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    Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
    1.
    发明申请
    Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids 有权
    使用芳族磺酸和/或多磺酸的金属盐改变焦炭形态的方法

    公开(公告)号：US20090184029A1

    公开(公告)日：2009-07-23

    申请号：US12010145

    申请日：2008-01-22

    申请人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown ,  Cornelius H. Brons

    发明人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown ,  Cornelius H. Brons

    IPC分类号： C10G9/14

    CPC分类号： C10B55/00 ,  C10B57/06

    摘要： A method for altering coke morphology in a delayed coking process of heavy oil is provided. An effective amount of oil dispersible or oil soluble metal salts of aromatic sulfonic acids and/or polysulfonic acids is added or contacted with the resid or heavy oil at a point before or after the step of heating the heavy oil to coking temperatures. The addition of additives facilitates the formation of shot coke and inhibits the formation of sponge coke.

    摘要翻译： 提供了一种在重油延迟焦化过程中改变焦炭形态的方法。 在将重油加热至焦化温度的步骤之前或之后的一点加入芳族磺酸和/或多磺酸的有效量的油分散性或油溶性金属盐与残油或重油接触。 添加添加剂促进了焦炭的形成并抑制海绵焦炭的形成。

    Delayed coking process for producing free-flowing coke using polymeric additives
    4.
    发明授权
    Delayed coking process for producing free-flowing coke using polymeric additives 有权
    使用聚合物添加剂生产自由流动焦炭的延迟焦化工艺

    公开(公告)号：US07658838B2

    公开(公告)日：2010-02-09

    申请号：US11127822

    申请日：2005-05-12

    申请人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown

    发明人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown

    IPC分类号： C10G9/00

    CPC分类号： C10B55/00 ,  C10B57/06 ,  C10G9/005 ,  C10G29/06 ,  C10G29/20 ,  C10G29/22 ,  C10G55/04 ,  C10G2300/107

    摘要： A delayed coking process for making substantially free-flowing coke, preferably shot coke. A coker feedstock, such as a vacuum residuum, is heated in a heating zone to coking temperatures then conducted to a coking zone wherein volatiles are collected overhead and coke is formed. At least one polymeric additive is added to the feedstock prior to it being heated in the heating zone, prior to its being conducted to the coking zone, or both.

    摘要翻译： 一种延迟焦化工艺，用于制造基本上自由流动的焦炭，优选喷射焦炭。 焦化原料如真空残渣在加热区被加热至焦化温度，然后进入焦化区，其中挥发物在塔顶馏出并形成焦炭。 至少一种聚合物添加剂在其被加热到加热区之前，在其被引导到焦化区之前或两者之前被加入到原料中。

    Method to alter coke morphology using either polynuclear aromatic compounds or functionalized lignin
    6.
    发明授权
    Method to alter coke morphology using either polynuclear aromatic compounds or functionalized lignin 失效
    使用多核芳香族化合物或官能化木质素改变焦炭形态的方法

    公开(公告)号：US07871511B2

    公开(公告)日：2011-01-18

    申请号：US12213758

    申请日：2008-06-24

    申请人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown

    发明人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown

    IPC分类号： C10G9/14

    CPC分类号： C10B55/00 ,  C10B57/06

    摘要： A method for altering coke morphology in a delayed coking process of heavy oil is provided. An effective amount of one or more oil dispersible or oil soluble polynuclear aromatic compounds, or functionalized lignin, is added or contacted with the resid or heavy oil at a point before or after the step of heating the heavy oil to coking temperatures. The addition of additives facilitates the formation of shot coke and inhibits the formation of sponge coke.

    摘要翻译： 提供了一种在重油延迟焦化过程中改变焦炭形态的方法。 在将重油加热至焦化温度的步骤之前或之后的时刻，将有效量的一种或多种油分散性或油溶性多核芳族化合物或官能化木质素与残油或重油相加或接触。 添加添加剂促进了焦炭的形成并抑制海绵焦炭的形成。

    Method to alter coke morphology using either polynuclear aromatic compounds or functionalized lignin
    8.
    发明申请
    Method to alter coke morphology using either polynuclear aromatic compounds or functionalized lignin 失效
    使用多核芳香族化合物或官能化木质素改变焦炭形态的方法

    公开(公告)号：US20090314689A1

    公开(公告)日：2009-12-24

    申请号：US12213758

    申请日：2008-06-24

    申请人： Ramesh Varadaraj ,  Siskin Michael ,  Leo D. Brown

    发明人： Ramesh Varadaraj ,  Siskin Michael ,  Leo D. Brown

    IPC分类号： C10G1/00

    CPC分类号： C10B55/00 ,  C10B57/06

    摘要： A method for altering coke morphology in a delayed coking process of heavy oil is provided. An effective amount of one or more oil dispersible or oil soluble polynuclear aromatic compounds, or functionalized lignin, is added or contacted with the resid or heavy oil at a point before or after the step of heating the heavy oil to coking temperatures. The addition of additives facilitates the formation of shot coke and inhibits the formation of sponge coke.

    摘要翻译： 提供了一种在重油延迟焦化过程中改变焦炭形态的方法。 在将重油加热至焦化温度的步骤之前或之后的时刻，有效量的一种或多种油分散性或油溶性多核芳族化合物或官能化木质素与残油或重油相加或接触。 添加添加剂促进了焦炭的形成并抑制海绵焦炭的形成。

    Delayed coking process
    9.
    发明授权
    Delayed coking process 失效
    延迟焦化工艺

    公开(公告)号：US08147676B2

    公开(公告)日：2012-04-03

    申请号：US11256728

    申请日：2005-10-21

    申请人： Michael Siskin ,  David T. Ferrughelli ,  Martin L. Gorbaty ,  Simon R. Kelemen ,  Leo D. Brown

    发明人： Michael Siskin ,  David T. Ferrughelli ,  Martin L. Gorbaty ,  Simon R. Kelemen ,  Leo D. Brown

    IPC分类号： C10B55/00

    CPC分类号： C10B57/06 ,  C10B55/00 ,  C10B57/08 ,  C10G9/005 ,  C10G55/04 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206

    摘要： The present invention relates to an improved delayed coking process. A coker feed, such as a vacuum resid, is treated with (i) a metal-containing agent and (ii) an oxidizing agent. The feed is treated with the oxidizing agent at an oxidizing temperature. The oxidized feed is then pre-heated to coking temperatures and conducted to a coking vessel for a coking time to allow volatiles to evolve and to produce a substantially free-flowing coke. A metals-containing composition is added to the feed at at least one of the following points in the process: prior to the heating of the feed to coking temperatures, during such heating, and/or after such heating.

    摘要翻译： 本发明涉及一种改进的延迟焦化方法。 用（i）含金属试剂和（ii）氧化剂处理焦化饲料如真空渣油。 在氧化温度下用氧化剂处理进料。 然后将氧化的进料预加热至焦化温度，并导入焦化容器中以获得焦化时间，以允许挥发物放出并产生基本上自由流动的焦炭。 在此过程中，将进料加热至焦化温度，在此加热期间和/或在此类加热之后，将含金属的组合物加入到进料中的至少一个方面。