公开(公告)号：US09969670B2

公开(公告)日：2018-05-15

申请号：US15111258

申请日：2015-01-20

Applicant: RHODIA OPERATIONS

Inventor： Pierre Ardaud ,  Thierry Vidal ,  Rabih Rached

IPC: C07C67/48 ,  C07C51/573 ,  C07C51/56

CPC classification number: C07C51/573 ,  C07C51/56 ,  C07C57/04

Abstract: The invention relates to a method for producing a (meth)acrylic anhydride A-C(═O)—O—(O═)C-A, comprising the following steps: a) a step of reacting an anhydride B—C(═O)—O—(O═)C—B with an acid A-COOH, resulting in the formation of mixed anhydride A-C(═O)—O—(O═)C—B and acid B—COOH; and b) a step of reacting the mixed anhydride with A-COOH, resulting in the (meth)acrylic anhydride. According to the invention, reaction steps (a) and (b) are carried out in the presence of hydrated triflic acid, and the anhydride A-C(═O)—O—(O═)C-A is isolated from the reaction medium produced in step (b) as follows: e1) heavy compounds having a volatility less than or equal to that of the anhydride A-C(═O)—O—(O═)C-A are separated from the reaction medium, said compounds including the anhydride and the hydrated triflic acid; e2) the anhydride is separated from the heavy compounds by difference in volatility.

公开(公告)号：US20140256554A1

公开(公告)日：2014-09-11

申请号：US14350599

申请日：2012-10-11

Applicant: RHODIA OPERATIONS

Inventor： Thierry Vidal ,  Benoit Abribat ,  Valerio Bramati ,  Marc Balastre

IPC: A01N25/02 ,  A01N25/04

CPC classification number: A01N25/02 ,  A01N25/04 ,  A01N31/14 ,  A01N33/18 ,  A01N33/20 ,  A01N37/22 ,  A01N37/26 ,  A01N37/40 ,  A01N43/12 ,  A01N43/653 ,  A01N43/90 ,  A01N47/22 ,  A01N47/34 ,  A01N47/38 ,  A01N51/00 ,  A01N53/00 ,  A01N57/12 ,  A01N57/16

Abstract: The present disclosure relates to compositions comprising from 10 to 90 wt % of a mixture M of compounds A having formula R1CONR2R3, wherein R1, R2, and R3 are described herein, and from 10 to 90 wt % of at least one compound B selected from the amide solvents, optionally combined with an ester solvent, and methods for producing the same. The present disclosure further relates to phytosanitary formulations comprising such compositions.

Abstract translation: 本公开内容涉及包含10至90重量％的混合物M的具有式R1CONR2R3的化合物A（其中R1，R2和R3如本文所述）和10至90重量％的至少一种选自以下的化合物B 任选地与酯溶剂组合的酰胺溶剂及其制备方法。 本公开还涉及包含这种组合物的植物检疫制剂。

公开(公告)号：US20220386603A1

公开(公告)日：2022-12-08

申请号：US17770033

申请日：2020-10-16

Applicant: RHODIA OPERATIONS

Inventor： Jean-Christophe Castaing ,  Clara Vernay ,  Francisco Lopez ,  Thierry Vidal

IPC: A01N43/16 ,  A01C1/06 ,  A01N25/02 ,  A01N25/12

Abstract: The present invention provides a method for increasing the growth of a plant by contacting a seed of the plant with a composition comprising a guar gum having an average molecular weight of between 2,000 Daltons and 90,000 Daltons. The present invention also provides a seed treated with a guar gum having an average molecular weight of between 2,000 Daltons and 90,000 Daltons.

公开(公告)号：US09420780B2

公开(公告)日：2016-08-23

申请号：US14350599

申请日：2012-10-11

Applicant: RHODIA OPERATIONS

Inventor： Thierry Vidal ,  Benoit Abribat ,  Valerio Bramati ,  Marc Balastre

IPC: A01N25/02 ,  A01N25/04

CPC classification number: A01N25/02 ,  A01N25/04 ,  A01N31/14 ,  A01N33/18 ,  A01N33/20 ,  A01N37/22 ,  A01N37/26 ,  A01N37/40 ,  A01N43/12 ,  A01N43/653 ,  A01N43/90 ,  A01N47/22 ,  A01N47/34 ,  A01N47/38 ,  A01N51/00 ,  A01N53/00 ,  A01N57/12 ,  A01N57/16

Abstract: The present disclosure relates to compositions comprising from 10 to 90 wt % of a mixture M of compounds A having formula R1CONR2R3, wherein R1, R2, and R3 are described herein, and from 10 to 90 wt % of at least one compound B selected from the amide solvents, optionally combined with an ester solvent, and methods for producing the same. The present disclosure further relates to phytosanitary formulations comprising such compositions.

Abstract translation: 本公开内容涉及包含10至90重量％的混合物M的具有式R1CONR2R3的化合物A（其中R1，R2和R3如本文所述）和10至90重量％的至少一种选自以下的化合物B 任选地与酯溶剂组合的酰胺溶剂及其制备方法。 本公开还涉及包含这种组合物的植物检疫制剂。

公开(公告)号：US11284558B2

公开(公告)日：2022-03-29

申请号：US16192952

申请日：2018-11-16

Applicant: RHODIA OPERATIONS

Inventor： Clara Vernay ,  Jean-Christophe Castaing ,  Zhiyun Chen ,  Thierry Vidal

IPC: A01C1/06 ,  C09D105/00 ,  C09D103/12 ,  C09D105/02 ,  C09D103/02

Abstract: A seed or seedling is coated with a cross-linked biopolymer and, optionally, a second binder selected from underivatized guar, cationic hydroxypropyl guar, polyacrylamide, poly(methacrylic acid), poly(acrylic acid), polyacrylate, poly(ethylene glycol), polyethyleneoxide, polyamide, hydroxypropyl guar, carboxymethyl guar, carboxymethylhydroxypropyl guar, underivatized starch, cationic starch, corn starch, wheat starch, rice starch, potato starch, tapioca, waxy maize, sorghum, waxy sarghum, sago, dextrin, chitin, chitosan, xanthan gum, carageenan gum, gum karaya, gum arabic, pectin, cellulose, hydroxycellulose, hydroxyalkyl cellulose, hydroxyethyl cellulose, carboxymethylhydroxyethyl cellulose, or hydroxypropyl cellulose. The seed coating composition is characterized by a dust value, as measured using a Heubach dustmeter device, which is lower by at least 30% as compared to an analogous composition that does not contain the crosslinked biopolymer.

公开(公告)号：US20150208645A1

公开(公告)日：2015-07-30

申请号：US14416926

申请日：2013-07-25

Applicant: RHODIA OPERATIONS

Inventor： Thierry Vidal ,  Valerio Bramati

IPC: A01N25/02 ,  C07C235/06 ,  A01N25/30

CPC classification number: A01N25/02 ,  A01N25/30 ,  C07C235/06 ,  A01N33/18 ,  A01N33/22 ,  A01N37/22 ,  A01N43/54 ,  A01N43/653 ,  A01N47/22 ,  A01N53/00 ,  A01N57/12 ,  A01N57/16

Abstract: The object of the present invention is phytosanitary compositions comprising an active phytosanitary product and an ether-amide compound. The ether-amide compound may natively be present as a solvent, co-solvent, crystallization inhibitor or an agent for increasing bioactivity of the active phytosanitary product.

Abstract translation: 本发明的目的是包含活性植物检疫产物和醚 - 酰胺化合物的植物检疫组合物。 醚 - 酰胺化合物可以本身作为溶剂，共溶剂，结晶抑制剂或用于提高活性植物检疫产品的生物活性的试剂存在。