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公开(公告)号：US06545103B2
公开(公告)日：2003-04-08
申请号：US09897562
申请日：2001-07-02
IPC分类号： C08F834
摘要： Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.
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公开(公告)号：US06031060A
公开(公告)日：2000-02-29
申请号：US82072
申请日：1998-05-20
摘要： Terminally functionalized silicone polymers prepared using protected functionalized initiators and processes for preparing the same. The silicone polymers includes protected, functionalized silicone polymers, such as mono-functional, homotelechelic, heterotelechelic, macromonomer, and radial polymers. The protected functionalized polymers can be optionally deprotected to afford functionalized silicone polymers.
摘要翻译： 使用保护的官能化引发剂制备的终端官能化硅氧烷聚合物及其制备方法。 硅氧烷聚合物包括受保护的官能化硅氧烷聚合物，例如单官能，均酮，异链烯，大分子单体和径向聚合物。 保护的官能化聚合物可以任选脱保护，得到官能化的硅氧烷聚合物。
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3.发明授权Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions 失效提供末端阴离子的改进功能化和末端阴离子改进功能化的方法的组合物公开(公告)号：US06858679B2
公开(公告)日：2005-02-22
申请号：US10359960
申请日：2003-02-07
摘要： Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.
摘要翻译： 公开了包含一种或多种阴离子聚合引发剂和一种或多种用于提高活性聚合物阴离子的官能化效率的添加剂的组合物。 本发明还提供包含一种或多种亲电子试剂和一种或多种用于提高活性聚合物阴离子的官能化效率的添加剂的组合物。 还公开了用于改善聚合物阴离子官能化效率的新型亲电子试剂和方法。
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4.发明授权Amine anionic polymerization initiators and functionalized polymers derived therefrom 失效胺阴离子聚合引发剂和衍生自其的官能化聚合物
公开(公告)号：US6121474A
公开(公告)日：2000-09-19
申请号：US256737
申请日：1999-02-24
申请人： James Anthony Schwindeman , Eric John Granger , Roderic Paul Quirk , Randy W. Hall , Robert James Letchford
发明人： James Anthony Schwindeman , Eric John Granger , Roderic Paul Quirk , Randy W. Hall , Robert James Letchford
IPC分类号： C08C19/44 , C08F4/46 , C08F8/42 , C08F36/04 , C08F257/02 , C08F279/02 , C07F7/02 , C07F7/10
CPC分类号： C08F279/02 , C08C19/44 , C08F257/02 , C08F36/04 , C08F4/46 , C08F8/42
摘要： Protected amine anionic polymerization initiators useful in the preparation of polymers having a protected amine functional group. The initiators are very soluble in hydrocarbon solvents.
摘要翻译： 用于制备具有受保护的胺官能团的聚合物的受保护的胺阴离子聚合引发剂。 引发剂非常易溶于烃溶剂。
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5.发明授权
公开(公告)号：US06107408A
公开(公告)日：2000-08-22
申请号：US31351
申请日：1998-02-26
IPC分类号： C08C19/44 , C08F236/10 , C08G81/02
CPC分类号： C08G81/022 , C08C19/44 , C08F236/10
摘要： Processes for the synthesis of star or multi-branched polymers and the resultant polymers. One or more alkadiene monomers are polymerized in the presence of suitable organometallic initiators and subsequently coupled to form star polymers. Prior to coupling, one or more alkenylsubstituted aromatic hydrocarbons are incorporated at the living ends of the polydienyl anions to provide increased linking efficiencies.
摘要翻译： 用于合成星形或多支化聚合物和所得聚合物的方法。 一种或多种链烯二烯单体在合适的有机金属引发剂的存在下聚合，随后偶联形成星形聚合物。 在偶联之前，一个或多个烯基取代的芳烃被并入聚二烯阴离子的活性末端以提供增加的连接效率。
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6.发明授权Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions 失效提供末端阴离子的改进功能化和末端阴离子改进功能化的方法的组合物公开(公告)号：US06605564B1
公开(公告)日：2003-08-12
申请号：US09301535
申请日：1999-04-28
IPC分类号： B01J3100
摘要： Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed. The additives are generally alkali metal halides or alkoxides, and the initiators are generally organs alkali metal compounds, particularly alkyl lithium compounds.
摘要翻译： 公开了包含一种或多种阴离子聚合引发剂和一种或多种用于提高活性聚合物阴离子的官能化效率的添加剂的组合物。 本发明还提供包含一种或多种亲电子试剂和一种或多种用于提高活性聚合物阴离子的官能化效率的添加剂的组合物。 还公开了用于改善聚合物阴离子官能化效率的新型亲电子试剂和方法。 添加剂通常是碱金属卤化物或醇盐，引发剂通常是碱金属化合物，特别是烷基锂化合物。
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公开(公告)号：US06271330B1
公开(公告)日：2001-08-07
申请号：US09373211
申请日：1999-08-12
IPC分类号： C08G7706
摘要： Terminally functionalized silicone polymers prepared using protected functionalized initiators and processes for preparing the same. The silicone polymers includes protected, functionalized silicone polymers, such as mono-functional, homotelechelic, heterotelechelic, macromonomer, and radial polymers. The protected functionalized polymers can be optionally deprotected to afford functionalized silicone polymers.
摘要翻译： 使用保护的官能化引发剂制备的终端官能化硅氧烷聚合物及其制备方法。 硅氧烷聚合物包括受保护的官能化硅氧烷聚合物，例如单官能，均酮，异链烯，大分子单体和径向聚合物。 保护的官能化聚合物可以任选脱保护，得到官能化的硅氧烷聚合物。
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8.发明授权Protected functionalized heterotelechelic polymers and processes for preparing the same 失效受保护的官能化杂多炔类聚合物及其制备方法公开(公告)号：US06362284B1
公开(公告)日：2002-03-26
申请号：US09195895
申请日：1998-11-19
IPC分类号： C08F832
CPC分类号： C08F8/00 , C08C19/02 , C08C19/44 , C08F8/04 , C08F8/42 , C08F36/04 , C08F12/00 , C08F4/48 , C08F4/72 , C08F4/46
摘要： Protected, functionalized heterotelechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers. Monomers are polymerized using a protected functionalized initiator to form a living polymer, and the living polymer is reacted with an electrophile to form heterotelechelic polymers.
摘要翻译： 受保护的官能化杂多炔类聚合物，其氢化和/或去保护的类似物，以及制备这些聚合物的方法。 使用保护的官能化引发剂聚合单体以形成活性聚合物，并且使活性聚合物与亲电试剂反应以形成异极乙烯基聚合物。
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公开(公告)号：US6107414A
公开(公告)日：2000-08-22
申请号：US196289
申请日：1998-11-19
摘要： Protected, functionalized heterotelechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers. Monomers are polymerized using a protected functionalized initiator to form a living polymer, and the living polymer is reacted with an electrophile to form heterotelechelic polymers.
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10.发明授权Protected functionalized telechelic polymers and processes for making the same 失效受保护的功能化遥爪聚合物和制造相同的方法
公开(公告)号：US5965681A
公开(公告)日：1999-10-12
申请号：US107678
申请日：1998-06-30
CPC分类号： C08C19/44 , C08F36/04 , Y10T428/31551 , Y10T428/31591 , Y10T428/31725 , Y10T428/31757 , Y10T428/31783 , Y10T428/31902 , Y10T442/2484 , Y10T442/2787 , Y10T442/2811
摘要： Protected, functionalized telechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers are disclosed. In the invention, a lithium initiator is added to a compound having at least two independently polymerizable vinyl groups to form a dilithium initiator. Monomer is then added to grow or polymerize polymer arms having living ends and the living ends functionalized.
摘要翻译： 公开了保护的官能化遥爪聚合物，其氢化和/或去保护的类似物，以及制备这些聚合物的方法。 在本发明中，将锂引发剂加入具有至少两个独立可聚合的乙烯基的化合物中以形成二锂引发剂。 然后加入单体以生长或聚合具有活性末端并且活性末端官能化的聚合物臂。
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