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1.发明授权Treatment of polyarylene sulfide/sulfone polymers with zinc compound and acidic solution 失效用锌化合物和酸溶液处理聚亚烷基硫化物/磺化聚合物
公开(公告)号：US5235034A
公开(公告)日：1993-08-10
申请号：US696451
申请日：1991-05-06
申请人： Rex L. Bobsein , Michael C. Yu , Roy F. Wright , David A. Soules
发明人： Rex L. Bobsein , Michael C. Yu , Roy F. Wright , David A. Soules
摘要： Poly(arylene sulfide/sulfone) polymers are treated in order to increase melt stability and decrease impurities by contacting the poly(arylene sulfide/sulfone) polymer with a soluble zinc compound and an acidic solution. In one embodiment, the polymer is treated first with the soluble zinc compound, followed by treatment with the acidic solution. In another embodiment, the polymer is treated in one step with a solution comprising a water soluble zinc compound in an acidic solution.
摘要翻译： 处理聚（亚芳基硫醚/砜）聚合物以通过使聚（亚芳基硫醚/砜）聚合物与可溶性锌化合物和酸性溶液接触来提高熔体稳定性和降低杂质。 在一个实施方案中，首先用可溶性锌化合物处理聚合物，然后用酸性溶液处理。 在另一个实施方案中，聚合物在一个步骤中用在酸性溶液中的水溶性锌化合物的溶液处理。
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公开(公告)号：US5350834A
公开(公告)日：1994-09-27
申请号：US62641
申请日：1993-05-14
申请人： Rex L. Bobsein , Michael C. Yu , Roy F. Wright , David A. Soules
发明人： Rex L. Bobsein , Michael C. Yu , Roy F. Wright , David A. Soules
摘要： Poly(arylene sulfide/sulfone) polymers are treated in order to increase melt stability and decrease impurities by contacting the poly(arylene sulfide/sulfone) polymer with a soluble zinc compound and an acidic solution. In one embodiment, the polymer is treated first with the soluble zinc compound, followed by treatment with the acidic solution. In another embodiment, the polymer is treated in one step with a solution comprising a water soluble zinc compound in an acidic solution.
摘要翻译： 处理聚（亚芳基硫醚/砜）聚合物以通过使聚（亚芳基硫醚/砜）聚合物与可溶性锌化合物和酸性溶液接触来提高熔体稳定性和降低杂质。 在一个实施方案中，首先用可溶性锌化合物处理聚合物，然后用酸性溶液处理。 在另一个实施方案中，聚合物在一个步骤中用在酸性溶液中的水溶性锌化合物的溶液处理。
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公开(公告)号：US5075420A
公开(公告)日：1991-12-24
申请号：US640092
申请日：1991-01-11
CPC分类号： C08J3/096 , C08G75/0236 , C08G75/0281 , C08G75/20 , C08J3/14 , C08J2381/00
摘要： A phenylene sulfide/sulfone polymer with relatively good melt stability and a method of producing such a polymer are provided. A previously produced phenylene sulfide/sulfone polymer is redissolved in N-methyl-2-pyrrolidone to form a solution. This solution is combined with an alcohol to precipitate highly melt stable phenylene sulfide/sulfone polymer in a particulate form. The alcohol has one to four carbon atoms, such as methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and the like and mixtures thereof.
摘要翻译： 提供了具有较好熔融稳定性的亚苯基硫醚/砜聚合物和制备这种聚合物的方法。 将先前生产的苯硫醚/砜聚合物再溶解在N-甲基-2-吡咯烷酮中以形成溶液。 该溶液与醇结合以沉淀出高度熔融稳定的亚硫醚/砜聚合物的颗粒形式。 醇具有1-4个碳原子，例如甲醇，乙醇，1-丙醇，2-丙醇，1-丁醇，2-丁醇等及其混合物。
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公开(公告)号：US5039788A
公开(公告)日：1991-08-13
申请号：US502812
申请日：1990-04-02
CPC分类号： C08J3/096 , C08G75/0236 , C08G75/0281 , C08G75/20 , C08J3/14 , C08J2381/00
摘要： A phenylene sulfide/sulfone polymer with relatively good melt stability and a method of producing such a polymer are provided. A previously produced phenylene sulfide/sulfone polymer is redissolved in N-methyl-2-pyrrolidone to form a solution. This solution is combined with an alcohol to precipitate highly melt stable phenylene sulfide/sulfone polymer in a particulate form. The alcohol has one to four carbon atoms, such as methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and the like and mixtures thereof.
摘要翻译： 提供了具有较好熔融稳定性的亚苯基硫醚/砜聚合物和制备这种聚合物的方法。 将先前生产的苯硫醚/砜聚合物再溶解在N-甲基-2-吡咯烷酮中以形成溶液。 该溶液与醇结合以沉淀出高度熔融稳定的亚硫醚/砜聚合物的颗粒形式。 醇具有1-4个碳原子，例如甲醇，乙醇，1-丙醇，2-丙醇，1-丁醇，2-丁醇等及其混合物。
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公开(公告)号：US4663082A
公开(公告)日：1987-05-05
申请号：US808971
申请日：1985-12-16
摘要： A stable water-based industrial cleaning composition comprising water, an additive comprising a mixture of an alkyl polyoxyalkylene sulfide and an alkyl polyoxyalkylene sulfoxide and at least one builder selected from the group consisting of alkali metal and ammonium salts of ethylenediamine tetraacetic acid, alkali metal and ammonium pyrophosphates, alkali metal and ammonium metasilicates, alkali metal hydroxides, alkaline earth metal hydroxides and alkali metal borates is disclosed. In accordance with the invention, said alkyl polyoxyalkylene sulfide may be partially oxidized to its corresponding alkyl polyoxyalkylene sulfoxide to produce said additive.
摘要翻译： 一种稳定的基于水的工业清洁组合物，其包含水，包含烷基聚氧化烯硫化物和烷基聚氧化烯亚砜的混合物的添加剂和至少一种助洗剂，其选自乙二胺四乙酸的碱金属和铵盐，碱金属和 焦磷酸铵，偏硅酸铵，碱金属氢氧化物，碱土金属氢氧化物和碱金属硼酸盐。 根据本发明，所述烷基聚氧化烯硫化物可以部分氧化成其相应的烷基聚氧化烯亚砜，以产生所述添加剂。
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公开(公告)号：US5179193A
公开(公告)日：1993-01-12
申请号：US789554
申请日：1991-11-08
申请人： Rex L. Bobsein , Howard F. Efner
发明人： Rex L. Bobsein , Howard F. Efner
CPC分类号： C08G75/20 , C08G75/0236
摘要： Branched aromatic sulfide sulfone polymer is produced by contacting at least one dihalo aromatic sulfone, at least one polymerizable sulfur source other than lithium sulfide, at least one alkali metal carbonate, at least one organic amide, at least one alkali metal carboxylate, at least one polyhalodiarylsulfone having more than two halogen substituents and water including water of hydration under polymerization conditions for a period of time sufficient to form an aromatic sulfide sulfone polymer. The polymer exhibits higher melt and solution viscosity than obtained in the same process except without the use in the reaction mixture of polyhalodiarylsulfone having more than two halogen substituents and is useful in the production of coatings, films, molded objects, and fibers.
摘要翻译： 分支芳香硫醚砜聚合物是通过使至少一种二卤代芳族砜，至少一种不同于硫化锂的可聚合硫源，至少一种碱金属碳酸盐，至少一种有机酰胺，至少一种碱金属羧酸盐，至少一种 具有多于两个卤素取代基的多卤代二芳基砜和包含水合的水在聚合条件下持续足以形成芳族硫化物砜聚合物的时间。 聚合物显示出比在相同方法中获得的熔体和溶液粘度更高的熔融和溶液粘度，除非在具有多于两个卤素取代基的多卤二芳基砜的反应混合物中使用，并且可用于制备涂料，膜，模制物体和纤维。
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7.发明授权Method for the production of light colored aromatic sulfide/sulfone polymers with 1,3-dialkyl-2-imidazolidinone diluent 失效用1,3-二烷基-2-咪唑烷酮稀释剂制备浅色芳香族硫化物/砜聚合物的方法
公开(公告)号：US5066774A
公开(公告)日：1991-11-19
申请号：US587836
申请日：1990-09-25
申请人： Jon F. Geibel , Rex L. Bobsein , Harold D. Yelton
发明人： Jon F. Geibel , Rex L. Bobsein , Harold D. Yelton
CPC分类号： C08G75/0259 , C08G75/0236 , C08G75/20
摘要： This invention provides a process to produce aromatic sulfide/sulfone polymers exhibiting high molecular weight, and having a light or "whitish" coloration. This process employs a dihaloaromatic sulfone, a sulfur-containing compound and a 1,3-dialkyl-2-imidazolidinone. These lighter colored polymers are more preferable commercially and may be useful in the production of coatings, films, molded objects, and glass or carbon fiber composites.
摘要翻译： 本发明提供一种生产表现出高分子量，具有浅或“发白”着色的芳族硫化物/砜聚合物的方法。 该方法采用二卤代芳砜，含硫化合物和1,3-二烷基-2-咪唑啉酮。 这些较浅的聚合物在商业上是更优选的，并且可用于制备涂料，膜，模塑物体以及玻璃或碳纤维复合材料。
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公开(公告)号：US5057592A
公开(公告)日：1991-10-15
申请号：US652302
申请日：1991-02-06
申请人： Rex L. Bobsein
发明人： Rex L. Bobsein
CPC分类号： C08G75/23 , C08G75/0236 , C08G75/025
摘要： A two-step process to make a poly(arylene sulfide sulfone) polymer containing ether groups having high molecular weights is described. In the first step an aromatic diphenol, a dihaloaromatic sulfone, a polar organic compound and an alkali metal base are reacted at an elevated temperature for a time period in the range of 1 minute to 2 hours. A sulfur source is then added to form a poly(arylene sulfide sulfone) polymer containing ether groups. An alkali metal carboxylate is also present in the second step. The polymers prepared by the invention method exhibit higher inherent viscosities, indicating higher molecular weight.
摘要翻译： 描述了制备含有高分子量的醚基的聚（亚芳基硫醚砜）聚合物的两步法。 在第一步中，将芳族二酚，二卤代芳香砜，极性有机化合物和碱金属碱在升高的温度下反应1分钟至2小时的时间。 然后加入硫源以形成含有醚基的聚（亚芳基硫醚砜）聚合物。 碱金属羧酸盐也存在于第二步中。 通过本发明方法制备的聚合物表现出较高的固有粘度，表明分子量较高。
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9.发明授权Reinforced plastic comprising fibrous reinforcement treated with poly(arylene sulfide sulfone) polymer containing ether groups 失效包括用含有醚基团的聚（亚芳基硫醚砜）聚合物处理的纤维增强材料的增强塑料
公开(公告)号：US5045367A
公开(公告)日：1991-09-03
申请号：US486589
申请日：1990-02-28
申请人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner , Mark L. Stone
发明人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner , Mark L. Stone
IPC分类号： C08J5/06
CPC分类号： C08J5/06 , C08J2381/00 , Y10S428/902 , Y10T428/2933 , Y10T428/2938 , Y10T428/30 , Y10T442/2402
摘要： A reinforced plastic is provided which comprises a poly(arylene sulfide sulfone) polymer matrix and fibrous reinforcement. The fibrous reinforcement is treated with a poly(arylene sulfide sulfone) polymer containing ether groups prior to forming the reinforced plastic. Such treatment improves the mechanical strength of the reinforced plastic.
摘要翻译： 提供了一种增强塑料，其包括聚（亚芳基硫醚砜）聚合物基质和纤维增强物。 在形成增强塑料之前，用含有醚基的聚（亚芳基硫醚砜）聚合物处理纤维增强物。 这种处理改善了增强塑料的机械强度。
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公开(公告)号：US4615836A
公开(公告)日：1986-10-07
申请号：US611655
申请日：1984-05-18
申请人： Rex L. Bobsein
发明人： Rex L. Bobsein
IPC分类号： C08H3/00
CPC分类号： C07C323/00
摘要： A process for preparing an alkylmercapto ester by reacting an alkyl mercaptoalkanol with an organic carboxylic acid or an organic anhydride in the presence of a titanium-containing catalyst.
摘要翻译： 一种通过烷基巯基烷醇与有机羧酸或有机酸酐在含钛催化剂存在下反应来制备烷基巯基酯的方法。
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