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1.发明授权
公开(公告)号：US5508035A
公开(公告)日：1996-04-16
申请号：US145055
申请日：1993-10-27
摘要： Stable emulsions of water-insoluble organic pesticides are formed by mixing the pesticide with an aqueous dispersion of a graft copolymer comprising a reactive polymeric surfactant base polymer and a nonionic hydrophobic grafted composition. The graft copolymer spontaneously absorbs organic pesticides with low water solubility upon simple mixing. The resulting product is much more stable to coalescence than emulsions made with conventional or polymeric surfactants.Emulsifiable organic based concentrates, having a continuous oil phase, which are formed from admixtures of pesticidally active water-insoluble organic pesticides with graft copolymers can be diluted with or in water, thus, inverting the continuous oil phase to stable water based oil-in-water emulsions of the active pesticide.
摘要翻译： 通过将农药与包含反应性聚合物表面活性剂基础聚合物和非离子疏水接枝组合物的接枝共聚物的水分散体混合而形成水不溶性有机农药的稳定乳液。 接枝共聚物在简单混合时自发吸收水溶性低的有机农药。 与用常规或聚合物表面活性剂制成的乳液相比，得到的产物比聚结更稳定。 由杀虫活性水不溶性有机农药与接枝共聚物的混合物形成的具有连续油相的可乳化有机基浓缩物可以用水稀释，也可以在水中稀释，从而将连续油相转化为稳定的水基油 - 活性农药水乳剂。
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2.发明授权
公开(公告)号：US5188824A
公开(公告)日：1993-02-23
申请号：US763791
申请日：1991-09-23
摘要： Stable, aqueous emulsion formulations of water-insoluble organic pesticides are formed from a mixture of (1) a water-insoluble organic pesticide, (2) a water based structured particle latex containing nonionic particles to which is bound a layer containing stabilizing pH independent ionic groups chemically bound at or near the surface of the polymer particles, and optionally a cosolvent and/or a cosurfactant for the pesticide. The resulting product is much more stable to coalescence than emulsions made with conventional surfactants.
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3.发明授权
公开(公告)号：US5089259A
公开(公告)日：1992-02-18
申请号：US400418
申请日：1989-08-30
摘要： Stable, aqueous emulsion formulations of water-insoluble organic pesticides are formed from a mixture of (1) a water-insoluble organic pesticide, (2) a water based structured particle latex containing nonionic particles to which is bound a layer containing stabilizing pH independent ionic groups chemically bound at or near the surface of the polymer particles, and optionally a cosolvent and/or cosurfactant for the pesticide. The resulting product is much more stable to coalescence than emulsions made with conventional surfactants.
摘要翻译： 稳定的水不溶性有机农药的水性乳液制剂由（1）水不溶性有机农药，（2）含有非离子颗粒的水基结构化颗粒胶乳的混合物形成，其结合含有稳定的pH独立离子的层 在聚合物颗粒表面或其附近化学结合的基团，以及任选的农药的共溶剂和/或辅助表面活性剂。 与用常规表面活性剂制成的乳液相比，所得产物的聚结更加稳定。
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公开(公告)号：US5753248A
公开(公告)日：1998-05-19
申请号：US560233
申请日：1995-11-21
IPC分类号： A01N25/02 , A01N25/04 , C08F2/04 , C08F2/08 , C08F257/02 , C08F265/04
CPC分类号： A01N25/02 , A01N25/04 , C08F257/02 , C08F265/04
摘要： The present invention further provides a substantially non-aqueous agricultural pesticide concentrate formulation of a non-ionic surfactant and a amphipathic graft copolymer composition in admixture with a water-insoluble organic agricultural pesticide which concentrate formulation can be easily diluted with water to form non-settling, freeze-thaw stable formulations. The present invention further provides methods for the use of water-diluted agricultural pesticide concentrate formulations of the above non-ionic surfactant concentrate formulations in the kill and control of agricultural pest.
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5.发明授权Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups 失效通过阳离子基团与亲核基团反应制备的半透膜
公开(公告)号：US4839203A
公开(公告)日：1989-06-13
申请号：US86122
申请日：1987-08-17
申请人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
发明人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
IPC分类号： B01D67/00 , B01D69/08 , B01D69/12 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/08 , B01D69/125 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , B01D2323/30
摘要： A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.
摘要翻译： 描述了一种新型复合膜及其制备方法。 膜的鉴别层通过反应性阳离子化合物基团与带有亲核部分的化合物的反应来制备。 至少一种反应物平均具有两个或更多个反应性基团。 反应产物含有通过电荷消除反应形成的共价键。 在本发明的优选实施方案中，亲核基团是阴离子的，并且最初在微孔基材上形成凝聚层。 所得的膜可用于反渗透，气体或超滤分离。
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公开(公告)号：US4178205A
公开(公告)日：1979-12-11
申请号：US825319
申请日：1977-08-17
CPC分类号： D21H17/44
摘要： A high strength, non-woven fibrous material is prepared by (a) mixing an aqueous slurry of a negatively charged, water-insoluble natural or synthetic fiber or blend of fibers with an amount up to the fiber charge reversal point of a structured particle latex having pH independent cationic charges bound at or near the particle surface to form an aqueous suspension, (b) draining water from the aqueous suspension to form a wet web (c) wet pressing the web and (d) drying the web by heating.
摘要翻译： 通过以下方法制备高强度非织造纤维材料：（a）将带负电荷的水不溶性天然或合成纤维或纤维混合物的水性浆料与结构化颗粒胶乳的纤维充电反转点的量混合 具有在颗粒表面处或附近结合的pH无关的阳离子电荷以形成水性悬浮液，（b）从水性悬浮液中排出水以形成湿纸幅（c）湿压纸幅和（d）通过加热干燥纸幅。
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7.发明授权Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups 失效通过阳离子基团与亲核基团反应制备的半透膜
公开(公告)号：US4704324A
公开(公告)日：1987-11-03
申请号：US790287
申请日：1985-10-22
申请人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
发明人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
IPC分类号： C08J5/22 , B01D20060101 , B01D67/00 , B01D69/02 , B01D69/08 , B01D69/12 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , B32B5/00 , B01D13/00
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/08 , B01D69/125 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , B01D2323/30 , Y10T428/249953 , Y10T428/249958 , Y10T428/249965 , Y10T428/249972 , Y10T428/249978
摘要： A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.
摘要翻译： 描述了一种新型复合膜及其制备方法。 膜的鉴别层通过反应性阳离子化合物基团与带有亲核部分的化合物的反应来制备。 至少一种反应物平均具有两个或更多个反应性基团。 反应产物含有通过电荷消除反应形成的共价键。 在本发明的优选实施方案中，亲核基团是阴离子的，并且最初在微孔基材上形成凝聚层。 所得的膜可用于反渗透，气体或超滤分离。
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公开(公告)号：US4187142A
公开(公告)日：1980-02-05
申请号：US825323
申请日：1977-08-17
CPC分类号： D21H21/54 , C08F8/44 , D21H17/34 , D21H17/375 , D21H17/43
摘要： A process for preparing a high strength composite by (A) mixing (1) an aqueous slurry of negatively charged, water-insoluble natural or synthetic fiber such as cellulose fiber, (2) a latex having a high density of pH independent cationic charges, such as sulfonium, bound at or near the particle surface, (3) a water-soluble, high molecular weight anionic polymer co-additive, such as a hydrolyzed polyacrylamide and optionally (4) conventional wet end additives; (B) draining water from the resulting aqueous suspension; (C) drying by heating.
摘要翻译： （A）混合（1）带负电荷的水不溶性天然或合成纤维如纤维素纤维的水性浆料，（2）具有高密度pH独立阳离子电荷的胶乳的制备高强度复合材料的方法， 例如结合在颗粒表面上或附近的锍，（3）水溶性高分子量阴离子聚合物共添加剂，例如水解聚丙烯酰胺和任选的（4）常规湿端添加剂; （B）从所得水悬浮液中排出水; （C）加热干燥。
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9.发明授权
公开(公告)号：US4797187A
公开(公告)日：1989-01-10
申请号：US86123
申请日：1987-08-17
申请人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
发明人： Thomas E. Davis , Donald L. Schmidt , Jee I. Kau , Ritchie A. Wessling , Sharon S. Whipple , Richard F. Fibiger , Dale M. Pickelman
IPC分类号： C08J5/22 , B01D20060101 , B01D67/00 , B01D69/02 , B01D69/08 , B01D69/12 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , C05B7/00
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/08 , B01D69/125 , B01D69/14 , B01D71/40 , B01D71/44 , B01D71/46 , B01D71/52 , B01D71/68 , B01D71/72 , B01D71/80 , B01D71/82 , B01D2323/30 , Y10T428/249953 , Y10T428/249958 , Y10T428/249965 , Y10T428/249972 , Y10T428/249978
摘要： A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.
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10.发明授权
公开(公告)号：US4525526A
公开(公告)日：1985-06-25
申请号：US554510
申请日：1983-11-23
CPC分类号： C08F8/44
摘要： Substantially linear, synthetic, water-soluble or water-dispersible cationic interpolymeric surfactants which are particularly useful for reducing the surface tension of an aqueous medium; such surfactants having a critical micelle concentration of from 0.01 to about 10 percent in water at 25.degree. C., a charge density of from about 1 to 5 meq/g and a number average molecular weight of from about 500 to about 40,000 and being composed of a plurality of nonionic hydrophobic units and pH independent hydrophilic cationic units randomly distributed in the backbone of such interpolymeric surfactants and wherein an average molecule of such surfactant contains from 1 to about 5 hydrophilic cationic units substituted with a pendant hydrophobic group, such hydrophobic group being an aralkyl group of from about 8 to about 20 carbon atoms are prepared by (1) aqueous, emulsion polymerization of a mixture of ethylenically unsaturated nonionic monomers at least one of which contains an ion-forming group in the presence of a copolymerizable monomeric surfactant to form a latex, (2) reacting the resulting latex with a coreactant to form a water-soluble cationic interpolymer.
摘要翻译： 特别适用于降低水性介质表面张力的基本线性，合成的，水溶性或水分散性的阳离子互聚表面活性剂; 这种表面活性剂在25℃的水中的临界胶束浓度为0.01至约10％，电荷密度为约1至5meq / g，数均分子量为约500至约40,000，并且组成 多个非离子疏水单元和pH不依赖的亲水阳离子单元，其随机分布在这种互聚表面活性剂的主链中，并且其中平均分子表面活性剂含有1至约5个被侧基疏水基取代的亲水性阳离子单元， 通过以下方法制备约8至约20个碳原子的芳烷基：（1）在可共聚的单体表面活性剂存在下，其中至少一种含有离子形成基团的烯键式不饱和非离子单体的混合物的水性乳液聚合， 形成胶乳，（2）使所得胶乳与共反应物反应以形成水溶性阳离子互聚物。
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