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    Storage stable aqueous formulations based on N-phenyl-3,4,5,6-tetrahydrophthalimide herbicides
    2.
    发明授权
    Storage stable aqueous formulations based on N-phenyl-3,4,5,6-tetrahydrophthalimide herbicides 失效
    基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺除草剂的储存稳定的水性制剂

    公开(公告)号：US06313070B1

    公开(公告)日：2001-11-06

    申请号：US09582883

    申请日：2000-07-06

    申请人： Matthias Bratz ,  Rainer Berghaus ,  August Wigger ,  Adolf Parg ,  Wessel Nuyken

    发明人： Matthias Bratz ,  Rainer Berghaus ,  August Wigger ,  Adolf Parg ,  Wessel Nuyken

    IPC分类号： A01N2530

    CPC分类号： A01N37/32 ,  A01N37/46 ,  A01N43/84 ,  A01N25/04 ,  A01N2300/00

    摘要： Storage-stable aqueous formulations comprising a) 0.1-60% by weight of a tetrahydrophthalimide of the formula I  where R1=H, F, Cl; R2=CH═C(Cl)—CO—B or CH═C(Br)—CO—B (B=C1-C6-alkyl, unsubstituted or substituted OH or SH); a group OR5, SR5, COOR5, OCH2COOR5, CH2—CO—OR6 or (C1-C6-alkyl)sulfonylamino; R5=H, C1-C6-alkyl, C3-C7-cycloalkyl, C2-C8-alkenyl, C2-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl R3=Cl, CN; R6=is H, C1-C6-alkyl, C2-C8-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl; b) 0.1-30% by weight of an anionic surfactant; c) 0.1-30% by weight of a non-ionic surfactant; d) 0.01-5% by weight of a thixotroping additive; e) 0-50% by weight of other herbicidal active ingredients; f) 0-20% by weight of other formulation auxiliaries, and g) 1-90% of water. Storage-stable aqueous formulations based on N-phenyl- 3,4,5,6 -tetrahydrophthalimide derivatives, and their use as herbicides in crop protection

    摘要翻译： 其中R1 = H，F，Cl; R2 = CH = C（C1）-CO-B或CH = C（Br）-CO-B的四氢邻苯二甲酰亚胺， B（B = C1-C6-烷基，未取代或取代的OH或SH）; OR5，SR5，COOR5，OCH2COOR5，CH2-CO-OR6或（C1-C6-烷基）磺酰基氨基; R5 = H，C1-C6 - 烷基，C 3 -C 7 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 6 - 炔基，（C 1 -C 6 - 烷氧基）羰基-C 1 -C 6烷基或C 1 -C 6烷氧基肟基-C 1 -C 6烷基R 3 = CN; R6 =是H，C1-C6-烷基，C2-C8-烯基，C2-C6-炔基，C3-C7-环烷基，C1-C6-烷氧基-C1-C6-烷基或C1-C6-烷氧基肟基C1 -C6-烷基; b）0.1-30重量％的阴离子表面活性剂; c）0.1-30重量％的非离子表面活性剂; d）0.01-5重量％的触变添加剂; e）0- 50重量％的其它除草活性成分; f）0-20重量％的其它制剂助剂，和g）1-90重量％的水。 基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺衍生物的储存稳定的水性制剂及其作为农作物保护中除草剂的用途

    Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates
    3.
    发明授权
    Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates 有权
    环己烯酮肟醚/（草甘膦/草甘膦）悬浮浓缩物

    公开(公告)号：US06383987B1

    公开(公告)日：2002-05-07

    申请号：US09868072

    申请日：2001-08-02

    申请人： Jürgen von der Heyde ,  Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Karl-Friedrich Jäger ,  Jürgen Fries ,  Adolf Parg

    发明人： Jürgen von der Heyde ,  Reiner Kober ,  Matthias Bratz ,  Rainer Berghaus ,  Karl-Friedrich Jäger ,  Jürgen Fries ,  Adolf Parg

    IPC分类号： A01N4380

    CPC分类号： A01N57/20 ,  A01N2300/00

    摘要： A substantially water-free formulation of crop protection agents, comprising essentially a) a cyclohexenone oxime ether of the formula I  where R1=ethyl, propyl; R2=hydrogen or an equivalent of an agriculturally useful cation; R3=2-(thioethyl)propyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-(methylthio)cyclopropyl, 5-(isopropyl)isoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl; R4, R5=H, CH3, CO—OCH3; Alk=CH2CH2, CH2CH(CH3), CH2CH═CH, CH2CH═C(Cl), CH2CH2CH═CH; R6=H, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy, dihalophenoxy; b) N-phosphonamethylglycine, or an ester or salt thereof, DL-homoalanin-4-yl(methyl)phosphinic acid or its ammonium salt; c) from 20 to 80% by weight of an aprotic or weakly protic solvent in which the components a) and b) are suspended; d) if desired emulsifiers, surfactants, surface-active and/or activity-enhancing auxiliaries, is described.

    摘要翻译： 基本上无水的作物保护剂制剂，其基本上包括式I的环己烯酮肟醚，其中R 1 =乙基，丙基; R 2 =氢或相当于农业上可用的阳离子; R 3 = 2-（硫代乙基）丙基，四氢噻喃 吡啶-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-（甲硫基）环丙基，5-（异丙基）异恶唑-3-基，2,5-二甲基吡唑-3-基 ，2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R4，R5 = H，CH3，CO-OCH3; Alk = CH2CH2，CH2CH（CH3），CH2CH = CH，CH2CH = C（ Cl），CH 2 CH 2 CH = CH; R 6 = H，苯基，卤代苯基，二卤代苯氧基，苯氧基，卤代苯氧基，二卤苯氧基; b）N-膦酰基甲基甘氨酸或其酯或盐，DL-高拉蛋白-4-基（甲基）次膦酸或其 铵盐; c）20至80重量％的非质子或弱质子溶剂，其中组分a）和b）悬浮; d）如果需要，乳化剂，表面活性剂，表面活性剂和/或活性增强助剂， 被描述。

    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative
    7.
    发明授权
    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative 有权
    含有3-杂环基取代的苯甲酰基衍生物的除草混合物

    公开(公告)号：US06479437B1

    公开(公告)日：2002-11-12

    申请号：US09701875

    申请日：2000-12-05

    申请人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

    发明人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

    IPC分类号： A01N4356

    CPC分类号： C05G3/02 ,  A01N43/78 ,  A01N43/80 ,  A01N2300/00

    摘要： A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I  in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.

    摘要翻译： 一种除草混合物，其包含a）除草活性量的式I的3-杂环基取代的苯甲酰基衍生物，其中所述变量具有以下含义：R 1，R 2是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷硫基 ，C 1 -C 6烷基亚磺酰基，C 1 -C 6烷基磺酰基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 1 -C 6卤代烷氧基; R 3是氢，卤素，C 1 -C 6烷基; X是 由异唑基，4,5-二氢异恶唑基和噻唑基组成的组，可以将杂环任选被卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基，R 6是C 1 -C 6 - 烷基或其环境相容的盐; b）具有协同有效量的含氮肥料，和c）协同有效的佐剂 量。

    Amphiphilic polymer compositions and their use
    8.
    发明授权
    Amphiphilic polymer compositions and their use 有权
    两亲聚合物组合物及其用途

    公开(公告)号：US07872067B2

    公开(公告)日：2011-01-18

    申请号：US11628609

    申请日：2005-06-07

    申请人： Günter Oetter ,  Christian Krüger ,  Harald Köhle ,  Maria Scherer ,  Norbert Wagner ,  Matthias Bratz ,  Rainer Berghaus ,  Richard van Gelder

    发明人： Günter Oetter ,  Christian Krüger ,  Harald Köhle ,  Maria Scherer ,  Norbert Wagner ,  Matthias Bratz ,  Rainer Berghaus ,  Richard van Gelder

    IPC分类号： C08G18/08

    CPC分类号： A01N25/04 ,  A01N25/30 ,  C08G18/283 ,  C08G18/3876 ,  C08G18/7831 ,  C08L33/06 ,  C08L75/04 ,  A01N47/24 ,  A01N43/653 ,  A01N43/40 ,  A01N53/00 ,  C08L2666/04

    摘要： The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection.The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I  in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C. is less than 50 g/l and which are different from the monomers M1a; and a3) up to 30% by weight, based on the total amount of monomers M1, of ethylenically unsaturated monomers M1c which are different from the monomers M1a and M1b, b) at least one hydrophilic polymer P2 which carries functional groups R2 which are reactive toward isocyanate groups, c) with at least one compound V which contains isocyanate groups and, with respect to the isocyanate groups, has a functionality of at least 1.5.

    摘要翻译： 本发明涉及两亲聚合物组合物，其制备方法及其用于制备水不溶性活性化合物，特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。 两亲聚合物组合物可以通过使a）至少一种携带官能团R1的异氰酸酯基团反应的疏水性聚合物P1，其由烯属不饱和单体M1构成，其包含：a1）至少10重量％ 单体M1的总量，其中X是氧或基团N-R4的式I的单体M1a; R1，R2，R3和R4如权利要求和说明书所定义; a2）高达90重量％，基于单体M1的总量，在25℃下在水中的溶解度小于50g / l且不同于单体M1a的中性单烯属不饱和单体M1b; 和a3）至多30重量％，基于单体M1的总量，不同于单体M1a和M1b的烯键式不饱和单体M1c，b）至少一个带有官能团R2的亲水性聚合物P2，其具有反应性 c）与至少一种含有异氰酸酯基团的化合物V相对于异氰酸酯基具有至少1.5的官能度。

    AQUEOUS ACTIVE INGREDIENT CONCENTRATE HAVING AN HERBICIDAL EFFECT
    9.
    发明申请
    AQUEOUS ACTIVE INGREDIENT CONCENTRATE HAVING AN HERBICIDAL EFFECT 审中-公开
    具有除草效果的水性活性成分浓度

    公开(公告)号：US20100160165A1

    公开(公告)日：2010-06-24

    申请号：US12376310

    申请日：2007-08-03

    申请人： Matthias Bratz ,  Rainer Berghaus ,  Ulrich Steinbrenner

    发明人： Matthias Bratz ,  Rainer Berghaus ,  Ulrich Steinbrenner

    IPC分类号： A01N43/56

    CPC分类号： A01N43/56 ,  A01N25/30 ,  A01N37/44 ,  A01N37/40 ,  A01N37/10 ,  A01N2300/00

    摘要： The present invention relates to aqueous active compound concentrates having herbicidal action. The compound contains, in dissolved form: c) at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1 and R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts; and d) at least one benzoic acid derivative of the formula II in which R7 is hydrogen, halogen, hydroxyl or methoxy and R8 is hydrogen, halogen or amino; or one of its agriculturally useful salts.

    摘要翻译： 本发明涉及具有除草作用的水性活性化合物浓缩物。 该化合物含有溶解形式：c）至少一种其中R 1和R 3彼此独立地为氢，卤素，甲基，卤代甲基，甲氧基，卤代甲氧基，甲硫基，甲基亚磺酰基或甲硫基的式I的4-苯甲酰基取代的吡唑化合物 甲基磺酰基; R2是未取代的或携带1,2,3或4个选自卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基和C 1 -C 4的取代基的5元杂环基 - 烷硫基; R4是氢，卤素或甲基; R5是C1-C6-烷基，C3-C6-环烷基或C3-C6-环烷基甲基; 和R6是氢或C1-C4-烷基; 或其农业上有用的盐之一; 和d）至少一种式II的苯甲酸衍生物，其中R 7是氢，卤素，羟基或甲氧基，R 8是氢，卤素或氨基; 或其农业上有用的盐之一。