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1.发明授权Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers 有权来自环己烷氧化副产物流的脂肪族聚酯多元醇作为聚氨酯和聚异氰脲酸酯聚合物的前体公开(公告)号：US09056940B2
公开(公告)日：2015-06-16
申请号：US13493840
申请日：2012-06-11
IPC分类号： C07C35/00 , C05G3/00 , C08G18/42 , C08G18/10 , C09D175/06 , C05C9/00 , C07C31/18 , C08G101/00
CPC分类号： C08G18/4222 , C05C9/005 , C05G3/0029 , C07C31/18 , C08G18/10 , C08G18/4286 , C08G2101/00 , C08G2105/02 , C09D175/06
摘要： The invention provides polyester polyol compositions and resin blends, useful as components of polyurethane and polyisocyanurate polymers, produced from cyclohexane oxidation reaction byproducts, such as water extracts and non-volatile distillation residues from the reaction. Such byproducts of industrial processes for preparation of adipic acid and caprolactam, important intermediates in the production of various types of nylon, have hitherto largely been used only as fuels. The present invention provides value-added products, methods for making, and methods for using the byproduct-derived polyester polyol compositions. For example, the invention provides polyurethane (PU) and/or polyisocyanurate (PIR) polymers made using the polyol compositions and polyfunctional isocyanates. The PU and PIR polymers can be used as adhesives, binders (e.g., for wood fibers), coatings (e.g., for controlled release fertilizers), and foams.
摘要翻译： 本发明提供聚酯多元醇组合物和树脂共混物，其可用作由环己烷氧化反应副产物如水提取物和来自反应的非挥发性蒸馏残余物产生的聚氨酯和聚异氰脲酸酯聚合物的组分。 用于制备己二酸和己内酰胺的工业方法的这种副产物，各种类型的尼龙的生产中的重要中间体迄今为止主要仅用作燃料。 本发明提供增值产品，制备方法和使用副产物衍生的聚酯多元醇组合物的方法。 例如，本发明提供使用多元醇组合物和多官能异氰酸酯制备的聚氨酯（PU）和/或聚异氰脲酸酯（PIR）聚合物。 PU和PIR聚合物可用作粘合剂，粘合剂（例如木纤维），涂层（例如用于控释肥料）和泡沫。
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2.发明申请ALIPHATIC POLYESTER POLYOLS FROM CYCLOHEXANE OXIDATION BYPRODUCT STREAMS AS PRECURSORS FOR POLYURETHANE AND POLYISOCYANURATE POLYMERS 有权作为聚氨酯和聚异氰酸酯聚合物前驱体的产品流程的环氧化合物氧化的聚氨酯聚合物公开(公告)号：US20130042659A1
公开(公告)日：2013-02-21
申请号：US13493840
申请日：2012-06-11
IPC分类号： C09K3/00 , C08G18/18 , C05C9/00 , C09D175/04 , C08K7/02 , C09J175/04 , C08G18/10 , C08G18/22
CPC分类号： C08G18/4222 , C05C9/005 , C05G3/0029 , C07C31/18 , C08G18/10 , C08G18/4286 , C08G2101/00 , C08G2105/02 , C09D175/06
摘要： The invention provides polyester polyol compositions and resin blends, useful as components of polyurethane and polyisocyanurate polymers, produced from cyclohexane oxidation reaction byproducts, such as water extracts and non-volatile distillation residues from the reaction. Such byproducts of industrial processes for preparation of adipic acid and caprolactam, important intermediates in the production of various types of nylon, have hitherto largely been used only as fuels. The present invention provides value-added products, methods for making, and methods for using the byproduct-derived polyester polyol compositions. For example, the invention provides polyurethane (PU) and/or polyisocyanurate (PIR) polymers made using the polyol compositions and polyfunctional isocyanates. The PU and PIR polymers can be used as adhesives, binders (e.g., for wood fibers), coatings (e.g., for controlled release fertilizers), and foams.
摘要翻译： 本发明提供聚酯多元醇组合物和树脂共混物，其可用作由环己烷氧化反应副产物如水提取物和来自反应的非挥发性蒸馏残余物产生的聚氨酯和聚异氰脲酸酯聚合物的组分。 用于制备己二酸和己内酰胺的工业方法的这种副产物，各种类型的尼龙的生产中的重要中间体迄今为止主要仅用作燃料。 本发明提供增值产品，制备方法和使用副产物衍生的聚酯多元醇组合物的方法。 例如，本发明提供使用多元醇组合物和多官能异氰酸酯制备的聚氨酯（PU）和/或聚异氰脲酸酯（PIR）聚合物。 PU和PIR聚合物可用作粘合剂，粘合剂（例如木纤维），涂层（例如用于控释肥料）和泡沫。
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3.发明授权Aromatic polyesterpolyols, isocyanurate-modified polyurethane foams, and methods of making them 有权芳族聚酯多元醇，异氰脲酸酯改性聚氨酯泡沫及其制备方法公开(公告)号：US08343378B2
公开(公告)日：2013-01-01
申请号：US12694306
申请日：2010-01-27
IPC分类号： C09K3/00
CPC分类号： C08G63/60 , C08G18/092 , C08G18/1808 , C08G18/4225 , C08G18/4244 , C08G18/4288 , C08G18/7664 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , C08J9/141 , C08J2375/06
摘要： Embodiments of this disclosure include, among others, polyol mixtures, methods of making a polyol mixture, methods of making a rigid isocyanurate-modified polyurethane foam, rigid isocyanurate-modified polyurethane foams, aromatic polyesterpolyols, and the like.
摘要翻译： 本公开的实施方案包括多元醇混合物，制备多元醇混合物的方法，制备刚性异氰脲酸酯改性聚氨酯泡沫塑料的方法，刚性异氰脲酸酯改性的聚氨酯泡沫，芳族聚酯多元醇等。
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4.发明授权Toluate esters for use as reactive and non-reactive diluent in polymer applications 有权用作聚合物应用中的反应性和非反应性稀释剂的托酯公开(公告)号：US07956213B2
公开(公告)日：2011-06-07
申请号：US12728862
申请日：2010-03-22
IPC分类号： C07C69/76
摘要： Disclosed are toluate ester compositions and their use as solvent, plasticizers, extender and/or diluents in binder formulations, a method of producing such ester compositions, as well as polymer compositions containing such liquid ester compositions. Also disclosed is a method of making toluate based esters by reacting methyl-p-toluate with ethylene glycol, diethylene or triethylene glycol, butanediol, etc.
摘要翻译： 公开了甲酸酯组合物及其作为粘合剂配制剂中的溶剂，增塑剂，增量剂和/或稀释剂的用途，制备这种酯组合物的方法，以及含有这种液体酯组合物的聚合物组合物。 还公开了通过使对甲苯甲酸甲酯与乙二醇，二亚乙基或三甘醇，丁二醇等反应制备甲苯甲酸酯的方法。
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5.发明授权Toluate ester for use as reactive and non-reactive diluent in polymer applications 有权用作聚合物应用中的反应性和非反应性稀释剂的托酯公开(公告)号：US07718823B2
公开(公告)日：2010-05-18
申请号：US10557103
申请日：2004-05-13
IPC分类号： C07C67/02
摘要： This invention relates to toluate ester compositions and their use as solvent, plasticizers, extender and/or diluents in binder formulations, a method of producing such ester compositions, as well as polymer compositions containing such liquid ester compositions. The method of making toluate based esters by reacting methyl-p-toluate with ethylene glycol, diethylene or triethylene glycol, butanediol, etc. More particularly, this invention relates to the mono- or di-ester of methyl toluic acid with a diol containing 2 to 6 carbon atoms that are low viscosity liquids at 25° C. The most common polymer that employs plasticizer is polyvinyl chloride (PVC). Typical amounts of plasticizer in PVC are from about 3 wt. % to about 50 wt. %. Phenolic resins generally require solvents, diluents and/or extenders that reduce the volatility and viscosity of the resin, especially when it is used in building and automotive products. Typical amounts of solvent are from about 5 wt. % to about 65 wt. %.
摘要翻译： 本发明涉及甲酸酯组合物及其作为粘合剂制剂中的溶剂，增塑剂，增量剂和/或稀释剂的用途，制备这种酯组合物的方法，以及含有这种液体酯组合物的聚合物组合物。 通过使对甲苯甲酸甲酯与乙二醇，二乙二醇或三甘醇，丁二醇等反应制备甲苯甲酸酯的方法。更具体地说，本发明涉及甲基甲苯甲酸与含有2的二醇的单酯或二酯 至6个碳原子，这是25℃下的低粘度液体。使用增塑剂的最常见的聚合物是聚氯乙烯（PVC）。 PVC中增塑剂的典型量为约3wt。 ％至约50wt。 ％。 酚醛树脂通常需要降低树脂的挥发性和粘度的溶剂，稀释剂和/或增量剂，特别是当用于建筑和汽车产品时。 溶剂的典型量为约5wt。 ％至约65wt。 ％。
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公开(公告)号：US08895773B2
公开(公告)日：2014-11-25
申请号：US12463018
申请日：2009-05-08
摘要： The present invention relates to the manufacture of alkyl p-toluates from an alkyl p-toluic acid ester and a mono-functional, branched, linear or cyclic medium chain length alkyl alcohol, and their use as a plasticizer in polymers. Additionally, the present invention relates to articles and materials comprising such alkyl p-toluates.
摘要翻译： 本发明涉及由对甲苯甲酸烷基酯和单官能，支链，直链或环状的中链长度烷基醇制备对甲苯甲酸烷基酯，以及它们在聚合物中作为增塑剂的用途。 另外，本发明涉及包含这种对甲苯甲酸烷基酯的制品和材料。
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7.发明申请AROMATIC POLYESTERPOLYOLS, ISOCYANURATE-MODIFIED POLYURETHANE FOAMS, AND METHODS OF MAKING THEM 有权芳族聚异戊二烯，异氰酸酯改性聚氨酯泡沫塑料及其制备方法公开(公告)号：US20110028581A1
公开(公告)日：2011-02-03
申请号：US12694306
申请日：2010-01-27
CPC分类号： C08G63/60 , C08G18/092 , C08G18/1808 , C08G18/4225 , C08G18/4244 , C08G18/4288 , C08G18/7664 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , C08J9/141 , C08J2375/06
摘要： Embodiments of this disclosure include, among others, polyol mixtures, methods of making a polyol mixture, methods of making a rigid isocyanurate-modified polyurethane foam, rigid isocyanurate-modified polyurethane foams, aromatic polyesterpolyols, and the like.
摘要翻译： 本公开的实施方案包括多元醇混合物，制备多元醇混合物的方法，制备刚性异氰脲酸酯改性聚氨酯泡沫塑料的方法，刚性异氰脲酸酯改性的聚氨酯泡沫，芳族聚酯多元醇等。
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