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    Photographic element and compound and process useful therewith
    1.
    发明授权
    Photographic element and compound and process useful therewith 失效
    摄影元素及其有用的化合物和方法

    公开(公告)号：US06296997B1

    公开(公告)日：2001-10-02

    申请号：US09707586

    申请日：2000-11-07

    申请人： Robert F. Romanet ,  William B. Vreeland ,  John W. Harder ,  Christopher T. Brown ,  Scott R. Conley ,  Michael P. Youngblood

    发明人： Robert F. Romanet ,  William B. Vreeland ,  John W. Harder ,  Christopher T. Brown ,  Scott R. Conley ,  Michael P. Youngblood

    IPC分类号： G03C108

    CPC分类号： G03C5/386

    摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a bicyclic azole dye-forming coupler compound having Formula I: wherein: BA represents a bicyclic azole coupler nucleus with —(C(R1)(R2))P— bonded to a ring carbon in a non-coupling position of the coupler nucleus; p is 1 or 2, and each R1 and R2 is independently selected from H and a substituent group, provided that any two of R1 and R2 may join to form a ring; Ra and Rb are each independently selected from H and a substituent group, provided that substituent groups may join to form a ring; each Y is an independently selected substituent and m is 0-4; X is selected from the group consisting of —C(O)—, —S(O)2—, —S(O)—, and —P(O)(OH)—; W is a connecting group having a chain of up to four atoms between X and Z, and n=0 or 1; and a) when n=0, Z is —NHR5 where R5 is H or a substituent, and b) when n=1, Z is selected from —OH, —SO2NHR5, and —NHR6 where R5 is H or a substituent group and R6 is a substituent bonded to —NH— by an electron withdrawing group in R6; provided that the ClogP value of the coupler compound is at least 5.0. The element provides improved color rendition.

    摘要翻译： 公开了一种照相元件，其包含感光卤化银乳剂层，其具有式I的双环唑形染料形成成色剂化合物：其中：BA表示具有 - （C（R 1）（R 2））P的双环唑偶合子核 - 键合到成色剂核的非偶联位置的环碳; p为1或2，并且每个R 1和R 2独立地选自H和取代基，条件是R 1和R 2中的任何两个可以连接形成 环; R a和R b各自独立地选自H和取代基，条件是取代基可以连接形成环;每个Y是独立选择的取代基，m是0-4; X选自 -C（O） - ， - S（O）2 - ， - S（O） - 和-P（O）（OH） - ; W是在X和Z之间具有至多四个原子的链的连接基团 ，n = 0或1; 和a）当n = 0时，Z是-NHR 5，其中R 5是H或取代基，和b）当n = 1时，Z选自-OH，-SO 2 NHR 5和-NHR 6，其中R 5是H或取代基，R 6是 通过R6中的吸电子基团与-NH-键合的取代基;条件是成色剂化合物的ClogP值至少为5.0。该元素提供改进的色彩再现。

    Synthesis of certain triazole compounds
    2.
    发明授权
    Synthesis of certain triazole compounds 失效
    某些三唑化合物的合成

    公开(公告)号：US06657066B1

    公开(公告)日：2003-12-02

    申请号：US10315631

    申请日：2002-12-10

    申请人： Ileana Place ,  John W. Harder ,  Robert F. Romanet ,  William B. Vreeland

    发明人： Ileana Place ,  John W. Harder ,  Robert F. Romanet ,  William B. Vreeland

    IPC分类号： C07D48704

    CPC分类号： C07D487/04

    摘要： Disclosed is a process for forming a 1H-pyrazolo (1,5-b)-[1,2,4]-triazole compound by ring closing a pyrazoloamidine compound comprising reacting the amidine with an oxidizing agent having a reduction potential vs Ag/AgCl that is more positive than −0.16V and less than +1.43V in the presence of a halogen atom. The invention also discloses certain triazole compounds that are successfully made by the conventional process. The process and compounds of the invention provide improved yields and reduce or eliminate unwanted side-reactions.

    摘要翻译： 公开了通过闭合吡唑并脒化合物形成1H-吡唑并（1,5-b） - [1,2,4] - 三唑化合物的方法，包括使脒与还原电位相对于Ag / AgCl的氧化剂反应 在存在卤素原子的情况下比-0.16V更正，小于+ 1.43V。 本发明还公开了通过常规方法成功制备的某些三唑化合物。 本发明的方法和化合物提供了提高的产率并减少或消除了不希望的副反应。

    DYE TRANSFERABLE MATERIAL WITH IMPROVED IMAGE STABILITY
    6.
    发明申请
    DYE TRANSFERABLE MATERIAL WITH IMPROVED IMAGE STABILITY 有权
    具有改进的图像稳定性的可转染的材料

    公开(公告)号：US20110067804A1

    公开(公告)日：2011-03-24

    申请号：US12565140

    申请日：2009-09-23

    申请人： William B. Vreeland

    发明人： William B. Vreeland

    IPC分类号： B41M5/50 ,  B41M5/03 ,  B41M5/035

    CPC分类号： B41M5/392 ,  B41M5/5227 ,  B41M7/0027 ,  B41M2205/02

    摘要： A heat transferable dye donor element includes a heat transferable dye and an N-oxyl radical light stabilizer that is derived from a hindered amine. The N-oxyl radical has the following formula, wherein R1, R2, R5, and R6 are each independently selected from a straight or branched C1-C6 alkyl, and R3 and R4 are each independently selected from H, OH, OR, COOH, or COOR, wherein R is a straight or branched C1-C6 alkyl or alkene, and has a molecular weight of 600 or less. The dye donor element includes a heat transferable material that can be in one or more sections or patches including heat transferable dye patches. The heat transferable material provides better dye image stability when applied to a thermal receiver element.

    摘要翻译： 可传热染料供体元件包括可转移染料和衍生自受阻胺的N-氧基自由基光稳定剂。 N-氧基具有下式，其中R 1，R 2，R 5和R 6各自独立地选自直链或支链C 1 -C 6烷基，R 3和R 4各自独立地选自H，OH，OR，COOH， 或COOR，其中R为直链或支链C1-C6烷基或烯烃，分子量为600以下。 染料供体元件包括可以在一个或多个部分中的可传热材料或包含可热转染色剂的贴剂。 当应用于热接收器元件时，可传热材料提供更好的染料图像稳定性。

    HEAT TRANSFERABLE MATERIAL FOR IMPROVED IMAGE STABILITY
    7.
    发明申请
    HEAT TRANSFERABLE MATERIAL FOR IMPROVED IMAGE STABILITY 有权
    用于改进图像稳定性的热转印材料

    公开(公告)号：US20100218887A1

    公开(公告)日：2010-09-02

    申请号：US12565112

    申请日：2009-09-23

    申请人： William B. Vreeland

    发明人： William B. Vreeland

    IPC分类号： B44C1/17 ,  B41M5/382 ,  B41M5/50 ,  C08K5/3435

    CPC分类号： B41M7/0027 ,  B41M5/392 ,  B41M5/423 ,  B41M2205/06 ,  B41M2205/30 ,  B41M2205/40

    摘要： A heat transferable material includes a heat transferable polymeric binder and a light stabilizer that is an N-oxyl radical derived from a hindered amine, the N-oxyl radical having the following formula, wherein R1, R2, R5, and R6 are each independently selected from a straight or branched C1-C6 alkyl, and R3 and R4 are each independently selected from H, OH, OR, COOH, or COOR, wherein R is a straight or branched C1-C6 alkyl or alkene, and having a molecular weight of 600 or less, is described. The heat transferable material can be in one or more sections or patches on a thermal donor element to provide a protective overcoat material. Optionally, a patch in the donor element can also include a dye. The heat transferable material provides better image stability and improved iridescence when applied to a thermal, inkjet, electophotographic, or silver halide receiver.

    摘要翻译： 可传热材料包括可传热聚合物粘合剂和作为衍生自受阻胺的N-氧基的光稳定剂，具有下式的N-氧基：其中R 1，R 2，R 5和R 6各自独立地选自 从直链或支链的C 1 -C 6烷基，并且R 3和R 4各自独立地选自H，OH，OR，COOH或COOR，其中R是直链或支链C 1 -C 6烷基或烯烃，并且分子量为 600以下。 可传热材料可以在热供体元件上的一个或多个部分或贴片中以提供保护性外涂层材料。 任选地，供体元件中的贴片还可以包括染料。 当应用于热，喷墨，电子摄影或卤化银接收器时，可传热材料提供更好的图像稳定性和改进的虹彩。

    Method and apparatus for transferring toner
    9.
    发明授权
    Method and apparatus for transferring toner 失效
    用于转印调色剂的方法和设备

    公开(公告)号：US5715509A

    公开(公告)日：1998-02-03

    申请号：US661291

    申请日：1996-06-10

    申请人： William J. Staudenmayer ,  William B. Vreeland

    发明人： William J. Staudenmayer ,  William B. Vreeland

    IPC分类号： G03G15/16 ,  G03G21/20

    CPC分类号： G03G15/167 ,  G03G15/161 ,  G03G21/20

    摘要： To assist transfer of toner images from a first transfer surface to a second transfer surface, the first transfer surface is actively cooled to prevent the toner sticking to it. Preferably, the cooling is accomplished by thermoelectric control device strips positioned in heat conducting relation with the first transfer surface. A thermoelectric control device can also be used to heat a second or receiving surface to which the toner is to be transferred to farther assist the transfer process.

    摘要翻译： 为了辅助将调色剂图像从第一转印表面转印到第二转印表面，第一转印表面被主动冷却以防止调色剂粘附到其上。 优选地，冷却通过与第一转印表面导热的热电控制装置条实现。 也可以使用热电控制装置来加热调色剂要转印到的第二或接收表面，以进一步帮助转印过程。