摘要:
Improved superconducting coils for a nuclear magnetic resonance probe use capacitive elements that are located in regions further from an active sample volume than magnetic field generating elements to which they are electrically connected. The sample volume is a substantially oblong shape, and the magnetic field generating elements run substantially parallel to the major axis of the shape, while the capacitor elements run perpendicular to the major axis. Gaps between the capacitor elements, and the width of the elements themselves, may increase toward the outside of the coil to minimize electrical discharge. The variation may be according to a monotonic, possibly linear, function. Discharge may also be minimized by using a dielectric cover that, together with a coil substrate, encloses the coil.
摘要:
RF electric fields produced by electric potential differences in NMR probe coil windings may penetrate the NMR sample and sample tube causing sensitivity loss and noise in NMR spectroscopy. Counter-wound spiral coils placed on the opposite surfaces of a planar substrate or on two adjacent planar substrates produce electric potentials that minimize the electric field over the sample region, thereby increasing the sensitivity of the NMR probe. Alternatively counter-wound spiral coils placed adjacent to each other on the outer surface of two concentric cylindrical surfaces that surround the NMR sample minimize the electric field over the sample region. The electric potential of the spiral coils is reduced by adjusting a length of at least one coil.
摘要:
RF electric fields produced by electric potential differences in NMR probe coil windings may penetrate the NMR sample and sample tube causing sensitivity loss and noise in NMR spectroscopy. Counter-wound spiral coils placed on the opposite surfaces of a planar substrate or on two adjacent planar substrates produce electric potentials that minimize the electric field over the sample region, thereby increasing the sensitivity of the NMR probe. Alternatively counter-wound spiral coils placed adjacent to each other on the outer surface of two concentric cylindrical surfaces that surround the NMR sample minimize the electric field over the sample region. The electric potential of the spiral coils is reduced by adjusting a length of at least one coil.
摘要:
A method and apparatus which utilizes the hysteritic behavior of type II superconductors is provided for reducing the effective magnetic susceptibility of such high temperature superconducting materials being used close to the sample region in nuclear magnetic resonance system probes by providing decaying AC changes in the magnetic field parallel to said superconductive material. The method is particularly applicable to receiver coils. Reducing the effective magnetic susceptibility of superconducting receiver coils enables the improved sensitivity they inherently provide to be realized without loss of resolution resulting from line broadening caused by susceptibility discontinuities of materials near the sample region of the probe.
摘要:
An optical imaging system for use as a solid-state camera, for example, which includes a plurality of solid-state elements for providing long-term storage of images, such elements being, for example, MNOS chips having a plurality of storage cells, which chips when exposed to an image focussed thereon can store a representation thereof. The chips are at a later time optically addressed, as by a scanning-light beam, to read out the stored image so as to provide an electrical output representing the stored image, such output being usable to provide a visual representation of the image such as on a display screen or in hard copy form.
摘要:
RF electric fields produced by electric potential differences in the NMR probe coil windings may penetrate the NMR sample and sample tube causing sensitivity loss and increased noise in NMR spectroscopy. Electrically conducting strips in close proximity to the windings of the NMR probe coil and oriented at right angles to direction of the coil winding they cross provide an alternative path for these electric fields while causing negligible effect upon the RF magnetic field, thereby increasing the sensitivity of the NMR probe.
摘要:
Improved superconducting coils for a nuclear magnetic resonance probe use capacitive elements that are located in regions further from an active sample volume than magnetic field generating elements to which they are electrically connected. The sample volume is a substantially oblong shape, and the magnetic field generating elements run substantially parallel to the major axis of the shape, while the capacitor elements run perpendicular to the major axis. The magnetic field generating elements and the capacitor elements may vary in length relative to their distance from a center of the oblong shape. The total number of capacitors formed by the loops may vary from one embodiment to another, typically depending on the necessary resonant frequency. A coil may use sub-coils, each of which incorporates a plurality of the magnetic field generating elements and interdigital capacitor elements, the capacitor elements preferably being located to both sides of the oblong shape.
摘要:
RF electric fields produced by electric potential differences in the NMR probe coil windings may penetrate the NMR sample and sample tube causing sensitivity loss and increased noise in NMR spectroscopy. Electrically conducting strips in close proximity to the windings of the NMR probe coil and oriented at right angles to direction of the coil winding they cross provide an alternative path for these electric fields while causing negligible effect upon the RF magnetic field, thereby increasing the sensitivity of the NMR probe.
摘要:
An NMR buffer is particularly useful for biomolecules that require a certain amount of salt in the buffer solution. A primary buffer component and a titrating component are selected based on low ion mobility. These selections allow for a lower conductivity buffer without reducing the salt content. As such, a higher sensitivity experiment results.
摘要:
The invention provides highly sensitive NMR probes for spectroscopy and microscopy. Thin-film superconducting coils on planar substrates are inductively coupled to form an RF transmitter/receiver. Two embodiments are illustrated. The first, which is particularly suited to liquid samples, uses two coils are positioned on opposite sides of a sample, with their long axis parallel to the axis of the sample. The coils are sized and positioned to maximize SNR, field homogeneity or field strength. In the second embodiment, circular coils are deposited on a substrate having a central aperture. Several coils in a solenoidal configuration are positioned orthogonal to and surrounding the sample.