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公开(公告)号:US06624254B1
公开(公告)日:2003-09-23
申请号:US09593861
申请日:2000-06-14
申请人: Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
发明人: Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
IPC分类号: C08F3008
CPC分类号: C08F290/148 , C08F8/12 , C08F230/08 , C08F2810/50 , C08F210/06 , C08F210/02
摘要: Silane functional polymers having uniform silane distribution, long chain branching or tertiary silane functionality and conversion thereof through coupling, hydrolysis, hydrolysis and neutralization, condensation, oxidation or hydrosilation are disclosed.
摘要翻译: 公开了具有均匀的硅烷分布,长链支化或叔硅烷官能团以及通过偶联,水解,水解和中和,缩合,氧化或硅氢化的转化的硅烷官能聚合物。
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2.
公开(公告)号:US08415434B2
公开(公告)日:2013-04-09
申请号:US12978006
申请日:2010-12-23
申请人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号: C08F255/00 , C08F255/02
CPC分类号: C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译: 聚合方法和所得聚合物组合物,所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下,聚合一种或多种可加聚单体和可聚合穿梭剂, 支链聚合物,优选包括伪嵌段分子结构。
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3.
公开(公告)号:US07858707B2
公开(公告)日:2010-12-28
申请号:US12065867
申请日:2006-09-14
申请人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号: C08F297/08 , C08F297/00
CPC分类号: C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译: 聚合方法和所得聚合物组合物,所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下,聚合一种或多种可加聚单体和可聚合穿梭剂, 支链聚合物,优选包括伪嵌段分子结构。
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4.
公开(公告)号:US20090163667A1
公开(公告)日:2009-06-25
申请号:US12065867
申请日:2006-09-14
申请人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号: C08L23/16 , C08F4/44 , C08F2/00 , C08F210/00
CPC分类号: C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译: 聚合方法和所得聚合物组合物,所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下,聚合一种或多种可加聚单体和可聚合穿梭剂, 支链聚合物,优选包括伪嵌段分子结构。
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公开(公告)号:US07943546B2
公开(公告)日:2011-05-17
申请号:US12434436
申请日:2009-05-01
申请人: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC分类号: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要: A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要翻译: 用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法,所述催化剂组合物包含过渡金属化合物,助催化剂和聚合改性剂,以及由此产生的催化剂组合物和改进的烯烃聚合方法。
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6.
公开(公告)号:US20110092651A1
公开(公告)日:2011-04-21
申请号:US12978006
申请日:2010-12-23
申请人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人: Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号: C08F297/02
CPC分类号: C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译: 聚合方法和所得聚合物组合物,所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下,聚合一种或多种可加聚单体和可聚合穿梭剂, 支链聚合物,优选包括伪嵌段分子结构。
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公开(公告)号:US07193024B2
公开(公告)日:2007-03-20
申请号:US10481064
申请日:2002-06-13
IPC分类号: C08F112/08 , C08F112/36 , C08F112/10
CPC分类号: C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F4/6592 , C08F212/36 , C08F2500/03 , C08F2500/15 , C08F2500/09 , C08F236/20 , C08F2500/25
摘要: A polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), the polymer comprising at least 75 mole % of units (1), from 0.01 to 5 mole % of units (2), and up to 20 mole % of units (3), the polymer having a branching factor BF 0.75. A process for preparing a polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), by contacting the alpha-olefin (1′), the divinylbenzene compound (2′), and ethylene (3′) in the presence of a polymerisation catalyst under polymerisation conditions wherein the mole ratio of alpha-olefin (1′) to divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) is at least 10:1, the mole ratio of divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) to ethylene (3′) is in the range of from 1:0.1 to 1:2000, and the mole ratio of (1′) to (3′) is at least 4:1.
摘要翻译: 包含衍生自具有至少3个碳原子的α-烯烃(1')的单元(1)的聚合物,衍生自二乙烯基苯的单元(2)或其衍生自C 1〜10-20烃基取代的衍生物(2' )和衍生自乙烯(3')的单元(3),所述聚合物包含至少75摩尔%的单元(1),0.01至5摩尔%的单元(2)和至多20摩尔%的单元 3),聚合物具有分支因子BF 0.75。 一种制备聚合物的方法,所述聚合物包含衍生自具有至少3个碳原子(1')的α-烯烃的单元(1),衍生自二乙烯基苯或C 1-10烃基取代衍生物的单元(2) (2')和由乙烯(3')衍生的单元(3),通过在聚合反应的存在下使α-烯烃(1'),二乙烯基苯化合物(2')和乙烯(3')接触 催化剂在聚合条件下,其中α-烯烃(1')与二乙烯基苯或其C 1-10烃基取代的衍生物(2')的摩尔比为至少10:1,二乙烯基苯 或其C 1〜10-20烃基取代的衍生物(2')与乙烯(3')的摩尔比为1:0.1至1:2000,并且(1')与 (3')至少为4:1。
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公开(公告)号:US08343886B2
公开(公告)日:2013-01-01
申请号:US13081659
申请日:2011-04-07
申请人: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC分类号: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要: A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and propylene and a polymerization process using the polymerization modifier.
摘要翻译: 包含用于共聚至少一种烯烃单体和丙烯的聚合改性剂和使用聚合改性剂的聚合方法的组合物。
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公开(公告)号:US20110184135A1
公开(公告)日:2011-07-28
申请号:US13081653
申请日:2011-04-07
申请人: Daryoosh Beigzadeh , Richard E. Campbell, JR. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人: Daryoosh Beigzadeh , Richard E. Campbell, JR. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
IPC分类号: C08F4/6592 , B01J31/14 , C08F4/52 , C08F4/642
CPC分类号: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要: A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and 1-octene and a polymerization process using the polymerization modifier.
摘要翻译: 包含用于共聚至少一种烯烃单体和1-辛烯的聚合改性剂和使用聚合改性剂的聚合方法的组合物。
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公开(公告)号:US06258902B1
公开(公告)日:2001-07-10
申请号:US09234831
申请日:1999-01-21
IPC分类号: C08F238
CPC分类号: C08F10/06 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/06 , C08F210/16 , C08F2410/02 , C08F4/65912 , C08F2500/03 , C08F2500/06 , C08F2500/09 , C08F212/08 , C08F210/14 , C08F210/08
摘要: A process for preparing homopolymers and copolymers of addition polymerizable monomers, or mixtures of such monomers, and the resulting polymer, wherein the process comprising contacting said monomer or mixture under high monomer conversion polymerization conditions with a catalyst composition comprising: a) a catalyst system comprising a Group 3-10 metal complex; and c) a silane, or hydrocarbylsilane corresponding to the formula: JjSiH4−j or AnJjSiH4-(n+j) wherein: J is C1-40 hydrocarbyl, A is a C2-20 alkenyl group, n is 1 or 2, and j is 0 or 1; wherein the polymer comprises from 0.1 to 100 long chain branches per 10,000 carbons, and at least some of which comprise a silane branching center.
摘要翻译: 一种制备加成聚合单体或这些单体的混合物的均聚物和共聚物以及所得聚合物的方法,其中所述方法包括在高单体转化聚合条件下将所述单体或混合物与催化剂组合物接触,所述催化剂组合物包含:a)催化剂体系,其包含 一组3-10金属络合物; 和c)对应于下式的硅烷或烃基硅烷:其中:J为C 1-4烃基,A为C 20-20烯基,n为1或2,j为0或1;其中聚合物包含0.1至100 每10,000个碳原子的长链支链,并且其中至少一些包含硅烷分支中心。
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