公开(公告)号：US3993457A

公开(公告)日：1976-11-23

申请号：US635367

申请日：1975-11-26

申请人： Robert P. Cahn ,  John P. Longwell ,  Stephen L. Wythe

发明人： Robert P. Cahn ,  John P. Longwell ,  Stephen L. Wythe

IPC分类号： C07C29/151 ,  C10K3/04 ,  C10L3/00

CPC分类号： C10L3/00 ,  C07C29/1518 ,  C10K3/04 ,  Y02E50/32 ,  Y02P20/582

摘要： Methanol and synthetic natural gas are produced concurrently by introducing a carbonaceous material into a gasification zone, and thereafter, passing sequentially the synthesis gas thus formed through a water gas shift conversion zone, a sulfur compound and carbon dioxide removal zone, a methanol synthesis zone and a methanation zone.

摘要翻译： 甲醇和合成天然气同时通过将碳质材料引入气化区，然后依次通过水煤气变换区，硫化合物和二氧化碳去除区，甲醇合成区和 甲烷化区。

公开(公告)号：US4058575A

公开(公告)日：1977-11-15

申请号：US586177

申请日：1975-06-12

申请人： Robert P. Cahn ,  John P. Longwell

发明人： Robert P. Cahn ,  John P. Longwell

IPC分类号： B01J27/12 ,  C07C5/27 ,  C07C13/00 ,  C07C3/56 ,  C07C5/28

CPC分类号： B01J27/12 ,  C07C5/2721 ,  Y02P20/584

摘要： Partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a metal selected from Group III-A, IV-B, V or VI-B elements of the Periodic Table, X is a halogen, n is the ratio of halogen atoms to atoms of M and varies from 1-8, and (b) a strong Bronsted acid are contacted with a hydrocarbon feedstock to recover the active or potentially active catalyst species from the partially deactivated catalyst stream prior to regeneration. In addition, potential organic and inorganic catalyst poisons present in said feedstock are removed therefrom during said contacting prior to introducing said feedstock into a hydrocarbon conversion process.

摘要翻译： 部分失活的烃转化催化剂，其包含（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表III-A，IV-B，V或VI-B族元素的金属，X是卤素， n是卤素原子与M原子的比率并且从1-8变化，和（b）强烈的布朗斯台德酸与烃原料接触以在再生之前从部分失活的催化剂物流中回收活性或潜在活性的催化剂物质 。 此外，在将所述原料引入烃转化过程之前，在所述接触期间，从所述原料中除去存在于所述原料中的潜在有机和无机催化剂毒物。

公开(公告)号：US4343606A

公开(公告)日：1982-08-10

申请号：US120651

申请日：1980-02-11

申请人： David W. Blair ,  William Bartok ,  John P. Longwell ,  Adel F. Sarofim

发明人： David W. Blair ,  William Bartok ,  John P. Longwell ,  Adel F. Sarofim

IPC分类号： F23C6/04 ,  F23M1/00

CPC分类号： F23C6/04

摘要： Fuels containing fixed-nitrogen chemical species are combusted in a multi-stage process. The process which converts substantially all of the fixed-nitrogen into molecular nitrogen (and thus avoids the formation of significant amounts of nitrogen oxides from the fixed-nitrogen) consists of four steps: (a) mixing said fuel with at least one first oxidizing agent in amounts such that the equivalence ratio of said fuel to said oxidizing agent is at least about 1.4; (b) partially combusting the mixture resulting from step (a) in at least one first stage at a first temperature of about 1850.degree. to about 2150.degree. K., with a residence time of at least 0.03 second; (c) mixing the combustion products resulting from step (b) with at least one second oxidizing agent in an amount such that the equivalence ratio of combustion products to the total amount of oxidizing agents in the mixture will be about 1.0 or less, such mixing taking place under conditions such that the temperature of the mixture will not exceed about 1800.degree. K.; and (d) completely combusting the mixture resulting from step (c) in at least one second stage at a second temperature of less than about 1800.degree. K.

摘要翻译： 含有固氮化学物质的燃料在多级过程中燃烧。 基本上将所有固定氮转化成分子氮（从而避免从固定氮中形成大量氮氧化物）的过程由四个步骤组成：（a）将所述燃料与至少一种第一氧化剂 其量使得所述燃料与所述氧化剂的当量比至少为约1.4; （b）在约1850℃至约2150℃的第一温度的至少一个第一阶段部分燃烧由步骤（a）得到的混合物，停留时间至少为0.03秒; （c）将步骤（b）产生的燃烧产物与至少一种第二氧化剂混合，其量使得燃烧产物与混合物中氧化剂总量的当量比为约1.0或更小，这样的混合 在混合物的温度不超过约1800℃的条件下进行; 和（d）在小于约1800°K的第二温度下在至少一个第二阶段中将由步骤（c）得到的混合物完全燃烧。

公开(公告)号：US4409094A

公开(公告)日：1983-10-11

申请号：US176580

申请日：1980-08-08

申请人： John P. Longwell ,  William A. Peters

发明人： John P. Longwell ,  William A. Peters

IPC分类号： C10G11/04 ,  C10G29/16

CPC分类号： C10G29/16 ,  C10G11/04

摘要： A process for treating liquid hydrocarbons to remove toxic, mutagenic and/or carcinogenic aromatic hydrocarbons comprises feeding the hydrocarbons into a reactor where vapors are thermally treated in contact with a catalyst consisting essentially of calcium oxide or a calcium oxide containing mineral. Thermally treating liquid hydrocarbons in contact with calcium oxide preferentially increases the cracking of aromatics thus producing a product having a reduced amount of aromatic compounds.

摘要翻译： 用于处理液体烃以除去有毒，致突变和/或致癌芳香烃的方法包括将烃进料到反应器中，其中蒸气与主要由氧化钙或含氧化钙组成的矿物质组成的催化剂接触进行热处理。 与氧化钙接触的液体烃的热处理优先增加芳族化合物的裂化，从而产生具有减少量芳族化合物的产物。

公开(公告)号：US4388062A

公开(公告)日：1983-06-14

申请号：US218631

申请日：1980-12-22

申请人： William Bartok ,  Yih H. Song ,  Vince J. Siminski ,  John P. Longwell

发明人： William Bartok ,  Yih H. Song ,  Vince J. Siminski ,  John P. Longwell

IPC分类号： F23C6/04 ,  F23M3/04

CPC分类号： F23C6/04

摘要： Fuels containing fixed-nitrogen chemical species are combusted in a multi-stage process. The process which converts substantially all of the fixed-nitrogen into molecular nitrogen (and thus avoids the formation of significant amounts of nitrogen oxides from the fixed-nitrogen) comprises six steps: (a) mixing the fuel with at least one first oxidizing agent in amounts such that the equivalence ratio of said fuel to said oxidizing agent is at least about 1.4; (b) partially combusting the mixture resulting from step (a) in at least one first stage at a first temperature of about 1750.degree. to about 2150.degree. K., with a residence time of at least 0.03 second to less than 0.2 second; (c) injecting a free radical agent into the partially combusted mixture of said fuel and said first oxidizing agent; (d) reacting the mixture of said free radical agent and said partially combusted mixture of said fuel and said first oxidizing agent for at least about 0.05 second to about 0.2 second; (e) mixing the reaction products resulting from step (d) with at least one second oxidizing agent in an amount such that the equivalence ratio of reaction products to the total amount of oxidizing agents in the mixture will be about 1.0 or less, such mixing taking place under conditions such that the temperature of the mixture will not exceed about 1800.degree. K.; and (f) completely combusting the mixture resulting from step (e) in at least one second stage at a second temperature of less than about 1800.degree. K.

摘要翻译： 含有固氮化学物质的燃料在多级过程中燃烧。 基本上将所有固定氮转化成分子氮（从而避免从固定氮中形成大量氮氧化物）的方法包括六个步骤：（a）将燃料与至少一种第一氧化剂混合在 使得所述燃料与所述氧化剂的当量比为至少约1.4; （b）在约1750°至约2150°K的第一温度的至少一个第一阶段部分燃烧由步骤（a）得到的混合物，停留时间为至少0.03秒至小于0.2秒; （c）将自由基试剂注入所述燃料和所述第一氧化剂的部分燃烧的混合物中; （d）使所述自由基和所述部分燃烧的所述燃料和所述第一氧化剂的混合物的混合物反应至少约0.05秒至约0.2秒; （e）将由步骤（d）得到的反应产物与至少一种第二氧化剂混合，使得反应产物与混合物中氧化剂总量的当量比为约1.0或更小，这样的混合 在混合物的温度不超过约1800℃的条件下进行; 和（f）在小于约1800°K的第二温度下在至少一个第二阶段完全燃烧由步骤（e）得到的混合物。