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公开(公告)号：US6150297A
公开(公告)日：2000-11-21
申请号：US122958
申请日：1998-07-27
IPC分类号： C07F7/28 , C07F17/00 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/02 , C08F210/02 , C08F212/08 , B01J31/02 , B01J31/18
CPC分类号： C07F17/00 , C08F10/02 , C08F210/02 , C08F2420/02 , C08F4/65908 , Y10S526/943
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CI.sub.ES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.
摘要翻译： 公开了包含环戊基蒽基配体，其催化衍生物和它们作为烯烃聚合催化剂的用途的第4族金属络合物，特别是用于乙烯和乙烯基芳族单体的共聚。 得到的共聚物是乙烯和具有聚簇指数CIES小于1.0的乙烯基芳族单体和聚合的乙烯基芳族单体含量低于50摩尔％的均匀的假无规共聚物。
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公开(公告)号：US06323294B1
公开(公告)日：2001-11-27
申请号：US09598803
申请日：2000-06-21
IPC分类号： C08F444
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/02 , C08F210/02 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CIES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.
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公开(公告)号：US06329486B1
公开(公告)日：2001-12-11
申请号：US09598802
申请日：2000-06-21
IPC分类号： C08F1208
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/02 , C08F210/02 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CIES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.
摘要翻译： 公开了包含环戊基蒽基配体，其催化衍生物和它们作为烯烃聚合催化剂的用途的第4族金属络合物，特别是用于乙烯和乙烯基芳族单体的共聚。 得到的共聚物是乙烯和具有聚簇指数CIES小于1.0的乙烯基芳族单体和聚合的乙烯基芳族单体含量低于50摩尔％的均匀的假无规共聚物。
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4.发明授权公开(公告)号：US06613921B2
公开(公告)日：2003-09-02
申请号：US09879463
申请日：2001-06-12
申请人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
发明人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
IPC分类号： C07F1700
CPC分类号： C07F17/00 , C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Compounds and metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof having up to 60 atoms other than hydrogen, said ligand comprising at least: (1) a cyclopentadienyl ring, (2) a 6, 7, or 8 membered ring other than a 6-carbon aromatic ring, and (3) an aromatic ring, with the proviso that said 6, 7, or 8 membered ring (2), is fused to both the cyclopentadienyl ring (1), and the aromatic ring (3), polymerization catalysts, a process to prepare the novel compounds and complexes, and olefin polymerization processes using the same are disclosed.
摘要翻译： 包含多于60个氢原子的多环，稠环配体或其惰性取代的衍生物的化合物和金属络合物，所述配体至少包括：（1）环戊二烯基环，（2）6,7或8元环 除了6碳芳环以外，和（3）芳香环，条件是所述6,7或8元环（2）与环戊二烯基环（1）和芳环（ 3），聚合催化剂，制备新型化合物和络合物的方法，以及使用其的烯烃聚合方法。
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5.发明授权Substituted polycyclic, fused ring compounds, metal complexes and polymerization process 有权取代的多环，稠环化合物，金属络合物和聚合过程公开(公告)号：US06806327B2
公开(公告)日：2004-10-19
申请号：US10124269
申请日：2002-04-16
申请人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen , Shaoguang Feng
发明人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen , Shaoguang Feng
IPC分类号： C08F444
CPC分类号： C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , C08F4/6592 , C08F212/08
摘要： Metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof comprising at least: (1) a cyclopentadienyl ring, (2) a 7 membered polyatomic ring, and (3) one or more aromatic ring systems, with the proviso that said 7 membered ring (2), is fused to both the cyclopentadienyl ring (1), and said one or more aromatic ring systems (3), and substituted in at least one ring position with a substituent group resulting in sp2 hybridization on the ring atom bonded thereto; polymerization catalysts; and olefin polymerization processes using the same are disclosed.
摘要翻译： 包含多环，稠环配体或其惰性取代的衍生物的金属络合物至少包含：（1）环戊二烯基环，（2）7元多原子环，和（3）一个或多个芳环体系，条件是所述 7元环（2）与环戊二烯基环（1）和所述一个或多个芳族环体系（3）融合，并且在至少一个环位置被取代基取代，导致sp 2杂交 与其结合的环原子; 聚合催化剂; 并且公开了使用其的烯烃聚合方法。
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6.发明授权公开(公告)号：US06800701B2
公开(公告)日：2004-10-05
申请号：US10437161
申请日：2003-05-13
申请人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
发明人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
IPC分类号： C08F444
CPC分类号： C07F17/00 , C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Compounds and metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof having up to 60 atoms other than hydrogen, said ligand comprising at least: (1) a cyclopentadienyl ring, (2) a 6, 7, or 8 membered ring other than a 6-carbon aromatic ring, and (3) an aromatic ring, with the proviso that said 6, 7, or 8 membered ring (2), is fused to both the cyclopentadienyl ring (1), and the aromatic ring (3), polymerization catalysts, a process to prepare the novel compounds and complexes, and olefin polymerization processes using the same are disclosed.
摘要翻译： 包含多于60个氢原子的多环，稠环配体或其惰性取代的衍生物的化合物和金属络合物，所述配体至少包括：（1）环戊二烯基环，（2）6,7或8元环 除了6碳芳环以外，和（3）芳香环，条件是所述6,7或8元环（2）与环戊二烯基环（1）和芳环（ 3），聚合催化剂，制备新型化合物和络合物的方法，以及使用其的烯烃聚合方法。
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公开(公告)号：US06624254B1
公开(公告)日：2003-09-23
申请号：US09593861
申请日：2000-06-14
申请人： Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
发明人： Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
IPC分类号： C08F3008
CPC分类号： C08F290/148 , C08F8/12 , C08F230/08 , C08F2810/50 , C08F210/06 , C08F210/02
摘要： Silane functional polymers having uniform silane distribution, long chain branching or tertiary silane functionality and conversion thereof through coupling, hydrolysis, hydrolysis and neutralization, condensation, oxidation or hydrosilation are disclosed.
摘要翻译： 公开了具有均匀的硅烷分布，长链支化或叔硅烷官能团以及通过偶联，水解，水解和中和，缩合，氧化或硅氢化的转化的硅烷官能聚合物。
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公开(公告)号：US08383542B2
公开(公告)日：2013-02-26
申请号：US13081653
申请日：2011-04-07
申请人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC分类号： C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要： A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and 1-octene and a polymerization process using the polymerization modifier.
摘要翻译： 包含用于共聚至少一种烯烃单体和1-辛烯的聚合改性剂和使用聚合改性剂的聚合方法的组合物。
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公开(公告)号：US07553917B2
公开(公告)日：2009-06-30
申请号：US11596336
申请日：2005-05-13
申请人： Daryoosh Beigzadeh , David D. Devore , Richard E. Campbell, Jr. , Duane R. Romer , James C. Stevens , Hendrik E. Tuinstra , Francis J. Timmers , Paul C. Vosejpka
发明人： Daryoosh Beigzadeh , David D. Devore , Richard E. Campbell, Jr. , Duane R. Romer , James C. Stevens , Hendrik E. Tuinstra , Francis J. Timmers , Paul C. Vosejpka
IPC分类号： C08F4/603 , C08F4/6192 , B01J31/14 , B01J31/22
CPC分类号： C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要： A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要翻译： 用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法，所述催化剂组合物包含过渡金属化合物，助催化剂和聚合改性剂，以及由此产生的催化剂组合物和改进的烯烃聚合方法。
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公开(公告)号：US07943546B2
公开(公告)日：2011-05-17
申请号：US12434436
申请日：2009-05-01
申请人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC分类号： C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要： A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要翻译： 用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法，所述催化剂组合物包含过渡金属化合物，助催化剂和聚合改性剂，以及由此产生的催化剂组合物和改进的烯烃聚合方法。
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