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公开(公告)号：US5496895A
公开(公告)日：1996-03-05
申请号：US942132
申请日：1992-09-08
IPC分类号： C08G81/00 , C08F8/00 , C08G81/02 , C08L3/10 , C08L89/00 , C08L101/00 , C08L101/16 , C08G63/48 , C08F32/00 , C08G63/91
CPC分类号： C08L3/10 , C08L101/00 , C08L89/00
摘要： To prepare a biodegradable plastic, biodegradable materials such as starches and a non-biodegradable polymer such as a polystyrene, polyurethane, polyethylene, polypropylene, or polycarbonate are treated: (1) under heat, pressure and reagents to break the polymers; and (2) by adding to them an oxidizing agent. This treatment forms and/or makes available reactive groups for bonding: (1) on the biodegradable material groups such as aldehyde or hydroxyl groups in the case of the carbohydrates and amine groups in the case of proteins and certain other compounds such as urea; and (2) on the non-biodegradable plastic groups such as aldehydes, methyl, propyl, ethyl, benzyl or hyroxyl groups. In one embodiment, plastic and starch are processed in an extruder by: (1) mixing a starch in a range of between 15 percent and 80 percent, an oxidizing agent and an agent to break up the starch and the plastics; and (2) subjecting the combination to sufficient heat and/or pressure to break the plastic into shorter chains and bond monosaccharides to monomers from the non-biodegradable polymer.
摘要翻译： 为了制备可生物降解的塑料，可以处理诸如淀粉和不可生物降解的聚合物如聚苯乙烯，聚氨酯，聚乙烯，聚丙烯或聚碳酸酯的可生物降解的材料：（1）在加热，压力和试剂下破坏聚合物; 和（2）向其中加入氧化剂。 该处理形成和/或提供用于结合的反应性基团：（1）在蛋白质和某些其它化合物如尿素的情况下，在碳水化合物和胺基团的情况下，可生物降解材料基团如醛或羟基; 和（2）在不可生物降解的塑料基团如醛，甲基，丙基，乙基，苄基或羟基上。 在一个实施方案中，塑料和淀粉通过以下方法在挤出机中加工：（1）混合15％至80％范围内的淀粉，一种氧化剂和一种用于分解淀粉和塑料的试剂; 和（2）使组合物具有足够的热和/或压力以将塑料破坏成更短的链，并将单糖与来自不可生物降解的聚合物的单体结合。
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2.发明授权
公开(公告)号：US5665152A
公开(公告)日：1997-09-09
申请号：US745106
申请日：1996-11-07
IPC分类号： C08J5/00 , B29C45/00 , B29C67/24 , C08L1/02 , C08L3/02 , C08L89/00 , C08L97/02 , C09D189/00 , C09D103/02
CPC分类号： C08L3/02 , B29C45/0001 , B29C67/24 , C08L89/00 , B29K2003/00 , B29K2089/00 , B29K2995/0059 , C08L1/02 , C08L2201/06 , C08L97/02
摘要： A method of forming solid, non-edible biodegradable, grain protein-based articles is provided wherein a grain protein formulation is heated to a maximum temperature of up to about 80.degree. C. to create a substantially homogeneous and flowable mixture which can be formed into biodegradable articles. The formulation includes from about 20-85% by weight of grain protein, from about 5-75% by weight starch, up to about 14% by weight water, from about 10-40% by weight plasticizer, and at least about 0.01 by weight of a reducing agent such as sodium bisulfite for cleaving disulfide bonds present in the grain protein. Optional ingredients such as fillers, fiber, lubricant/mold release agents and colorants can also be used. The formulations can be processed in extrusion or injection molding equipment to create solid articles.
摘要翻译： 提供了一种形成固体，不可食用的可生物降解的谷物蛋白质制品的方法，其中将谷物蛋白质制剂加热至最高约80℃的最高温度以产生基本上均匀且可流动的混合物，其可形成 可生物降解物品。 该制剂包括约20-85重量％的谷物蛋白质，约5-75重量％的淀粉，至多约14重量％的水，约10-40重量％的增塑剂和至少约0.01个 重量的还原剂如亚硫酸氢钠，用于切割存在于谷物蛋白质中的二硫键。 还可以使用任选的成分，例如填料，纤维，润滑剂/脱模剂和着色剂。 制剂可以在挤出或注塑设备中加工以制备固体制品。
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公开(公告)号：US07534459B2
公开(公告)日：2009-05-19
申请号：US10284552
申请日：2002-10-30
IPC分类号： A23J1/00
CPC分类号： A23J3/00
摘要： Hydrothermal processes are provided for preparing hybrid proteins containing altered SS/SH bonds, thereby yielding hybrid proteins having enhanced functional properties. The processes involve steam treatment of an aqueous protein-containing slurry containing at least two different proteins in a jet cooker (16) or similar device in order to heat shock and thereby alter the conformation of some of the proteins, followed by relatively rapid cooling to cause formation of the desired hybrids. Plant and animal proteins may be processed, and the starting slurry can be pH-modified and/or supplemented with one or more additional ingredients (e.g., salts, phosphates, fatty acids, polysaccharides, alcohols, aromatic compounds). The hybrid proteins are useful as food ingredients (e.g., solubility, wetability, dispersibility, foaming, emulsification, viscosity, gelation or thickening agents).
摘要翻译： 提供水热法用于制备含有改变的SS / SH键的杂交蛋白，从而产生具有增强的功能特性的杂交蛋白。 该方法包括在喷射蒸煮器（16）或类似装置中蒸汽处理含有至少两种不同蛋白质的含水蛋白质浆液，以便热休克，从而改变一些蛋白质的构象，然后相对快速冷却至 导致所需杂交体的形成。 可以处理植物和动物蛋白质，并且起始浆液可以用一种或多种另外的成分（例如盐，磷酸盐，脂肪酸，多糖，醇，芳族化合物）进行pH修饰和/或补充。 杂交蛋白质可用作食品成分（例如溶解性，润湿性，分散性，发泡性，乳化性，粘度，凝胶化或增稠剂）。
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公开(公告)号：US06749842B2
公开(公告)日：2004-06-15
申请号：US10057215
申请日：2002-01-24
申请人： Jeremy T. Miller , Clodualdo C. Maningat , Sukh Bassi , Dharmen Makwana , Rangaswamy Chinnaswamy
发明人： Jeremy T. Miller , Clodualdo C. Maningat , Sukh Bassi , Dharmen Makwana , Rangaswamy Chinnaswamy
IPC分类号： A61K7075
摘要： Improved liquid foamer products, methods of preparation thereof, and end-use personal care products including the foamers are provided wherein the liquid foamers comprise a quantity of aqueous liquid hydrolyzed grain protein (e.g., aqueous liquid hydrolyzed wheat gluten protein) with an amount up to about 10% by weight of initially solid hydrolyzed grain protein (e.g., hydrolyzed wheat gluten protein powder) solubilized in the liquid ingredient. The foamer products have good foaming and color characteristics, and can be readily incorporated into a variety of personal care product formulations.
摘要翻译： 提供了改进的液体起泡剂产品，其制备方法和包括起泡剂的最终用途的个人护理产品，其中液体起泡剂包含一定量的水性液体水解谷物蛋白（例如，水性液体水解的小麦面筋蛋白） 约10重量％溶解在液体成分中的初始固体水解谷蛋白（例如，水解小麦谷蛋白粉）。 起泡剂产品具有良好的起泡和着色特性，并且可以容易地并入各种个人护理产品配方中。
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公开(公告)号：US5965708A
公开(公告)日：1999-10-12
申请号：US814219
申请日：1997-03-11
申请人： Sukh Bassi , Clodualdo C. Maningat , Rangaswamy Chinnaswamy , Li Nie , Michael K. Weibel , John J. Watson
发明人： Sukh Bassi , Clodualdo C. Maningat , Rangaswamy Chinnaswamy , Li Nie , Michael K. Weibel , John J. Watson
摘要： Gluten protein-based biodegradable or edible films are produced using aqueous, essentially alcohol-free casting dispersions containing modified protein (preferably wheat gluten protein) and a plasticizer. The modified protein is prepared by treating purified naturally occurring wheat protein with a reducing agent (e.g., sodium metabisulfite) in order to reduce the average molecular weight of the wheat protein and to cleave disulfide bonds therein. Such modified wheat gluten protein lowers the viscosity and allows increased solid contents in the casting dispersions, allowing fabrication of improved films using continuous casting techniques and without use of organic solvents.
摘要翻译： 使用含有改性蛋白质（优选小麦面筋蛋白质）和增塑剂的水性基本上无醇的浇铸分散体来生产基于蛋白质的可生物降解或可食用的薄膜。 通过用还原剂（例如偏亚硫酸氢钠）处理纯化的天然存在的小麦蛋白来制备修饰的蛋白质，以便降低小麦蛋白质的平均分子量并在其中切割二硫键。 这种改性的小麦谷蛋白降低了粘度，并且允许在铸塑分散体中增加固体含量，允许使用连续铸造技术制造改进的膜并且不使用有机溶剂。
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公开(公告)号：US5977312A
公开(公告)日：1999-11-02
申请号：US962151
申请日：1997-10-31
摘要： Wheat gluten protein-based biodegradable or edible films are produced using aqueous, essentially alcohol-free casting dispersions containing modified wheat protein and a plasticizer. The modified wheat protein is prepared by treating purified naturally occurring wheat protein with a reducing agent (e.g., sodium metabisulfite) in order to reduce the average molecular weight of the wheat protein and to cleave disulfide bonds therein. Such modified wheat gluten protein lowers the viscosity and allows increased solid contents in the casting dispersions, allowing fabrication of improved films.
摘要翻译： 使用含有改性小麦蛋白质和增塑剂的水性基本上无醇的浇铸分散体来生产小麦面筋蛋白质的可生物降解或可食用的薄膜。 通过用还原剂（例如偏亚硫酸氢钠）处理纯化的天然存在的小麦蛋白质来制备修饰的小麦蛋白质，以便降低小麦蛋白质的平均分子量并在其中切割二硫键。 这种改性小麦谷蛋白降低了粘度，并允许在铸塑分散体中增加固体含量，从而制备改进的膜。
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公开(公告)号：US5747648A
公开(公告)日：1998-05-05
申请号：US614373
申请日：1996-03-12
摘要： Wheat gluten protein-based biodegradable or edible films are produced using aqueous, essentially alcohol-free casting dispersions containing modified wheat protein and a plasticizer. The modified wheat protein is prepared by treating purified naturally occurring wheat protein with a reducing agent (e.g., sodium metabisulfite) in order to reduce the average molecular weight of the wheat protein and to cleave disulfide bonds therein. Such modified wheat gluten protein lowers the viscosity and allows increased solid contents in the casting dispersions, allowing fabrication of improved films.
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8.发明授权
公开(公告)号：US5610277A
公开(公告)日：1997-03-11
申请号：US526078
申请日：1995-09-11
IPC分类号： C07K1/30 , C07K14/415 , C07K2/00
CPC分类号： C07K14/415
摘要： An improved alcohol-free method for fractionating gluten into gliadin and glutenin fractions is provided where an acidic dispersion of gluten is formed with a reducing agent (e.g., sodium metabisulfite) operable for breaking disulfide bonds in the gluten protein. Thereafter, the pH of the dispersion is raised to cause glutenin to precipitate while leaving gliadin suspended in the dispersion. The respective fractions can then be separated by decanting or centrifugation. In preferred processing, the dispersion is reacidified prior to separation in order to achieve a higher degree of separation of the glutenin and gliadin.
摘要翻译： 提供了一种用于将谷蛋白分级成麦醇溶蛋白和谷蛋白级分的改进的无酒精方法，其中用可破坏谷蛋白中的二硫键的还原剂（例如偏亚硫酸氢钠）形成麸质的酸性分散体。 此后，分散液的pH升高，使麦谷蛋白沉淀，同时留下悬浮在分散体中的麦醇溶蛋白。 然后可以通过倾析或离心分离各个级分。 在优选的处理中，在分离之前将分散体再酸化以达到更高程度的谷蛋白和麦醇溶蛋白的分离。
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