摘要:
A direct antifreeze cooled fuel cell is disclosed for producing electrical energy from reducing and process oxidant fluid streams that includes an electrolyte secured between an anode catalyst and a cathode catalyst; a porous anode substrate secured in direct fluid communication with and supporting the anode catalyst; a porous wetproofed cathode substrate secured in direct fluid communication with and supporting the cathode catalyst; a porous water transport or cooler plate secured in direct fluid communication with the porous cathode substrate; and, a direct antifreeze solution passing through the porous water transport plate. A preferred direct antifreeze solution passing through the porous water transport plate remains essentially within the water transport plate and does not poison the catalysts.
摘要:
A direct antifreeze cooled fuel cell is disclosed for producing electrical energy from reducing and process oxidant fluid streams that includes an electrolyte secured between an anode catalyst and a cathode catalyst; a porous anode substrate secured in direct fluid communication with and supporting the anode catalyst; a porous wet proofed cathode substrate secured in direct fluid communication with and supporting the cathode catalyst; a porous water transport plate secured in direct fluid communication with the porous cathode substrate; and, a direct antifreeze solution passing through the porous water transport plate. In operation of the fuel cell, because product water generated electrochemically at the cathode catalyst flows away from the cathode catalyst into the cathode substrate and into the water transport plate and because the cathode substrate is wetproofed, the antifreeze solution passing through the water transport plate remains essentially within this plate. In a preferred embodiment, the antifreeze solution passing through the water transport plate may be directed to flow at a pressure less than that of the oxidant stream passing adjacent the cathode substrate.
摘要:
A fine pore enthalpy exchange barrier is disclosed for use with a fuel cell power plant. The barrier includes a support matrix that defines pores and a liquid transfer medium that fills the pores creating a gas barrier. An inlet surface of the fine pore enthalpy exchange barrier is positioned in contact with a process oxidant inlet stream entering a fuel cell power plant, and an opposed exhaust surface of the barrier is positioned in contact with an exhaust stream exiting the plant so that water and heat exchange from the exhaust stream directly into the process oxidant inlet stream to heat and humidify the stream as it enters the plant. The liquid transfer medium may include water, aqueous salt solutions, aqueous acid solutions, or organic antifreeze water solutions.
摘要:
A fuel cell power plant system includes the ability to operate an enthalpy recovery device even under cold conditions. A bypass arrangement allows for selectively bypassing one or more portions of the enthalpy recovery device under selected conditions. In one example, the enthalpy recovery device is completely bypassed under selected temperature conditions to allow the device to freeze and then later to be used under more favorable temperature conditions. In another example, the enthalpy recovery device is selectively bypassed during a system startup operation. One example includes a heater associated with the enthalpy recovery device. Another example includes preheating oxidant supplied to one portion of the enthalpy recovery device.
摘要:
Water flow field inlet manifolds (33, 37) are disposed at the fuel cell stack (11) base. Water flow field outlet manifolds (34, 38) are located at the fuel cell stack top. Outlet and inlet manifolds are interconnected (41-43, 47, 49, 50) so gas bubbles leaking through the porous water transport plate cause flow by natural convection, with no mechanical water pump. Variation in water level within a standpipe (58) controls (56, 60, 62, 63) the temperature or flow of coolant. In another embodiment, the water is not circulated, but gas and excess water are vented from the water outlet manifolds. Water channels (70) may be vertical. A hydrophobic region (80) provides gas leakage to ensure bubble pumping of water. An external heat exchanger (77) maximizes water density differential for convective flow.
摘要:
A proton exchange membrane (PEM) fuel cell includes fuel and oxidant flow field plates (26, 40) having fuel and oxidant channels (27, 28; 41, 44), and water channels, the ends (29, 48) of which that are adjacent to the corresponding reactant gas inlet manifold (34, 42) are dead ended, the other ends (31, 50) draining excess water into the corresponding reactant gas exhaust manifold (36, 45). Flow restrictors (39, 47) maintain reactant gas pressure above exit manifold pressure, and may comprise interdigitated channels (65, 66; 76, 78). Solid reactant gas flow field plates have small holes (85, 88) between reactant gas channels (27, 28; 41) and water drain channels (29, 30; 49, 50). In one embodiment, the fuel cells of a stack may be separated by either coolant plates (51) or solid plates (55) or both. In a second embodiment, coolant plates (51a) have weep holes (57) that inject water into the ends (29) of the reactant gas water channels which are in the region of the inlet manifold (34), thereby assuring humidification of the reactants.
摘要:
A coolant treatment system for a direct antifreeze cooled fuel cell power plant including a degassifier for providing interaction between an oxidant and an antifreeze solution which has circulated throughout the fuel cell power plant so that dissolved gases within the antifreeze solution are removed. The fuel cell power plant is configured to allow the antifreeze solution to be in direct fluid communication with the fuel cell assemblies comprising the fuel cell power plant.
摘要:
A fuel cell system is shut down by disconnecting the primary load, shutting off the air flow, and controlling the fuel flow into the system (including shutting off the fuel flow) and the gas flow out of the system in a manner that results in the fuel cell gases coming to equilibrium across the cells at a gas composition of at least 0.0001% hydrogen (by volume), and preferably between 1.0% and less than 4.0% hydrogen, by volume, with a balance of nitrogen and possibly other gases inert and harmless to the fuel cell, all the oxygen having been consumed by reacting with the hydrogen within the cell. That gas composition is maintained within the cells throughout shut-down, such as by adding hydrogen to replace any that is consumed by reaction with air leaking into the cells during the period of shut-down. This shut-down procedure causes virtually no cell performance losses.
摘要:
A direct antifreeze cooled fuel cell power plant is disclosed. The plant includes at least one fuel cell a thermal management system that directs flow of a cooling fluid for controlling heat within the plant, including a direct antifreeze solution passing through the water transport plate. The plant also integrates the direct antifreeze solution with a direct mass and heat transfer device, a water treatment system, and a steam injection system so that the direct antifreeze solution minimizes problems related to operation of the plant in sub-freezing conditions. A preferred antifreeze solution is an alkanetriol selected from the group consisting of glycerol, butanetriol, and pentanetriol. The direct antifreeze solutions minimize movement of the antifreeze as a vapor out of a water transport plate into contact with cathode or anode catalysts, and also minimize direct antifreeze solution loss from other power plant systems.
摘要:
An operating system for a direct antifreeze cooled fuel cell power plant is disclosed for producing electrical energy from reducing and process oxidant fluid reactant streams. The system includes at least one fuel cell for producing electrical energy from the reducing and oxidant fluid streams; fuel processing components for processing a hydrocarbon fuel into the reducing fluid; a thermal management system that directs flow of a cooling fluid for controlling heat within the plant including a porous water transport plate adjacent and in fluid communication with a cathode catalyst of the fuel cell; a direct antifreeze solution passing through the water transport plate; and, a split oxidant passage that directs the process oxidant stream into and through the fuel cell.