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1.发明授权
公开(公告)号：US5491204A
公开(公告)日：1996-02-13
申请号：US429442
申请日：1995-04-27
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material is formed from a polyepoxide, a polyamine and an alkanolamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译： 提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。 阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％ 湿度。 阻挡材料由聚环氧化物，多胺和链烷醇胺形成。 任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。 包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。
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公开(公告)号：US5639848A
公开(公告)日：1997-06-17
申请号：US631494
申请日：1996-04-12
CPC分类号： C08G59/5006 , B32B27/08 , C08G59/18 , C08G59/184 , C08G59/50 , C08J7/047 , C08L63/00 , C08J2323/12 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： An ungelled thermoplastic resin having gas barrier properties and containing at least 7 percent by weight of amine nitrogen is derived via the reaction of a polyamine devoid of oxyalkylene moieties and containing up to about two primary amino nitrogen groups per molecule and a polyepoxide in a molar ratio of polyamine to polyepoxide of from 1.4:1 to 0.83:1.
摘要翻译： 具有阻气性并含有至少7重量％胺氮的未凝胶热塑性树脂通过缺乏氧化烯部分的多胺与每分子含有至多约两个伯氨基氮基团和多环氧化物的摩尔比的反应得到 的多胺与聚环氧化物的比例为1.4：1至0.83：1。
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公开(公告)号：US5573819A
公开(公告)日：1996-11-12
申请号：US549291
申请日：1995-10-27
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from polyepoxide and polyamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译： 提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。 阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％ 湿度。 阻挡材料可以由聚环氧化物和多胺形成。 任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。 包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。
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公开(公告)号：US5006381A
公开(公告)日：1991-04-09
申请号：US375659
申请日：1989-06-30
CPC分类号： C08G59/5006 , B32B27/08 , C08G59/18 , C08G59/184 , C08G59/50 , C08J7/047 , C08L63/00 , C08J2323/12 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： Ungelled thermoplastic resins, coating compositions of such resins and multilayer containers and packaging films including a layer of an ungelled thermoplastic resin are disclosed. The ungelled thermoplastic resins are reaction products of polyepoxides with polyamines.
摘要翻译： 公开了未凝胶化热塑性树脂，这种树脂的涂料组合物和多层容器以及包括未凝胶化热塑性树脂层的包装膜。 未凝胶化的热塑性树脂是聚环氧化物与多胺的反应产物。
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公开(公告)号：US5489455A
公开(公告)日：1996-02-06
申请号：US168286
申请日：1993-12-17
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00 , B29D22/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： A container is composed of one at least one layer of a gas-permeable polymeric material such as a polyolefin, polycarbonate or a polyester and at least one layer of a polymeric gas barrier material containing at least seven percent by weight of amine nitrogen derived from the reaction product of a polyamine and a polyepoxide.
摘要翻译： 容器由至少一层气体可透过的聚合材料如聚烯烃，聚碳酸酯或聚酯和至少含有至少七重量百分比的胺氮的至少一层聚合气体阻隔材料组成， 多胺和多环氧化物的反应产物。
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公开(公告)号：US5438109A
公开(公告)日：1995-08-01
申请号：US168351
申请日：1993-12-17
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from polyepoxide and polyamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译： 提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。 阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％ 湿度。 阻挡材料可以由聚环氧化物和多胺形成。 任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。 包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。
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公开(公告)号：US5300541A
公开(公告)日：1994-04-05
申请号：US767458
申请日：1991-09-30
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from polyepoxide and polyamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译： 提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。 阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，并且在23摄氏度的2天气氛中的二氧化碳渗透性小于约15cc密耳/ 100，相对于0％ 湿度。 阻挡材料可以由聚环氧化物和多胺形成。 任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。 包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。
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公开(公告)号：US5008137A
公开(公告)日：1991-04-16
申请号：US367992
申请日：1989-06-19
IPC分类号： C08G59/18 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/31507 , Y10T428/31511 , Y10T428/31797 , Y10T428/31913 , Y10T428/31938
摘要： Multilayer packaging materials and multilayer containers including a barrier material having excellent resistance to gas permeability are provided. The multilayer packaging materials and containers include at least one permeable polymeric material and at least one layer of a barrier material which is a reaction product of: (i) an ungelled amine-functional polymeric resin, which is a reaction product of a polyamine and a polyfunctional material having at least two functional groups reactive with said polyamine, the ungelled polymeric resin further containing an average of greater than two polyamine moieties per molecule within said resin; and (ii) a material selected from the group consisting of a polyepoxide, a polyoxalate or mixtures thereof, the barrier material characterized as containing at least about four percent by weight amine nitrogen and having an oxygen permeability of less than about 3 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from coating compositions including as co-curable resinous materials, e.g., a polyepoxide and an ungelled amine-functional polymeric resin formed from a polyepoxide and a polyamine having up to about two primary amino nitrogen groups per molecule, the polyamine and polyepoxide present in a reaction mixture at a molar ratio of from about 1.4:1 to about 0.83:1.
摘要翻译： 提供了具有优异的耐气体渗透性的阻隔材料的多层包装材料和多层容器。 多层包装材料和容器包括至少一种可渗透聚合物材料和至少一层阻隔材料层，其是以下物质的反应产物：（i）未凝胶化的胺官能聚合物树脂，其是多胺和 具有至少两个与所述多胺反应的官能团的多官能材料，所述未凝胶化聚合物树脂在所述树脂内每分子平均含有大于两个多胺部分; 所述阻挡材料的特征在于含有至少约4重量％的胺氮并具有小于约3cc-mil / cm 3的氧渗透性， 100天2天气氛，二氧化碳渗透性在23℃和0％相对湿度的2天大气压下小于约15cc密耳/ 100。 阻挡材料可以由包括作为共固化树脂材料的涂料组合物形成，例如聚环氧化物和由聚环氧化物形成的未凝胶化的胺官能聚合物树脂和每分子具有多达约两个伯氨基氮基团的多胺，多胺 和聚环氧化物以约1.4:1至约0.83:1的摩尔比存在于反应混合物中。
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9.发明授权Pressurizable thermoplastic container having an exterior polyurethane layer and its method of making 失效具有外部聚氨酯层的可加压热塑性容器及其制造方法
公开(公告)号：US5300334A
公开(公告)日：1994-04-05
申请号：US991484
申请日：1992-12-16
申请人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
发明人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
CPC分类号： C08J7/047 , B65D23/0814 , C08J2475/00 , Y10T428/1352 , Y10T428/1379 , Y10T428/1386 , Y10T428/31551 , Y10T428/31565
摘要： Pressurizable thermoplastic containers, such as those made from polyethylene terephthalate containing a polyurethane layer on the exterior surface thereof are disclosed. The polyurethane layer which is typically applied by a coating process provides the bottle with resistance to stress cracking. The containers are useful as refillable bottles for carbonated beverages which have a tendency to stress crack.
摘要翻译： 公开了可加压热塑性容器，例如由其外表面上含有聚氨酯层的聚对苯二甲酸乙二醇酯制成的那些。 通常通过涂覆方法施加的聚氨酯层为瓶子提供抗应力开裂性。 这些容器可用作具有压力裂纹倾向的碳酸饮料的可再填充瓶。
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公开(公告)号：US5902643A
公开(公告)日：1999-05-11
申请号：US977086
申请日：1997-11-24
IPC分类号： B32B27/38 , B32B27/00 , B65D23/08 , C08G59/50 , C08J7/00 , C08J7/04 , C09D163/00 , B05D3/10 , B29D22/00 , B32B1/02
CPC分类号： C08J7/047 , C08G59/50 , C08J2367/02 , C08J2463/00 , Y10T428/1393 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786
摘要： Disclosed is a multilayer packaging material which is suitable for use as a container for malt beverages and which is tinted so as to block at least 90% of light with wavelengths of electromagnetic radiation ranging from 300 nm to 500 nm. The tinted multilayer packaging materials of the present invention includes: (a) at least one layer of a carbon dioxide (CO.sub.2)-permeable polymeric packaging material, and (b) at least one layer of a CO.sub.2 -treated gas barrier coating, which has an oxygen permeability constant not more than 0.05 cubic centimeter-mil/100 square inches/atmosphere/day. The CO.sub.2 -permeable packaging material can be any polymeric material through which CO.sub.2 can pass and which can be used as a packaging material for food or beverages. The gas barrier coating has an oxygen permeability constant, before CO.sub.2 treatment, of less than 0.3. This gas barrier coating includes the reaction product of a polyamine (A) and a polyepoxide (B). The polyamine (A) can be an initial polyamine or an ungelled polyamine adduct having active amine hydrogens. Polyepoxide (B) can be a polyepoxide having a plurality of glycidyl groups linked to an aromatic member.
摘要翻译： 公开了一种多层包装材料，其适用于麦芽饮料的容器，其被着色以阻挡至少90％的具有300nm至500nm的电磁辐射波长的光。 本发明的有色多层包装材料包括：（a）至少一层二氧化碳（CO 2） - 可渗透聚合物包装材料，和（b）至少一层经CO 2处理的气体阻隔涂层，其具有 氧气渗透常数不大于0.05立方厘米/ 100平方英寸/大气/天。 二氧化碳可透过的包装材料可以是CO 2可以通过的任何聚合物材料，其可用作食品或饮料的包装材料。 阻气涂层在CO2处理之前的氧气渗透率常数小于0.3。 该阻气涂层包括多胺（A）和聚环氧化物（B）的反应产物。 多胺（A）可以是具有活性胺氢的初始多胺或未凝胶化的多胺加合物。 聚环氧化物（B）可以是具有连接到芳族成员的多个缩水甘油基的聚环氧化物。
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