摘要:
An improved method for the selective vapor phase oxidation of acrolein to acrylic acid in a recirculating solids reactor system using a particulate molybdenum vanadate multimetal oxide as oxidant involving specific reactant concentrations (preferably 5 mol % to 30 mol % propylene, 0 to 20 mol % oxygen, 0 to 70 mol % water, and the remainder inert gas), solids particle size (20 to 300 micrometers), temperature (250 to 450° C.) and gas (1 to 15 seconds) and solids (2 to 60 seconds) residence times. Such a process leads to improved selectivity, conversion and solids conversion ratio.
摘要:
An improved method for the selective vapor phase oxidation of propylene to acrolein in a recirculating solids reactor system using a bismuth molybdate multimetal oxide involving specific reactant concentrations (preferably 5 mol % to 30 mol % propylene, 0 to 20 mol % oxygen, and the remainder inert gas), particle size (1 to 300 micrometers), temperature (250 to 450° C.) and gas (1 to 15 seconds) and solids (2 to 60 seconds) residence times. Such a process leads to improved selectivity and propylene conversion.
摘要:
Process is disclosed which is suitable for high speed production of uniform, lightweight webs by air-laydown of textile fibers. A toothed disperser roll doffs the fibers into an air stream of high uniform velocity and low turbulence to form a thin fiber layer from which the fibers are deposited in web form on a moving screen. A curved disperser plate, shrouds a portion of the disperser roll up to the point of fiber doffing. By using a disperser plate with a rough surface, preferably one having lateral grooves, web uniformity is remarkably improved.
摘要:
A method for manufacturing of an improved attrition resistant catalyst having an oxide-rich surface layer involving forming a slurry comprising; catalyst, catalyst precursor or catalyst support particles (e.g., transition metal oxides), a colloidal oxide sol (e.g., colloidal silica), and a solution of a solvent and solute wherein the solute consist essentially of a precursor of said oxide-rich surface with particle size no greater than 5 nm (e.g., aqueous silicic acid or polysilicic acid) and then spray drying the slurry to form porous microspheres of attrition resistant catalyst; and, calcining the spray dried microspheres. Such a catalyst is particularly useful in oxidation processes wherein the oxidation is performed by an oxidized form of the catalyst and the resulting reduced form of the catalyst is separately regenerated (e.g., two-step vapor phase processes carried out in recirculating solids reactors, transport bed reactors or circulating fluidized bed reactors and the like).
摘要:
The tensile strength of apertured nonwoven fabric can be increased by a change in the two-stage process of impinging fine columnar streams of liquid, first onto one face of a fibrous web and then onto the opposite face thereof, the change being that the asymmetrical woven wire screen on which the web is positioned during the second stage of the process is oriented with the wire forming the higher knuckle in the screen running in the direction of passage of the web beneath the fine columnar streams, with the area weight of the web being from 0.5 to 2.0 oz/yd.sup.2.
摘要:
An improved process for calcination and activation of a catalyst containing mixed oxides of vanadium and phosphorus (V/P/O) involving the addition of spray dried catalyst precursor to a fluidizing oxygen containing gas at a controlled rate such that the temperature is maintained at a range of 370 to 410.degree. C. (preferably 390.+-.5.degree. C.). The catalyst precursor experiences, in addition to rapid temperature rise, dehydration/calcination at this elevated temperature in the fluidized state for an average range of residence time of less than about 4 hours at 3.5 atm of air or above, and up to 20 hours at 1 atm of air while simultaneously and continuously maintaining an average V.sub.ox of 4.55 or less. Such a process is useful in preparing a V/P/O catalyst that exhibits enhanced activity for the oxidation of n-butane to maleic anhydride. The novel process also provides an improved method for start-up of a commercial scale recirculating solids reactor.
摘要翻译:一种用于煅烧和活化含有钒和磷的混合氧化物(V / P / O)的催化剂的改进方法,其涉及将喷雾干燥的催化剂前体以受控的速率加入到含流化气体的气体中,使得温度保持在 范围为370至410℃(优选390 +/- 5℃)。 除了快速升温之外,催化剂前体还经历在流化状态下的这个升高温度下的脱水/煅烧,在3.5atm空气或以上的平均停留时间范围小于约4小时,并且在高达20小时 1atm的空气,同时且连续地维持4.55或更低的平均Vox。 这种方法可用于制备对正丁烷氧化成马来酸酐具有增强的活性的V / P / O催化剂。 该新方法还提供了一种用于启动商业规模循环固体反应器的改进方法。
摘要:
A compressed batt of fibers is fed against a rotating toothed roll for dispersion of the fibers from the batt and this dispersion of fibers is fed through the point of closest clearance between the toothed roll and a feed roll rotating in the opposite direction. Downstream of this point of closest clearance, a stationary shoe is provided spaced from the surface of the toothed roll to permit the dispersion of fibers to follow the surface of the toothed roll. The shoe is closely fitted to the surface of the feed roll which has the effect of forming a pinch point where the feed roll enters beneath the shoe. In accordance with the invention, the shoe is equipped with passages for the flow of air to exit at the pinch point to prevent fibers from entering the pinch point, i.e., between the feed roll and shoe.
摘要:
The tensile strength of nonwoven fabric made by traversing a fibrous web on an apertured support with fine columnar streams of liquid is increased when the fine columnar streams are divided up into an array of a plurality of rows of streams, instead of a single row, with the streams in each row being staggered from one another and the rows being spaced 10 to 80 mils apart.
摘要:
A staple fiber batt of improved uniformity is made by the fibers falling onto a moving conveyor, skimming off the top of the batt by jets of air flowing across the top of the batt, which thereby determines the level of the batt, and redepositing the skimmed off fibers onto said batt. The batt can then be compacted for further processing.