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公开(公告)号：US4581302A
公开(公告)日：1986-04-08
申请号：US307123
申请日：1981-09-30
CPC分类号： H01M8/0295 , H01M2/1646 , H01M8/142 , H01M2008/147 , H01M2300/0048 , H01M2300/0051 , Y02E60/526
摘要： A matrix material for a molten carbonate fuel cell is described which is flexible, pliable and has rubber-like compliance at room temperature. The matrix has three components comprising fine inert particulate material, larger crack attenuating ceramic particulate material, and an organic polymeric binder. A process of assembling a molten carbonate fuel cell utilizing the compliant matrix material is also described. The compliant matrix material is inserted into a molten carbonate fuel cell stack utilizing fuel cell anodes with sufficient porosity to contain excess electrolyte. The fuel cell is heated up to a temperature sufficient to remove the polymer binder and cause a portion of the electrolyte material present in the anode to wick into the matrix to substantially fill it completely.
摘要翻译： 描述了一种熔融碳酸盐燃料电池的基质材料，其在室温下是柔性的，柔韧的并且具有类似橡胶的柔顺性。 该基体具有包括细惰性颗粒材料，较大的裂纹衰减陶瓷颗粒材料和有机聚合物粘合剂的三个组分。 还描述了利用顺应性基质材料组装熔融碳酸盐燃料电池的方法。 使用具有足够孔隙率的燃料电池阳极以容纳过量电解质将顺应性基质材料插入熔融碳酸盐燃料电池堆中。 将燃料电池加热到足以除去聚合物粘合剂的温度，并使阳极中存在的电解质材料的一部分吸入基质中以基本上完全填充它。
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公开(公告)号：US4538348A
公开(公告)日：1985-09-03
申请号：US549020
申请日：1983-11-07
CPC分类号： H01M8/0295 , H01M2/1646 , H01M8/142 , H01M2008/147 , H01M2300/0048 , H01M2300/0051 , Y02E60/526 , Y10T29/49108
摘要： A matrix material for a molten carbonate fuel cell is described which is flexible, pliable and has rubber-like compliance at room temperature. The matrix has three components comprising fine inert particulate material, larger crack attenuating ceramic particulate material, and an organic polymeric binder. A process of assembling a molten carbonate fuel cell utilizing the compliant matrix material is also described. The compliant matrix material is inserted into a molten carbonate fuel cell stack utilizing fuel cell anodes with sufficient porosity to contain excess electrolyte. The fuel cell is heated up to a temperature sufficient to remove the polymer binder and cause a portion of the electrolyte material present in the anode to wick into the matrix to substantially fill it completely.
摘要翻译： 描述了一种熔融碳酸盐燃料电池的基质材料，其在室温下是柔性的，柔韧的并且具有类似橡胶的柔顺性。 该基体具有包括细惰性颗粒材料，较大的裂纹衰减陶瓷颗粒材料和有机聚合物粘合剂的三个组分。 还描述了利用顺应性基质材料组装熔融碳酸盐燃料电池的方法。 使用具有足够孔隙率的燃料电池阳极以容纳过量电解质将顺应性基质材料插入熔融碳酸盐燃料电池堆中。 将燃料电池加热到足以除去聚合物粘合剂的温度，并使阳极中存在的电解质材料的一部分吸入基质中以基本上完全填充它。
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公开(公告)号：US4317865A
公开(公告)日：1982-03-02
申请号：US189886
申请日：1980-09-24
CPC分类号： H01M8/0295
摘要： A molten carbonate fuel cell electrolyte-matrix material and a molten carbonate fuel cell including such material are described. The electrolyte-matrix material comprises carbonate electrolytes in intimate combination with ceria matrix material. The electrolyte-matrix material shows substantially no phase change or reaction with the electrolyte after at least 2000 hours under molten carbonate fuel cell operating conditions.
摘要翻译： 描述了一种熔融碳酸盐燃料电池电解质基质材料和包括这种材料的熔融碳酸盐燃料电池。 电解质基体材料包括与二氧化铈基体材料紧密结合的碳酸盐电解质。 电解质基质材料在熔融碳酸盐燃料电池工作条件下至少在2000小时后基本上表现出与电解质的相变或反应。
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公开(公告)号：US5330727A
公开(公告)日：1994-07-19
申请号：US995845
申请日：1992-12-23
CPC分类号： C01B3/583 , B01D53/864 , B01D53/8696 , C10K3/04 , H01M8/0662 , C01B2203/044 , C01B2203/047
摘要： The concentration of carbon monoxide in a gaseous medium is reduced by selective catalytic oxidation in the presence of gaseous oxygen by passing the gaseous medium through a catalyst capable of oxidizing carbon monoxide in an exothermic reaction at temperatures within a given temperature range and by controlling the temperatures encountered in the catalyst in such a manner that the exothermic reaction takes place first above a threshold temperature below which the catalyst would be rapidly inactivated at the relatively high carbon monoxide concentrations present in the gaseous medium as it enters the catalyst, and subsequently, after the carbon monoxide concentration has been reduced to an acceptable level, at less than the threshold temperature to further reduce the carbon monoxide concentration to a desired minimum level below that achievable at temperatures above the threshold temperature.
摘要翻译： 气态介质中一氧化碳的浓度通过气态介质存在下的选择性催化氧化而降低，气态介质通过能够在给定温度范围内的温度下在放热反应中氧化一氧化碳的催化剂，并通过控制温度 在催化剂中遇到，使得放热反应首先发生在高于阈值温度的阈值温度以下，在气体介质进入催化剂之前，催化剂将在气态介质中存在的相对较高的一氧化碳浓度下迅速失活，随后，在 一氧化碳浓度已经降低到可接受的水平，低于阈值温度，以进一步将一氧化碳浓度降低到低于在高于阈值温度的温度下可实现的最低水平。
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公开(公告)号：US06187466B1
公开(公告)日：2001-02-13
申请号：US09121756
申请日：1998-07-23
IPC分类号： H01M200
CPC分类号： H01M8/0234 , H01M8/0247 , H01M8/0263 , H01M8/0267 , H01M8/0271 , H01M8/04074 , H01M8/04119 , H01M8/2483
摘要： A fuel cell (10), having a proton exchange membrane (48), an anode and a cathode, and cathode and anode water transport plates (12, 16), includes a water capillary edge seal to optimize and greatly improve fuel cell operation without the need for additional seals or impregnation of the water transport plates. The water filled porous bodies of the water transport plates (12, 16) use the capillary forces of the water, which is a product of the electrochemical reaction of the fuel cell (10) and the preferred coolant, to prevent gas intrusion into the water system and over board leakage of the gases as well as the resultant hazardous mixture of gaseous fuel and oxidizing gas.
摘要翻译： 具有质子交换膜（48），阳极和阴极以及阴极和阳极水输送板（12,16）的燃料电池（10）包括水毛细管边缘密封，以优化并大大改善燃料电池操作而没有 需要额外的密封或浸渍水输送板。 水输送板（12,16）的充水多孔体使用作为燃料电池（10）和优选冷却剂的电化学反应的产物的水的毛细管力，以防止气体侵入水中 系统和板上的气体泄漏以及所产生的气体燃料和氧化气体的有害混合物。
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6.发明授权
公开(公告)号：US6010675A
公开(公告)日：2000-01-04
申请号：US853663
申请日：1992-03-19
CPC分类号： C01B3/583 , B01D53/864 , B01D53/8696 , C10K3/04 , H01M8/0662 , C01B2203/044 , C01B2203/047
摘要： The concentration of carbon monoxide in a gaseous medium is reduced by selective catalytic oxidation in the presence of gaseous oxygen by passing the gaseous medium through a catalyst capable of oxidizing carbon monoxide in an exothermic reaction at temperatures within a given temperature range and by controlling the temperatures encountered in the catalyst in such a manner that the exothermic reaction takes place first above a threshold temperature below which the catalyst would be rapidly inactivated at the relatively high carbon monoxide concentrations present in the gaseous medium as it enters the catalyst, and subsequently, after the carbon monoxide concentration has been reduced to an acceptable level, at less than the threshold temperature to further reduce the carbon monoxide concentration to a desired minimum level below that achievable at temperatures above the threshold temperature.
摘要翻译： 气态介质中一氧化碳的浓度通过气态介质存在下的选择性催化氧化而降低，气态介质通过能够在给定温度范围内的温度下在放热反应中氧化一氧化碳的催化剂，并通过控制温度 在催化剂中遇到，使得放热反应首先发生在高于阈值温度的阈值温度以下，在气体介质进入催化剂之前，催化剂将在气态介质中存在的相对较高的一氧化碳浓度下迅速失活，随后，在 一氧化碳浓度已经降低到可接受的水平，低于阈值温度，以进一步将一氧化碳浓度降低到低于在高于阈值温度的温度下可实现的最低水平。
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公开(公告)号：US5009968A
公开(公告)日：1991-04-23
申请号：US405251
申请日：1989-09-08
申请人： Robin J. Guthrie , Murray Katz , Craig R. Schroll
发明人： Robin J. Guthrie , Murray Katz , Craig R. Schroll
CPC分类号： H01M8/0247 , H01M8/0267 , H01M8/04007 , H01M8/247 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The end plates (16) of a fuel cell stack (12) are formed of a thin membrane. Pressure plates (20) exert compressive load through insulation layers (22, 26) to the membrane. Electrical contact between the end plates (16) and electrodes (50, 58) is maintained without deleterious making and breaking of electrical contacts during thermal transients. The thin end plate (16) under compressive load will not distort with a temperature difference across its thickness. Pressure plate (20) experiences a low thermal transient because it is insulated from the cell. The impact on the end plate of any slight deflection created in the pressure plate by temperature difference is minimized by the resilient pressure pad, in the form of insulation, therebetween.
摘要翻译： 燃料电池堆（12）的端板（16）由薄膜形成。 压板（20）通过绝缘层（22,26）向膜施加压缩载荷。 保持端板（16）和电极（50,58）之间的电接触，而不会在热瞬变期间有害地制造和断开电触点。 压缩载荷下的薄端板（16）不会随其厚度的温差而变形。 压板（20）由于与电池绝缘而经历低热瞬变。 通过温度差在压力板上产生的任何轻微挠曲对端板的冲击由其间的绝缘形式的弹性压力垫最小化。
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公开(公告)号：US4548874A
公开(公告)日：1985-10-22
申请号：US676340
申请日：1984-11-29
申请人： Murray Katz , Craig R. Schroll
发明人： Murray Katz , Craig R. Schroll
CPC分类号： H01M8/2485 , C25B15/06
摘要： Electrical short protection is provided in an electrolytic cell stack by the combination of a thin, nonporous ceramic shield and a noble metal foil disposed on opposite sides of the sealing medium in a gas manifold gasket. The thin ceramic shield, such as alumina, is placed between the porous gasket and the cell stack face at the margins of the negative end plate to the most negative cells to impede ion current flow. The noble metal foil, for instance gold, is electrically coupled to the negative potential of the stack to collect positive ions at a harmless location away from the stack face. Consequently, corrosion products from the stack structure deposit on the foil rather than on the stack face to eliminate electrical shorting of cells at the negative end of the stack.
摘要翻译： 通过薄的无孔陶瓷屏蔽和设置在气体歧管垫圈中的密封介质的相对侧上的贵金属箔的组合，在电解池堆叠中提供电短路保护。 诸如氧化铝的薄陶瓷屏蔽物被放置在多孔垫片和负极板边缘之间的电池堆表面到最负电池以阻止离子电流流动。 贵金属箔，例如金，电耦合到堆叠的负电位，以在远离堆叠面的无害位置处收集正离子。 因此，来自堆叠结构的腐蚀产物沉积在箔上而不是在堆叠面上，以消除在堆叠的负端的电池的电短路。
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9.发明授权Manifold dielectric barrier for a fuel cell electrical power generation system 失效用于燃料电池发电系统的歧管介质阻挡层
公开(公告)号：US4467018A
公开(公告)日：1984-08-21
申请号：US288913
申请日：1981-07-31
申请人： Craig R. Schroll
发明人： Craig R. Schroll
CPC分类号： H01M8/244 , H01M8/2485 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y10T29/4911
摘要： A manifold dielectric barrier for use in a power section of a fuel cell electrical power generation system. The power section comprises a fuel cell stack and two external reactant manifolds for respectively conveying oxygen-rich gas and fuel into the fuel cell stack. The power section also includes discharge manifolds for conveying spent products away from the fuel cell stack. The manifold dielectric barrier dielectrically isolates the fuel cell stack from each of the manifolds. The manifold dielectric barrier includes an impermeable ceramic member, a first ceramic gasket intermediate of and contiguous with the ceramic member and the fuel cell stack, and a second ceramic gasket intermediate of and contiguous with the ceramic member and each of the manifolds.
摘要翻译： 一种用于燃料电池发电系统的功率部分的歧管介电阻挡层。 功率部分包括燃料电池堆和两个外部反应物歧管，用于分别将富氧气体和燃料输送到燃料电池堆中。 功率部分还包括用于将废弃产品输送离开燃料电池堆的排放歧管。 歧管介电屏障介电隔离燃料电池堆和每个歧管。 歧管介质阻挡层包括不可渗透的陶瓷构件，陶瓷构件和燃料电池堆中间并与陶瓷构件和燃料电池堆相邻的第一陶瓷衬垫，以及与陶瓷构件和每个歧管相连接的第二陶瓷衬垫。
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公开(公告)号：US4322482A
公开(公告)日：1982-03-30
申请号：US158019
申请日：1980-06-09
CPC分类号： H01M8/0295 , H01M8/145 , Y02E60/526
摘要： Thru-cracks in the electrolyte retaining matrix of a molten carbonate fuel cell caused by thermal cycling of the cell between operating and room temperature are prevented by an improved matrix comprising a major proportion of submicron support particles and a minor proportion, perhaps only a few percent, of much larger crack attenuator particles. In one embodiment wherein the electrolyte is to be a binary lithium-potassium carbonates composition, the matrix comprises 90 volume percent submicron lithium aluminate support particles and 10 volume percent alumina crack attenuator particles with an average size of 100 microns.
摘要翻译： 通过在操作和室温之间的电池的热循环引起的熔融碳酸盐燃料电池的电解质保留基质中的裂纹通过包含主要比例的亚微米载体颗粒和较小比例的改进的基体来防止，可能只有少数百分比 ，更大的裂纹衰减剂颗粒。 在电解质为二元碳酸锂 - 碳酸钾组合物的一个实施方案中，基质包含90体积百分比的亚微米铝酸锂载体颗粒和10体积％的平均粒径为100微米的氧化铝裂解衰减剂颗粒。
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