactants in the presence of a catalyst composition formed from a palladium salt, a bidentate phosphorus ligand, and a tertiary monophosphine or a secondary phosphine oxide present in specified quantity.
摘要翻译： 用于生产一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物的改进方法包括在由钯盐，二齿磷配位体和叔三膦或仲膦制成的催化剂组合物存在下使反应物接触 氧化物以规定量存在。
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