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1.发明授权Integrated hydroprocessing scheme for production of premium quality distillates and lubricants 失效一体化加氢处理方案，用于生产优质馏出物和润滑油
公开(公告)号：US4764266A
公开(公告)日：1988-08-16
申请号：US19983
申请日：1987-02-26
摘要： An integrated refining scheme for hydroprocessing high boiling fractions such as gas oil and catalytically cracked cycle oils to produce premium quality distillates, especially jet fuels and naphthas suitable for reforming into high octane gasoline. In addition, unconverted, high boiling fractions suitable for processing by conventional refining techniques into high quality, low pour point lube base stocks are obtained. The integrated hydroprocessing comprises a first stage hydrocracking step employing an aromatic selective hydrocracking catalyst based on a large pore size acidic component such as amorphous alumina or silica alumina or a large pore size zeolite such as zeolite X or zeolite Y. The hydrocracking may be operated either in a naphtha directing mode under conditions of moderate to high severity or under conditions of low to moderate severity to produce a relatively higher proportion of product boiling in the middle distillate range. The unconverted fraction from the hydrocracking step is passed to a second step in which it is hydroprocessed over a zeolite beta catalyst with additional hydrogenation-dehydrogenation functionality. In this stage, the paraffins remaining in the feed are attacked by the zeolite beta to form isoparaffins and conditions may be controlled to favor hydroisomerization over hydrocracking so as to increase the yield of middle distillate product, especially of high isoparaffinic jet fuels and diesel fuel.
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2.发明授权Hydrotreating/isomerization process to produce low pour point distillate fuels and lubricating oil stocks 失效加氢处理/异构化工艺生产低倾点馏出燃料和润滑油库存
公开(公告)号：US4518485A
公开(公告)日：1985-05-21
申请号：US557696
申请日：1983-12-02
摘要： A process for dewaxing a hydrocarbon feedstock with a relatively high pour point and containing paraffins selected from the group of normal paraffins and slightly branched paraffins and sulfur and nitrogen compounds which comprises subjecting said oil to hydrotreating in a hydrotreating zone operated at hydrotreating conditions sufficient to remove at least a portion of said sulfur and nitrogen compounds and subjecting said hydrotreated oil to catalytic dewaxing by contacting said oil with a catalyst comprising zeolite beta having a silica/alumina ratio of at least 30:1 and a hydrogenation/dehydrogenation component under isomerization conditions.
摘要翻译： 一种使具有较高倾点的烃原料脱蜡并含有选自正构烷烃和轻支化链烷烃和硫和氮化合物的链烷烃的方法，其包括使所述油在加氢处理区中加氢处理，所述加氢处理区在加氢处理条件下操作，所述加氢处理条件足以除去 所述硫和氮化合物的至少一部分，并使所述加氢处理的油通过使所述油与二氧化硅/氧化铝比为至少30:1的沸石β和在异构化条件下的氢化/脱氢组分接触的催化剂进行催化脱蜡。
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3.发明授权Integrated hydroprocessing scheme for production of premium quality distillates and lubricants 失效一体化加氢处理方案，用于生产优质馏出物和润滑剂
公开(公告)号：US4851109A
公开(公告)日：1989-07-25
申请号：US192072
申请日：1988-05-09
CPC分类号： C10G65/12 , C10G2300/1074 , C10G2400/02 , C10G2400/04 , C10G2400/08 , F02B3/06
摘要： An integrated refining scheme for hydroprocessing high boiling fractions such as gas oil and catalytically cracked cycle oils to produce premium quality distillates, especially jet fuels and naphthas suitable for reforming into high octane gasoline. In addition, unconverted, high boiling fractions suitable for processing by conventional refining techniques into high quality, low pour point lube base stocks are obtained. The integrated hydroprocessing comprises a first stage hydrocracking step employing an aromatic selective hydrocracking catalyst based on a large pore size acidic component such as amorphous alumina or silica alumina or a large pore size zeolite such as zeolite X or zeolite Y. The hydrocracking may be operated either in a naphtha directing mode under conditions of moderate to high severity or under conditions of low to moderate severity to produce a relatively higher proportion of product boiling in the middle distillate range. The unconverted fraction from the hydrocracking step is passed to a second step in which it is hydroprocessed over a zeolite beta catalyst with additional hydrogenation-dehydrogenation functionality. In this stage, the paraffins remaining in the feed are attacked by the zeolite beta to form isoparaffins and conditions may be controlled to favor hydroisomerization over hydrocracking so as to increase the yield of middle distillate product, especially of highly isoparaffinic jet fuels and diesel fuel.
摘要翻译： 一种用于加氢处理高沸点馏分（如瓦斯油和催化裂解循环油）的综合精炼方案，以生产优质馏出物，特别是适用于重整为高辛烷值汽油的喷气燃料和石脑油。 此外，获得了适用于通过常规精制技术加工成高质量低倾点润滑油基础油料的未转化的高沸点馏分。 一体化加氢处理包括使用基于大孔径酸性组分如无定形氧化铝或二氧化硅氧化铝或大孔径沸石如沸石X或沸石Y的芳族选择性加氢裂化催化剂的第一阶段加氢裂化步骤。加氢裂化可以 在中等至高严重度的条件下或在低至中等严重度的条件下以石脑油引导模式在中间馏分范围内产生相对较高比例的沸点产物。 来自加氢裂化步骤的未转化的级分被传递到第二步骤，其中其在具有另外的氢化 - 脱氢官能团的沸石β催化剂上进行加氢处理。 在这个阶段，剩余在饲料中的链烷烃被沸石β攻击以形成异链烷烃，并且可以控制条件以有利于加氢裂化加氢异构化，从而提高中间馏分产物，特别是高度异链烷烃喷气燃料和柴油燃料的产率。
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公开(公告)号：US4419220A
公开(公告)日：1983-12-06
申请号：US379422
申请日：1982-05-18
CPC分类号： C10G45/64 , C10G29/06 , Y10S208/02
摘要： Hydrocarbon feedstocks such as distillate fuel oils and gas oils are dewaxed by isomerizing the waxy components over a zeolite beta catalyst. The process may be carried out in the presence or absence of added hydrogen. Preferred catalysts have a zeolite silica:alumina ratio over 100:1.
摘要翻译： 诸如馏出燃料油和瓦斯油之类的烃原料通过在沸石β催化剂上使蜡状组分异构化来脱蜡。 该方法可以在存在或不加入氢气的情况下进行。 优选的催化剂具有100:1以上的沸石二氧化硅：氧化铝比。
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公开(公告)号：US5419830A
公开(公告)日：1995-05-30
申请号：US102675
申请日：1993-08-05
申请人： Tai-Sheng Chou , Nai Y. Chen , Grant G. Karsner , Clinton R. Kennedy , Rene B. LaPierre , Melcon G. Melconian , Richard J. Quann , Stephen S. Wong
发明人： Tai-Sheng Chou , Nai Y. Chen , Grant G. Karsner , Clinton R. Kennedy , Rene B. LaPierre , Melcon G. Melconian , Richard J. Quann , Stephen S. Wong
CPC分类号： C10G45/64 , C10G47/16 , C10G47/36 , Y10S208/01
摘要： Nitrogenous compounds especially bases such as ammonia vapor are used to control the operation of a hydrocracker or catalytic dewaxer. Catalyst activity and selectivity may be controlled by addition of the base to the feed, for example, to control the balance between isomerization and hydrocracking in an operation using a zeolite beta catalyst. Runaway conditions may be controlled by the addition of nitrogenous compounds to regulate the temperature profile within the reactor.
摘要翻译： 氮化合物尤其是碱例如氨蒸汽用于控制加氢裂化器或催化脱蜡机的运行。 催化剂活性和选择性可以通过向进料添加碱来控制，例如在使用沸石β催化剂的操作中控制异构化和加氢裂化之间的平衡。 失控条件可以通过加入含氮化合物来控制，以调节反应器内的温度分布。
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公开(公告)号：US4501926A
公开(公告)日：1985-02-26
申请号：US533017
申请日：1983-09-16
摘要： Hydrocarbon feedstocks such as distillate fuel oils and gas oils are dewaxed by isomerizing the waxy components over a zeolite beta catalyst. The process may be carried out in the presence or absence of added hydrogen. Preferred catalysts have a zeolite silica:alumina ratio over 100:1.
摘要翻译： 诸如馏出燃料油和瓦斯油之类的烃原料通过在沸石β催化剂上使蜡状组分异构化来脱蜡。 该方法可以在存在或不加入氢气的情况下进行。 优选的催化剂具有100:1以上的沸石二氧化硅：氧化铝比。
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公开(公告)号：US5110445A
公开(公告)日：1992-05-05
申请号：US545162
申请日：1990-06-28
申请人： Nai Y. Chen , Randall D. Partridge
发明人： Nai Y. Chen , Randall D. Partridge
IPC分类号： C10G67/04
CPC分类号： C10G67/0409 , C10G2400/10
摘要： Hydrocarbon lubricants having a high viscosity index (V.I.) and low pour point are produced by hydroisomerizing a waxy lube feed such as slack wax or a waxy gas oil over zeolite beta after which aromatic components are removed by extraction, e.g. with furfural. The raffinate is then dewaxed, preferably by solvent dewaxing to target pour point with a final hydrofinishing step. The hydroisomerization coupled with the aromatics extraction and dewaxing increases the range of crudes that can be processed into high V.I. lubes while maintaining equivalent product qualities. Hydrogen consumption in the process is relatively low.
摘要翻译： 具有高粘度指数（V.I.）和低倾点的烃类润滑剂通过将蜡状润滑油进料例如松散蜡或蜡状瓦斯油在沸石β上加氢异构化而生成，其后通过萃取除去芳族组分，例如， 与糠醛。 然后将脱蜡剂脱蜡，优选通过溶剂脱蜡至最终加氢精制步骤的目标倾点。 加氢异构化与芳烃萃取和脱蜡相结合，增加可加工成高V.I.的原油范围。 同时保持同等的产品质量。 过程中的氢消耗相对较低。
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公开(公告)号：US5037529A
公开(公告)日：1991-08-06
申请号：US459403
申请日：1989-12-29
IPC分类号： C10G59/02
CPC分类号： C10G59/02
摘要： High purity benzene and high octane alkylaromatic gasoline can be obtained via a dual stage reforming process utilizing a non-acidic Group VIII metal containing microporous crystalline silicate catalyst in the first stage followed by first stage effluent treatment over acidic zeolite catalyst operating under conditions in the second stage to upgrade the first stage effluent in RON, in aromatic content or both.
摘要翻译： 高纯度苯和高辛烷值的烷基芳烃汽油可以通过双阶段重整方法获得，该方法利用在第一阶段中使用含非极性Ⅷ族金属的微孔结晶硅酸盐催化剂，然后在第二阶段的条件下在酸性沸石催化剂上进行第一阶段流出物处理 在RON，芳香含量或两者都升级第一阶段流出物的阶段。
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公开(公告)号：US4944862A
公开(公告)日：1990-07-31
申请号：US262779
申请日：1988-10-26
摘要： Dewaxing, preferably catalytic dewaxing over zeolite beta or ZSM-5, improves the crackability of a heavy, waxy feed to a catalytic cracking unit. When the catalytic dewaxing occurs at temperatures above about 360.degree. C., using ZSM-5 dewaxing catalyst, high octane gasoline is obtained as a by product of catalytic dewaxing.
摘要翻译： 脱蜡，优选在沸石β或ZSM-5上进行催化脱蜡，改善重质蜡质进料到催化裂化装置的裂解性。 当催化脱蜡发生在高于约360℃的温度时，使用ZSM-5脱蜡催化剂，作为催化脱蜡的副产物获得高辛烷值汽油。
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公开(公告)号：US4500417A
公开(公告)日：1985-02-19
申请号：US453970
申请日：1982-12-28
申请人： Nai Y. Chen , Werner O. Haag , Tracy J. Huang , Stephen S. Wong
发明人： Nai Y. Chen , Werner O. Haag , Tracy J. Huang , Stephen S. Wong
IPC分类号： C10G45/64 , B01J29/00 , B01J29/74 , B01J29/78 , C07C1/00 , C07C1/04 , C07C9/00 , C07C67/00 , C10G47/16 , C10G49/08 , C10G47/20
CPC分类号： C10G47/16 , B01J2229/37 , B01J29/7415 , B01J29/7815 , Y10S208/95
摘要： The high boiling fraction of Fischer-Tropsch synthesis is upgraded by contact with a catalyst comprising a high-silica, large pore zeolite and a hydrogenation component. The products are a distillate fraction characterized by low sulfur and nitrogen content, high isoparaffin content and low pour point and a lube fraction characterized by its high viscosity index and low pour point.
摘要翻译： 通过与包含高二氧化硅，大孔沸石和氢化组分的催化剂接触来提高费 - 托合成的高沸点馏分。 该产品是以低硫和氮含量，高异链烷烃含量和低倾点为特征的馏出物部分，其特征在于其高粘度指数和低倾点。
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