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1.
公开(公告)号:US10862161B2
公开(公告)日:2020-12-08
申请号:US16102606
申请日:2018-08-13
发明人: Dong Hee Anna Choi , Niall Donnelly , Tim Holme , Will Hudson , Sriram Iyer , Oleh Karpenko , Mohit Singh , Adrian Winoto
IPC分类号: H01M10/0562 , C04B35/486 , C04B35/495 , C04B35/645 , H01M10/0525 , C04B35/626 , C04B35/65 , H01M10/0585 , C01G25/00 , C04B35/488 , C04B35/622 , C04B35/64 , C04B41/00 , C04B41/50 , C04B35/117 , H01M10/052 , H01M10/056 , H01M10/0561 , H01M4/86 , H01M4/36
摘要: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (
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2.
公开(公告)号:US10431850B2
公开(公告)日:2019-10-01
申请号:US15632011
申请日:2017-06-23
发明人: Dong Hee Anna Choi , Niall Donnelly , Tim Holme , Will Hudson , Sriram Iyer , Oleh Karpenko , Kian Kerman , Mohit Singh , Adrian Winoto
IPC分类号: H01M4/36 , H01M10/0562 , H01M10/0525 , C04B35/626 , C04B35/65 , H01M10/0585 , C01G25/00 , C04B35/488 , C04B35/622 , C04B35/64 , C04B35/486 , C04B35/495 , C04B35/645 , C04B41/00 , C04B41/50 , C04B35/117 , H01M10/052 , H01M10/056 , H01M10/0561 , H01M4/86
摘要: Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (
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3.
公开(公告)号:US09806372B2
公开(公告)日:2017-10-31
申请号:US14531929
申请日:2014-11-03
发明人: Tim Holme , Niall Donnelly , Sriram Iyer , Adrian Winoto , Mohit Singh , Will Hudson , Dong Hee Anna Choi , Oleh Karpenko , Kian Kerman
IPC分类号: H01M10/0562 , H01M10/0525 , C04B35/626 , C04B35/65 , H01M10/0585 , C01G25/00 , C04B35/488 , C04B35/622 , C04B35/64 , H01M10/052 , H01M10/056 , H01M10/0561
CPC分类号: H01M10/0562 , C01G25/006 , C01P2006/40 , C04B35/117 , C04B35/486 , C04B35/4885 , C04B35/495 , C04B35/62218 , C04B35/6261 , C04B35/6262 , C04B35/64 , C04B35/645 , C04B35/65 , C04B41/009 , C04B41/5027 , C04B2235/3203 , C04B2235/3205 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3222 , C04B2235/3227 , C04B2235/3229 , C04B2235/3244 , C04B2235/3248 , C04B2235/3251 , C04B2235/3255 , C04B2235/3256 , C04B2235/3258 , C04B2235/3294 , C04B2235/6025 , C04B2235/656 , C04B2235/6567 , C04B2235/661 , C04B2235/666 , C04B2235/764 , C04B2235/786 , C04B2235/96 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0561 , H01M10/0585 , H01M2300/0071 , H01M2300/0091
摘要: Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (
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公开(公告)号:US20160172658A1
公开(公告)日:2016-06-16
申请号:US15050789
申请日:2016-02-23
发明人: Niall Donnelly , Tim Holme
IPC分类号: H01M4/04
CPC分类号: H01M4/0409 , C01G25/006 , C01P2004/61 , C04B35/00 , C04B35/486 , C04B35/62218 , C04B35/62645 , C04B35/653 , C04B2235/3203 , C04B2235/3227 , C04B2235/5436 , C04B2235/764 , C04B2235/787 , H01M10/0525 , H01M10/0562 , H01M10/058 , Y02T10/7011
摘要: The present invention is directed to battery technologies and processing techniques thereof. In various embodiments, ceramic electrolyte powder material (or component thereof) is mixed with two or more flux to form a fluxed powder material. The fluxed powder material is shaped and heated again at a temperature less than 1100° C. to form a dense lithium conducting material. There are other variations and embodiments as well.
摘要翻译: 本发明涉及电池技术及其处理技术。 在各种实施方案中,将陶瓷电解质粉末材料(或其组分)与两种或更多种助熔剂混合以形成助熔粉末材料。 在低于1100℃的温度下再次成形并加热熔化的粉末材料以形成致密的锂导电材料。 还有其他变化和实施例。
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公开(公告)号:US10746468B2
公开(公告)日:2020-08-18
申请号:US15787623
申请日:2017-10-18
发明人: Sriram Iyer , Tim Holme , Niall Donnelly
IPC分类号: C04B35/64 , C04B35/119 , C04B35/44 , C04B35/48 , C04B35/488 , F27D5/00 , H01M10/052 , H01M10/0585 , C04B35/10 , C04B35/486 , C08K3/105 , C08K5/09 , C08K5/12 , H01M10/0562 , B28B7/00 , H01M10/0525 , B30B15/34 , F27B17/02 , F27B21/02 , H01M10/04 , C08K3/22
摘要: Setter plates are fabricated from Li-stuffed garnet materials having the same, or substantially similar, compositions as a garnet Li-stuffed solid electrolyte. The Li-stuffed garnet setter plates, set forth herein, reduce the evaporation of Li during a sintering treatment step and/or reduce the loss of Li caused by diffusion out of the sintering electrolyte. Li-stuffed garnet setter plates, set forth herein, maintain compositional control over the solid electrolyte during sintering when, upon heating, lithium is prone to diffuse out of the solid electrolyte.
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6.
公开(公告)号:US20190334204A1
公开(公告)日:2019-10-31
申请号:US16389842
申请日:2019-04-19
发明人: Tim Holme , Niall Donnelly
IPC分类号: H01M10/0562 , H01M10/0525 , C04B35/645 , C04B35/622 , C04B35/64 , C04B35/626 , C04B41/50 , C04B35/486 , C04B35/117 , C04B35/488 , C04B35/495 , C01G25/00 , C04B35/65 , H01M10/0585 , C04B41/00
摘要: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (
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公开(公告)号:US10361455B2
公开(公告)日:2019-07-23
申请号:US15908732
申请日:2018-02-28
发明人: Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , Will Gardner , Tim Holme , Sriram Iyer , Shuang Li
IPC分类号: H01M2/14 , H01M10/0565 , H01M10/0562 , H01M10/052 , H01M10/056 , H01M10/058 , C04B35/488 , C04B35/622
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号:US10431806B2
公开(公告)日:2019-10-01
申请号:US15050789
申请日:2016-02-23
发明人: Niall Donnelly , Tim Holme
IPC分类号: H01M4/04 , C04B35/00 , H01M10/0525 , H01M10/0562 , H01M10/058 , C01G25/00 , C04B35/486 , C04B35/622 , C04B35/626 , C04B35/653
摘要: The present invention is directed to battery technologies and processing techniques thereof. In various embodiments, ceramic electrolyte powder material (or component thereof) is mixed with two or more flux to form a fluxed powder material. The fluxed powder material is shaped and heated again at a temperature less than 1100° C. to form a dense lithium conducting material. There are other variations and embodiments as well.
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9.
公开(公告)号:US10403931B2
公开(公告)日:2019-09-03
申请号:US14509025
申请日:2014-10-07
发明人: Tim Holme , Niall Donnelly
IPC分类号: H01M10/052 , H01M10/0562 , H01M10/0525 , C04B35/626 , C04B35/65 , H01M10/0585 , C01G25/00 , C04B35/488 , C04B35/622 , C04B35/64 , C04B35/486 , C04B35/495 , C04B35/645 , C04B41/00 , C04B41/50 , C04B35/117 , H01M10/056 , H01M10/0561 , H01M4/86 , H01M4/36
摘要: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (
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公开(公告)号:US09966630B2
公开(公告)日:2018-05-08
申请号:US15007908
申请日:2016-01-27
发明人: Lei Cheng , Sriram Iyer , Will Gardner , Tim Holme , Shuang Li , Cheng-chieh Chao , Niall Donnelly , Arnold Allenic
IPC分类号: H01M2/14 , H01M10/0562 , H01M10/0565
CPC分类号: H01M10/0562 , H01M2/145 , H01M10/052 , H01M10/056 , H01M10/0565 , H01M10/058
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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