VINYL ESTER/ETHYLENE-BASED BINDERS FOR PAPER AND PAPERBOARD COATINGS
    1.
    发明申请
    VINYL ESTER/ETHYLENE-BASED BINDERS FOR PAPER AND PAPERBOARD COATINGS 审中-公开
    乙烯基酯/乙烯基纸和纸板涂料的粘合剂

    公开(公告)号:US20120021237A1

    公开(公告)日:2012-01-26

    申请号:US12839662

    申请日:2010-07-20

    Abstract: Disclosed are surfactant-stabilized latex emulsions which can be used as binders in paper coating compositions. Such latex emulsions comprise an interpolymer formed by emulsion polymerizing monomers selected from vinyl esters, e.g., vineyl acetate; ethylene; certain unsaturated mono- and di-carboxylic acid materials such as acrylic acid or maleic anhydride; and certain polyethylenically unsaturated cross-linking co-monomers such as diallyl phthalate. These latex emulsions are stabilized with surfactants which are substantially free of environmentally suspect alkyl phenol ethoxylates (APEs). The paper coating compositions containing latex emulsion binders of this type exhibit especially desirable coating strength as quantified by the Dry Pick Values (as defined herein) which such compositions provide.

    Abstract translation: 公开了可用作纸涂料组合物中的粘合剂的表面活性剂稳定的胶乳乳液。 这种胶乳乳液包含通过乳液聚合选自乙烯基酯的单体形成的互聚物,例如乙酸葡萄酯; 乙烯; 某些不饱和单羧酸和二羧酸物质如丙烯酸或马来酸酐; 和某些多烯属不饱和交联共聚单体如邻苯二甲酸二烯丙酯。 这些胶乳乳液用基本上不含环保的烷基酚乙氧基化物(APE)的表面活性剂稳定。 含有这种胶乳乳液粘合剂的纸张涂料组合物显示出特别理想的涂层强度,其通过这种组合物提供的干燥选择值(如本文所定义)而定量。

    FUNCTIONALIZED VINYL ACETATE ETHYLENE BINDERS FOR PAPER AND PAPERBOARD COATINGS
    2.
    发明申请
    FUNCTIONALIZED VINYL ACETATE ETHYLENE BINDERS FOR PAPER AND PAPERBOARD COATINGS 审中-公开
    功能性醋酸乙烯酯纸和纸板涂料

    公开(公告)号:US20160115649A1

    公开(公告)日:2016-04-28

    申请号:US14406893

    申请日:2012-09-10

    Abstract: A paper product comprising a planar fibrous cellulose substrate, and a coating composition disposed on a surface of said substrate comprising an interpolymer prepared by the emulsion polymerization of (i) one or more vinyl ester monomers; (ii) ethylene; (iii) an unsaturated silane co-monomer; and (iv) one or more emulsion-stabilizing ionic co-monomers comprising one or more of unsaturated, substituted sulfonic acid, one or more of an unsaturated phosphonic acid, or an ester of one of those acids, in the presence of (v) a stabilizing system which comprises one or more anionic and/or nonionic surfactants but less than about 1 pphm of any protective colloid material; and (v) water.

    Abstract translation: 一种纸制品,其包含平面纤维素纤维素基质和涂布组合物,所述涂料组合物设置在所述基材的表面上,所述涂料组合物包含通过(i)一种或多种乙烯基酯单体的乳液聚合制备的互聚物; (ii)乙烯; (iii)不饱和硅烷共聚单体; 和(iv)一种或多种乳液稳定的离子共聚单体,其包含一种或多种不饱和的,取代的磺酸,一种或多种不饱和膦酸或这些酸之一的酯,在(v) 稳定系统,其包含一种或多种阴离子和/或非离子表面活性剂,但小于约1pphm的任何保护胶体材料; 和(v)水。

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